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Volume 28
Main Index

Issue 1


Assignment of the valence molecular orbitals of cis-[PtR2L2] complexes: UV photoelectron spectra and SCF-MS-X.alpha. calculations
Dong Sheng Yang, G. Michael Bancroft, John D. Bozek, R. J. Puddephatt, and John S. Tse
pp 1 - 2; DOI:
10.1021/ic00300a001
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Rational synthesis of monooxo thioanions from tetrakis(benzenethiolato)oxomolybdate(1-). Structural characterization of the [Ph4P]+ salts of the [(.eta.2-S2)MoO(.mu.-S)2MoS(.eta.2-S2)]2-, [(.eta.2-S2)MoO(MoS4)]2-, [(S4)MoX(.mu.-S)2MoSX(.eta.2-S2)]2- (X = S, O), and [(S4)MoO(MoS4)]2- anions
D. Coucouvanis and Sang Man Koo
pp 2 - 5; DOI:
10.1021/ic00300a002
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An equilibrium involving edge- and face-shared bioctahedral d3-d3 ditungsten complexes: W2Cl6(PEt3)4 and W2Cl6(PEt3)3
Stephanie T. Chacon, Malcolm H. Chisholm, William E. Streib, and William Van der Sluys
pp 5 - 6; DOI:
10.1021/ic00300a003
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Variable temperature T1 studies on rhenium hydrido phosphine complexes, ReH5(PPh3)3, PR3=PMePh2 and PPh3, ReH7(PPh3)2, and Re2H8(PPh3)4. Classical or nonclassical hydrides?
F. Albert Cotton and Rudy L. Luck
pp 6 - 8; DOI:
10.1021/ic00300a004
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Oxo-molybdenum(V) complexes with sulfide and hydrogensulfide ligands: models for the molybdenum(V) centers of xanthine oxidase and xanthine dehydrogenase
Raghuvir Singh, Jack T. Spence, Graham N. George, and Stephen P. Cramer
pp 8 - 10; DOI:
10.1021/ic00300a005
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Halogenation of benzyl- and (heteroaromatic methyl)cobaloximes: direct competition between ring halogenation and cobalt-carbon bond cleavage
B. D. Gupta, Manoj Kumar, and Sujit Roy
pp 11 - 18; DOI:
10.1021/ic00300a006
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Interaction of the iron(III) complex of N-[2-((o-Hydroxyphenyl)glycino)ethyl]salicylideneamine with catechol and cyanide: a model for the binding site in the dioxygenase enzymes
K. Spartalian and Carl J. Carrano
pp 19 - 24; DOI:
10.1021/ic00300a007
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Polymeric thiolate complexes in solution. Solution equilibria studies of the cadmium(II) complexes of 3-(dimethylamino)-1-propanethiol and comparative study with other aliphatic .gamma.-mercapto amines
P. Gonzalez-Duarte and J. Vives
pp 25 - 30; DOI:
10.1021/ic00300a008
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Does one-electron transfer to nickel(II) porphyrins involve the metal or the porphyrin ligand?
Doris Lexa, Michel Momenteau, Joel Mispelter, and Jean Michel Saveant
pp 30 - 35; DOI:
10.1021/ic00300a009
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The pentacoordinate [CuI((imidH)2DAP)]+ cation: its structural verification, ligand rearrangement, and deceptive reaction with dioxygen
John A. Goodwin, Greg A. Bodager, Lon J. Wilson, David M. Stanbury, and W. Robert Scheidt
pp 35 - 42; DOI:
10.1021/ic00300a010
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Ligand-substitution and electron-transfer reactions of pentacoordinate copper(I) complexes
John A. Goodwin, Lon J. Wilson, David M. Stanbury, and Robert A. Scott
pp 42 - 50; DOI:
10.1021/ic00300a011
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Effects of transition-metal ions on the reduction of di-2-pyridyl ketone with sodium borohydride
Myunghyun Paik Suh, Chee Hun Kwak, and Junghun Suh
pp 50 - 53; DOI:
10.1021/ic00300a012
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Electrochemical investigation of kinetic and thermodynamic aspects of oxidation and reduction of mononuclear and binuclear rhodium dithiocarbamate and diselenocarbamate complexes
Alan M. Bond, Ray Colton, and Desma R. Mann
pp 54 - 59; DOI:
10.1021/ic00300a013
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Oxidative synthesis of bis(.mu.-hydroxo)chromium(III) dimers with aromatic amine ligands. Structure, physical properties, and base hydrolysis kinetics of the bis(.mu.-hydroxo)bis[(tris(2-pyridylmethyl)amine)chromium(III)] ion
Boyd G. Gafford and Robert A. Holwerda
pp 60 - 66; DOI:
10.1021/ic00300a014
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Early stages of the hydrolysis of chromium(III) in aqueous solution. 4. The stability constants of the hydrolytic dimer, trimer, and tetramer at 25.degree.C and I = 1.0 M
Hans Stuenzi, Leone Spiccia, Francois P. Rotzinger, and Werner Marty
pp 66 - 71; DOI:
10.1021/ic00300a015
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Use of thermal lensing spectrophotometry (TLS) for the study of mononuclear hydrolysis of uranium(IV)
Ingmar Grenthe, Giovanni Bidoglio, and Nicolo Omenetto
pp 71 - 74; DOI:
10.1021/ic00300a016
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Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 7. Photochemistry of (CO)4CoM(CO)3(bpy) (M = Mn, Re; bpy = 2,2'-bipyridine): photocatalytic disproportionation of the manganese complex in the presence of PR3
Hans K. Van Dijk, Jos Van der Haar, Derk J. Stufkens, and Ad Oskam
pp 75 - 81; DOI:
10.1021/ic00300a017
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Luminescent tetrametallic complexes of ruthenium
W. Rorer Murphy, Karen J. Brewer, Geoffrey Gettliffe, and John D. Petersen
pp 81 - 84; DOI:
10.1021/ic00300a018
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Multiple-state emission from ligand-bridged tungsten carbonyl [(OC)5W-L-W(CO)5] complexes
Mthembeni M. Zulu and Alistair J. Lees
pp 85 - 89; DOI:
10.1021/ic00300a019
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Knudsen effusion mass spectrometric investigation of palladium-germanium clusters
J. E. Kingcade and K. A. Gingerich
pp 89 - 92; DOI:
10.1021/ic00300a020
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Infrared, Raman, resonance Raman, and excitation profile studies of tetrakis(.mu.-acetato)bis[(triphenylarsine)rhodium(II)](Rh-Rh), and tetrakis(.mu.-acetato)bis[(triphenylstibine)rhodium(II)](Rh-Rh)
Robin J. H. Clark and Andrew J. Hempleman
pp 92 - 96; DOI:
10.1021/ic00300a021
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Magnetic and spectroscopic characterization of the high-spin (6A1) .dblharw. low-spin (2T2) transition in an iron(III) complex of pyridoxal thiosemicarbazone
Madan Mohan, Puranam H. Madhuranath, Alok Kumar, Munesh Kumar, and Narendra K. Jha
pp 96 - 99; DOI:
10.1021/ic00300a022
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Ferromagnetic interactions between t2g3 and eg2 magnetic orbitals in a chromium(III)nickel(II)3 tetranuclear compound
Yu Pei, Yves Journaux, and Olivier Kahn
pp 100 - 103; DOI:
10.1021/ic00300a023
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Electronic structure and enhanced reactivity of carbon dioxide coordinated with a rhodium(I) complex. An ab initio MO study
Shigeyoshi Sakaki, Tetsuro Aizawa, Nobuaki Koga, Keiji Morokuma, and Katsutoshi Ohkubo
pp 103 - 109; DOI:
10.1021/ic00300a024
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Electron correlation effects on the ground-state structure and stability of triborane(9)
John F. Stanton, William N. Lipscomb, Rodney J. Bartlett, and Michael L. McKee
pp 109 - 111; DOI:
10.1021/ic00300a025
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Crystal and molecular structure of the (.mu.-hydroxo)dicopper(II) O-BISTREN complex Cu2(OH)(C24O3N8H54)Br3.6H2O
Ramunas J. Motekaitis, Philip R. Rudolf, Arthur E. Martell, and Abraham Clearfield
pp 112 - 115; DOI:
10.1021/ic00300a026
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1,3-Bis(2,5,8,11-tetraazaundecyl)benzene (MXTRIEN): synthesis, binucleating chelating tendencies, and formation and thermal degradation of its cobalt dioxygen complex
Rached Menif and Arthur E. Martell
pp 116 - 122; DOI:
10.1021/ic00300a027
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Direct electrochemical synthesis of alkane- and arenethiolato derivatives of indium and thallium
James H. Green, Rajesh Kumar, Narace Seudeal, and Dennis G. Tuck
pp 123 - 127; DOI:
10.1021/ic00300a028
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Ferric ion sequestering agents. 20. 2,3-Dihydroxyterephthalamides: highly efficient iron(III)-chelating agents
Thomas M. Garrett, Peter W. Miller, and Kenneth N. Raymond
pp 128 - 133; DOI:
10.1021/ic00300a029
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Effects of anions on redox reactions. 2. Chromium(II) reduction of sepulcratocobalt(3+) in the presence of halide ions
Nita A. Lewis, William L. Purcell, and Daniel V. Taveras
pp 133 - 138; DOI:
10.1021/ic00300a030
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Synthesis of asymmetric dirhodium(4+) complexes. X-ray crystal structure of Rh2(form)3(NO3)(PPh3).0.5CH2Cl2 and Rh2(form)3(NO3)(C5H5N) (form = N,N'-di-p-tolylformamidinate)
Pasquale Piraino, Giuseppe Bruno, Giuseppe Tresoldi, Sandra Lo Schiavo, and Francesco Nicolo
pp 139 - 144; DOI:
10.1021/ic00300a031
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p.pi.-p.pi. Bonding between phosphorus and sulfur: synthesis and characterization of a dithiaphospholium cation
Neil Burford, Bruce W. Royan, Anthony Linden, and T. Stanley Cameron
pp 144 - 150; DOI:
10.1021/ic00300a032
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Synthesis of the new organic metal bis[bis(ethylenedithio)tetrathiafulvalene] tricyanomethanide and characterization of its metal-insulator phase transition at .apprx.180 K
Mark A. Beno, Hau H. Wang, L. Soderholm, K. Douglas Carlson, L. N. Hall, Luis Nunez, Helena Rummens, Benjamin Anderson, John A. Schlueter, and et al.
pp 150 - 154; DOI:
10.1021/ic00300a033
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Homogeneous coprecipitation as a means toward high-Tc and sharp-transition yttrium barium cuprate (YBa2Cu3O7-x) superconducting oxides
R. S. Liu, C. T. Chang, and P. T. Wu
pp 154 - 156; DOI:
10.1021/ic00300a034
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Outer-sphere electron transfer between (cyclam)nickel(2+) and copper(III) imine-oxime complexes
Ashiq Hussein, Yousif Sulfab, and Mohamed Nasreldin
pp 157 - 160; DOI:
10.1021/ic00300a035
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Coordination behavior of acetazolamide (5-acetamido-1,3,4-thiadiazole-2-sulfonamide): synthesis, crystal structure, and properties of bis(acetazolamidato)tetraamminenickel(II)
S. Ferrer, J. Borras, C. Miratvilles, and A. Fuertes
pp 160 - 163; DOI:
10.1021/ic00300a036
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Lewis base adducts of main group 1 metal compounds. 7. The lithium-coinage-metal parallel: novel adducts of lithium(I) bromide and iodide with 2,6-dimethylpyridine
Colin L. Raston, Claire R. Whitaker, and Allan H. White
pp 163 - 165; DOI:
10.1021/ic00300a037
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Cobalt-carbon bond disruption enthalpies: the first reliable measurement of a Co-methyl BDE via solution thermochemical methods
Paul J. Toscano, Allen L. Seligson, Matthew T. Curran, Andrew T. Skrobutt, and David C. Sonnenberger
pp 166 - 168; DOI:
10.1021/ic00300a038
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Issue 2


Oxidation of tertiary amine buffers by copper(II)
Fengjiang Wang and Lawrence M. Sayre
pp 169 - 170; DOI:
10.1021/ic00301a001
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Preparation, structure, and reactivity of the non-bonded organoditantalum(IV) complexes (.eta.-C5Me4R)2Ta2(.mu.-X)2X4 (R = Me, Et; X = Cl, Br), precursors to the doubly bonded organoditantalum(III) complexes (.eta.-C5Me4R)2Ta2(.mu.-X)4
Ching Ting and Louis Messerle
pp 171 - 173; DOI:
10.1021/ic00301a002
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Structural model for the binding of iron by anthracycline drugs
Michael J. Maroney, Roberta O. Day, Thomas Psyris, Lisa M. Fleury, and Joyce P. Whitehead
pp 173 - 175; DOI:
10.1021/ic00301a003
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Synthesis and characterization of a trinuclear polyoxomolybdate containing a reactive [MoO3] unit, [(n-C4H9)4N]2[Mo3O7(CH3C(CH2O)3)2], and its conversion to the methoxy derivative [(n-C4H9)4N][Mo3O6(OCH3)(CH3C(CH2O)3)2]
Lidun Ma, Shuncheng Liu, and Jon Zubieta
pp 175 - 177; DOI:
10.1021/ic00301a004
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Self-assembling trimolecular redox chains at zeolite Y modified electrodes
Zhuyin Li, Cuiwei Lai, and Thomas E. Mallouk
pp 178 - 182; DOI:
10.1021/ic00301a005
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Syntheses and crystal structures of syn and gauche isomers of the chloride-bridged face-sharing bioctahedral molybdenum(III) dimers [PHMe3][Mo2Cl7(PMe3)2]
F. Albert Cotton and Rudy L. Luck
pp 182 - 187; DOI:
10.1021/ic00301a006
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Ligand design for complexation in aqueous solution. 1. Neutral oxygen donor bearing groups as a means of controlling size-based selectivity for metal ions
Robert D. Hancock, Rekha Bhavan, Peter W. Wade, Jan C. A. Boeyens, and Susan M. Dobson
pp 187 - 194; DOI:
10.1021/ic00301a007
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The solubilization process of sulfur in liquid ammonia and the equilibrium state of these solutions
P. Dubois, J. P. Lelieur, and G. Lepoutre
pp 195 - 200; DOI:
10.1021/ic00301a008
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Some perfluoroalkyl-substituted tripnicogens and their hydrolysis to yield chiral dipnicogens
Larry R. Avens, Richard A. Wolcott, Leonard V. Cribbs, and Jerry L. Mills
pp 200 - 205; DOI:
10.1021/ic00301a009
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Reactions of secondary phosphines with a phosphorus-phosphorus bond and related reactions
Larry R. Avens, Leonard V. Cribbs, and Jerry L. Mills
pp 205 - 211; DOI:
10.1021/ic00301a010
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Exchange reactions of tetrakis(trifluoromethyl)diphosphine with pnicogen-pnicogen, phosphorus-hydrogen, and phosphorus-chlorine bonds
Larry R. Avens, Leonard V. Cribbs, and Jerry L. Mills
pp 211 - 214; DOI:
10.1021/ic00301a011
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Unanticipated formation of dibromo[1,2-bis(diphenylphosphino)ethane]nickel(II) by sequential Michael reversion and Michael addition of dibromobis(diphenylvinylphosphine)nickel(II)
Jeffrey A. Rahn, Andre Delian, and John H. Nelson
pp 215 - 217; DOI:
10.1021/ic00301a012
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Intramolecular [4 + 2] Diels-Alder cycloaddition reactions of phospholes with vinylphosphines promoted by palladium and platinum
Jeffrey A. Rahn, Mark S. Holt, George A. Gray, Nathaniel W. Alcock, and John H. Nelson
pp 217 - 226; DOI:
10.1021/ic00301a013
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Novel reactions of the [BPh4]- salt of the bifunctional complex [(triphos)Rh(S2CO)]+ (triphos = MeC(CH2PPh2)3): one-electron reduction, cleavage of B-H and B-C bonds, and metathesis of CS2-like heteroallene molecules
Claudio Bianchini, Andrea Meli, Franco Laschi, Francesco Vizza, and Piero Zanello
pp 227 - 233; DOI:
10.1021/ic00301a014
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The iron-nitrato/iron-nitrosyl couple in the presence of hexamethylphosphoric triamide and its relevance to oxygen activation and transfer. X-ray structure of Fe(NO3)(Cl)2(HMPA)2
Henri Li Kam Wah, Michele Postel, and Felix Tomi
pp 233 - 238; DOI:
10.1021/ic00301a015
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Synthesis and characterization of paramagnetic trinickel-molybdenum and trinickel-tungsten clusters
Michael J. Chetcuti, John C. Huffman, and Steven R. McDonald
pp 238 - 242; DOI:
10.1021/ic00301a016
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IR investigation of pentacarbonyliron adducts at the surface of silicalite, ZSM-5, zeolite Y, and .gamma.-alumina
K. Mohana Rao, G. Spoto, E. Guglielminotti, and A. Zecchina
pp 243 - 247; DOI:
10.1021/ic00301a017
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Coordination of cyclodextrin: synthesis and characterization of two diastereomers of (.alpha.- and .beta.-cyclodextrinato)bis(ethylenediamine)cobalt(III)(1+) and their related complexes
Kazuaki Yamanari, Motonori Nakamichi, and Yoichi Shimura
pp 248 - 252; DOI:
10.1021/ic00301a018
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Organometallic precursors to aluminum nitride: synthesis and crystal structures of amidodimethylaluminum trimer and the planar species amidodi-tert-butylaluminum trimer
Leonard V. Interrante, Gary A. Sigel, Mary Garbauskas, Carolyn Hejna, and Glen A. Slack
pp 252 - 257; DOI:
10.1021/ic00301a019
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Preparation, characterization, and crystal structure of the adducts WOF4.nC5H5N (n = 1, 2)
Lucile Arnaudet, Roland Bougon, Buu Ban, Pierrette Charpin, Jacques Isabey, Monique Lance, Martine Nierlich, and Julien Vigner
pp 257 - 262; DOI:
10.1021/ic00301a020
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Chemistry of yttrium triisopropoxide revisited. Characterization and crystal structure of Y5(.mu.5-O)(.mu.3-OPr-iso)4(.mu.2-OPr-iso)4(OPr-iso)5
Olivier Poncelet, William J. Sartain, Liliane G. Hubert-Pfalzgraf, Kirsten Folting, and Kenneth G. Caulton
pp 263 - 267; DOI:
10.1021/ic00301a021
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Structural origin of semiconducting properties of the molybdenum red bronzes A0.33MoO3 (A = potassium, rubidium, cesium, thallium)
Myung Hwan Whangbo, Michel Evain, Enric Canadell, and Marcel Ganne
pp 267 - 271; DOI:
10.1021/ic00301a022
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Magnetic properties of lanthanide complexes with nitronyl nitroxides.
C. Benelli, A. Caneschi, D. Gatteschi, L. Pardi, P. Rey, D. P. Shum, and R. L. Carlin
pp 272 - 275; DOI:
10.1021/ic00301a023
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Structure and magnetic properties of linear-chain complexes of rare-earth ions (gadolinium, europium) with nitronyl nitroxides
C. Benelli, A. Caneschi, Dante Gatteschi, L. Pardi, and P. Rey
pp 275 - 280; DOI:
10.1021/ic00301a024
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Vibrational and x-ray photoelectron spectroscopy for tetrachlorotetrakis(trimethylphosphine)molybdenumtungsten
Richard T. Carlin and Robert E. McCarley
pp 280 - 282; DOI:
10.1021/ic00301a025
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Polarized specular reflectance spectra of the partially oxidized metallophthalocyanines Ni(pc)I and Co(pc)I: charge-transfer transitions in one-dimensional conductors
Michael D. Heagy, Dean E. Rende, Glenn W. Shaffer, Bonnie M. Wolfe, Kwangkyoung Liou, Brian M. Hoffman, and Ronald L. Musselman
pp 283 - 286; DOI:
10.1021/ic00301a026
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Single-crystal EPR spectra of copper-manganese bimetallic ferrimagnetic chains
Dante Gatteschi, Olivier Guillou, Claudia Zanchini, Roberta Sessoli, Olivier Kahn, Michel Verdaguer, and Yu Pei
pp 287 - 290; DOI:
10.1021/ic00301a027
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Matrix infrared spectra of reaction and photolysis products of stibine and ozone
Lester Andrews, Brian W. Moores, and Kathleen K. Fonda
pp 290 - 297; DOI:
10.1021/ic00301a028
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Spectra and structure of organophosphorus molecules. 39. Microwave, Raman, and infrared spectra of trimethylphosphine sulfide and three deuteriated species.
J. R. Durig and K. K. Chatterjee
pp 298 - 304; DOI:
10.1021/ic00301a029
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Carbon dioxide interaction with pentacarbonylhydridochromate(1-): theoretical study of the thermodynamic aspects
C. Bo and A. Dedieu
pp 304 - 309; DOI:
10.1021/ic00301a030
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Photophysical investigation of palladium(II) ortho-metalated complexes
Carl A. Craig and Richard J. Watts
pp 309 - 313; DOI:
10.1021/ic00301a031
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Remarkable structures of dialane(4), Al2H4
Koop Lammertsma, Osman F. Guener, R. Michelle Drewes, Alan E. Reed, and Paul v. R. Schleyer
pp 313 - 317; DOI:
10.1021/ic00301a032
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Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 6. Photochemistry of Ph3SnM(CO)3(.alpha.-diimine) (M = Mn, Re): evidence for different primary photoprocesses of the manganese and rhenium complexes
Ronald R. Andrea, Wim G. J. De Lange, Derk J. Stufkens, and Ad Oskam
pp 318 - 323; DOI:
10.1021/ic00301a033
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Flash photolysis studies of organotransition-metal complexes. Kinetics and mechanism of substitution reactions of [Co(CO)(L)(THF)NO] (THF = tetrahydrofuran; L = CO, PPh3, P(OPh)3)
Shulin Zhang and Gerard R. Dobson
pp 324 - 329; DOI:
10.1021/ic00301a034
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Activation volumes for aquation of chromium(III) pentaammine complexes with neutral leaving groups: comparison with and mechanistic differentiation from cobalt(III) analogs
Neville J. Curtis, Geoffrey A. Lawrance, and Rudi Van Eldik
pp 329 - 333; DOI:
10.1021/ic00301a035
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Volumes of activation and volume profiles as mechanistic criteria for base hydrolysis reactions of cobalt(III) amine complexes
Yoichi Kitamura, Geoffrey A. Lawrance, and Rudi Van Eldik
pp 333 - 338; DOI:
10.1021/ic00301a036
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Oxidative homolysis of pentaaquoorganochromium(III) cations induced by macrocyclic nickel(III) complexes
Tetsuo Katsuyama, Andreja Bakac, and James H. Espenson
pp 339 - 341; DOI:
10.1021/ic00301a037
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Competitive uncatalyzed geometrical isomerization and .beta.-hydride elimination of alkyl complexes of platinum(II)
Giuseppe Alibrandi, Matteo Cusumano, Domenico Minniti, Luigi Monsu Scolaro, and Raffaello Romeo
pp 342 - 347; DOI:
10.1021/ic00301a038
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Thermodynamic study of the formation in aqueous solution of cadmium(II) complexes with polyazacycloalkanes. Synthesis and crystal structure of the dicadmium(II) complex Na[Cd2(L)Cl2](ClO4)3 (L = 1,4,7,10,13,16,19,22,25,28-decaazacyclotriacontane)
Andrea Bencini, Antonio Bianchi, Manuel Castello, Massimo Di Vaira, Juan Faus, Enrique Garcia-Espana, Mauro Micheloni, and Piero Paoletti
pp 347 - 351; DOI:
10.1021/ic00301a039
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Copper(II) as a probe of the active centers of alkaline phosphatase
Ivano Bertini, Claudio Luchinat, Maria Silvia Viezzoli, Lucia Banci, Seymour H. Koenig, Helios T. Leung, and Joseph E. Coleman
pp 352 - 358; DOI:
10.1021/ic00301a040
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Crystal structure of a silver salt of the antibiotic lasalocid A: a dimer having an exact 2-fold symmetry
Il Hwan Suh, Katsuyuki Aoki, and Hiroshi Yamazaki
pp 358 - 362; DOI:
10.1021/ic00301a041
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Preparation and characterization of sulfur-capped trinuclear molybdenum(IV) complexes with Mo3O3S cores and of sulfur-bridged dinuclear molybdenum(V) complexes with Mo2O3S cores. Crystal and molecular structures of Ba[Mo3O3S(Hnta)3].10H2O and K2[Mo3O3S(cys)3].6H2O
Takashi Shibahara, Haruo Akashi, Shuichi Nagahata, Hiroshi Hattori, and Hisao Kuroya
pp 362 - 370; DOI:
10.1021/ic00301a042
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Triammineruthenium(II) complexes bound with the novel bridging ligand 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz)
Ronald Ruminski, Jaqueline Kiplinger, Timothy Cockroft, and Charles Chase
pp 370 - 373; DOI:
10.1021/ic00301a043
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Volume profiles for solvolysis reactions of sterically hindered diethylenetriamine complexes of palladium(II) in aqueous solution
J. J. Pienaar, M. Kotowski, and R. Van Eldik
pp 373 - 375; DOI:
10.1021/ic00301a044
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Pulse radiolysis studies on pertechnetate and perrhenate in aqueous media. Decay of the technetium(VI) transient
Karen Libson, James C. Sullivan, William A. Mulac, Sheffield Gordon, and Edward Deutsch
pp 375 - 377; DOI:
10.1021/ic00301a045
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High-pressure NMR kinetics. 36. 1H NMR kinetic study of dimethyl sulfoxide exchange on tetrakis(dimethyl sulfoxide)platinum(II) at variable temperature and pressure
Yves Ducommun, Lothar Helm, Andre E. Merbach, Bjoern Hellquist, and Lars I. Elding
pp 377 - 379; DOI:
10.1021/ic00301a046
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The nature of iridium(III) in aqueous alkaline medium. An oxygen-18-tracer study
Kenton R. Rodgers, Heinz Gamsjaeger, and R. Kent Murmann
pp 379 - 381; DOI:
10.1021/ic00301a047
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Reaction of intermediate-sized boranes with methylidenetriphenylphosphorane
Lawrence Barton, Pamela K. Rush, Tim Zhu, Peggy Nevels, and Mark H. Owens
pp 381 - 382; DOI:
10.1021/ic00301a048
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Synthesis of Cp2Ti[C.tplbond.CSi(CH3)3]2 and the synthesis and molecular structure of [Cp2TiC.tplbond.CSi(CH3)3]2
Gary L. Wood, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 382 - 384; DOI:
10.1021/ic00301a049
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Encapsulated phosphides: Ru8(CO)21(.mu.6-P)(.mu.4-PPh)(.mu.2-PPh2), a molecule with a six-coordinate phosphorus atom in a condensed cluster
Francoise Van Gastel, Nicholas J. Taylor, and Arthur J. Carty
pp 384 - 388; DOI:
10.1021/ic00301a050
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Issue 3


Kinked cyanide binding to iron in a highly hindered dicyano-iron(III)-basket-handle porphyrin complex
Michele Schappacher, Jean Fischer, and Raymond Weiss
pp 389 - 390; DOI:
10.1021/ic00302a001
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Identification of a soluble form of colloidal manganese(IV)
Joaquin F. Perez-Benito, Enrique Brillas, and Ramon Pouplana
pp 390 - 392; DOI:
10.1021/ic00302a002
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Solid-state chalcogenide anions of tantalum and niobium: synthesis and structures of the Ta2S114- and Nb4Se226- anions
Serge Schreiner, Lorraine E. Aleandri, Doris Kang, and James A. Ibers
pp 392 - 393; DOI:
10.1021/ic00302a003
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Bromide-assisted hydrogen peroxide disproportionation catalyzed by vanadium bromoperoxidase: absence of direct catalase activity and implications for the catalytic mechanism
Richard R. Everett and Alison Butler
pp 393 - 395; DOI:
10.1021/ic00302a004
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A general synthetic route to the dirhenium octahydrides Re2H8(PR3)4 from the triply bonded complexes Re2Cl4(PR3)4. An unexpected structure for the complex Re2H8(dppm)2 (dppm = Ph2PCH2PPh2)
Phillip E. Fanwick, Dawn R. Root, and Richard A. Walton
pp 395 - 397; DOI:
10.1021/ic00302a005
PDF
Chromium, molybdenum, and tungsten zerovalent complexes of the nitrogen chelating ligand 2-(phenylazo)pyridine (2-PAP), including air-stable cis-M(CO)2(2-PAP)2 and M(2-PAP)3
Martin N. Ackermann, Carolyn R. Barton, Charles J. Deodene, Elizabeth M. Specht, Sarah C. Keill, William E. Schreiber, and Hidong Kim
pp 397 - 403; DOI:
10.1021/ic00302a006
PDF
1,1'-Bis(diphenylphosphino)ferrocene complexes of platinum(II) and platinum(I). Crystal and molecular structure of [(L-L)Pt(.mu.-H)(.mu.-CO)Pt(L-L)][BF4].0.5H2O, where L-L = Fe(.eta.5-C5H4PPh2)2
Anna Laura Bandini, Guido Banditelli, Maria Agostina Cinellu, Gavino Sanna, Giovanni Minghetti, Francesco Demartin, and Mario Manassero
pp 404 - 410; DOI:
10.1021/ic00302a007
PDF
Infrared spectroscopic studies on metal carbonyl compounds. 24. Observation of the infrared spectrum of an acylrhodium tetracarbonyl during the hydroformylation of olefins with rhodium-containing catalyst precursors
Marc Garland and Gyorgy Bor
pp 410 - 413; DOI:
10.1021/ic00302a008
PDF
First examples of an isomeric methylene-bridged free phosphinomethylphosphoranimine and a metalated phosphinomethylphosphoranimine. Synthesis, characterization, and isomerization of the heterodifunctional ligand Me3SiN:P(Ph)2CH2PPh2 and the transmetalation to the titanium derivative (.eta.5-C5H5)Ti(Cl)2N:P(Ph)2CH2PPh2
Kattesh V. Katti and Ronald G. Cavell
pp 413 - 416; DOI:
10.1021/ic00302a009
PDF
Phase-transfer catalysts in extraction kinetics: palladium extraction by dioctyl sulfide and KELEX 100
S. J. Al-Bazi and Henry Freiser
pp 417 - 420; DOI:
10.1021/ic00302a010
PDF
The ferro/ferricyanide couple in an aluminum chloride-1-methyl-3-ethylimidazolium chloride ambient-temperature molten salt
B. Das, R. Carlin, and Robert A. Osteryoung
pp 421 - 426; DOI:
10.1021/ic00302a011
PDF
Coordination geometries of hexaamine cage complexes
Peter Comba
pp 426 - 431; DOI:
10.1021/ic00302a012
PDF
Intramolecular, base-induced formation of a metal-metal bond in [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2]3+ (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). Crystal structures of [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2](ClO4)3.cntdot.H2O and [L2MoIII2(.mu.-O)(.mu.-CH3CO2)2](ClO4)(BF4).cntdot.H2O and of the mixed-valence complex [L2MoIIIMoIV(.mu.-O)(.mu.-CH3CO2)2](ClO43.cntdot.H2O
Karl Wieghardt, Ursula Bossek, Ademir Neves, Bernhard Nuber, and Johannes Weiss
pp 432 - 440; DOI:
10.1021/ic00302a013
PDF
Five- and six-coordinate high-spin iron(III) porphyrin complexes with teflate (OTeF5-) ligands
Patti J. Kellett, Michael J. Pawlik, Lucille F. Taylor, Ronald G. Thompson, Mark A. Levstik, Oren P. Anderson, and Steven H. Strauss
pp 440 - 447; DOI:
10.1021/ic00302a014
PDF
(.mu.-Ethylenediaminetetraacetato)(.mu.-oxo)(.mu.-sulfido)bis(oxotungstate(V)): the first crystallographically characterized complex containing the W2(O)2(.mu.-O)(.mu.-S) unit
Shinji Ikari, Yoichi Sasaki, and Tasuku Ito
pp 447 - 451; DOI:
10.1021/ic00302a015
PDF
A ruthenium(III) analogue of the Udenfriend system: Ru(III)-EDTA-ascorbate-molecular oxygen in the effective oxygen atom transfer reaction of saturated and unsaturated organic compounds
M. M. Taqui Khan, R. S. Shukla, and A. Prakash Rao
pp 452 - 458; DOI:
10.1021/ic00302a016
PDF
(.mu.-Hydroxo)bis(.mu.-carboxylato)diruthenium and (.mu.-oxo)bis(.mu.-carboxylato)diruthenium Complexes Containing Weatk Intramolecular Ru.cntdot..cntdot..cntdot.Ru interactions
Peter Neubold, Karl Wieghardt, Bernhard Nuber, and Johannes Weiss
pp 459 - 467; DOI:
10.1021/ic00302a017
PDF
Syntheses, structures, and spectral properties of a synthetic analog of copper(II)-bleomycin and an intermediate in the process of its formation
Steven J. Brown, Samuel E. Hudson, Douglas W. Stephan, and Pradip K. Mascharak
pp 468 - 477; DOI:
10.1021/ic00302a018
PDF
Manganese(II) N,N'-dipyridoxylethylenediamine-N,N'-diacetate 5,5'-bis(phosphate). Synthesis and characterization of a paramagnetic chelate for magnetic resonance imaging enhancement
Scott M. Rocklage, William P. Cacheris, Steven C. Quay, F. Ekkehardt Hahn, and Kenneth N. Raymond
pp 477 - 485; DOI:
10.1021/ic00302a019
PDF
Evidence for the binding of bromide to mercury in organomercurial-protein complexes obtained by using bromine-81 magnetic resonance spectroscopy
Joseph J. Pesek and Faridah Abhanan
pp 485 - 487; DOI:
10.1021/ic00302a020
PDF
Cobalt-59 nuclear magnetic resonance studies of chloro-, bromo-, and iodo-substituted tris(acetylacetonato)cobalt(III) complexes
Scott C. Busse and Edwin H. Abbott
pp 488 - 491; DOI:
10.1021/ic00302a021
PDF
Preparation and characterization of alkali-metal (.alpha.-cyanoalkyl)trihydroborate-dioxane complexes
J. L. Peters, M. Mittakanti, T. J. Lofthouse, and K. W. Morse
pp 492 - 494; DOI:
10.1021/ic00302a022
PDF
Cocondensation reaction between phosphine and fluorine: matrix infrared spectra of difluorophosphorane, difluorophosphine and fluorophosphine
Lester Andrews and Robert Withnall
pp 494 - 499; DOI:
10.1021/ic00302a023
PDF
Reactivity of phosphonitriles with low-coordinated phosphorus double-bonded compounds
Juergen Boeske, Edgar Niecke, Martin Nieger, Edgar Ocando, Jean Pierre Majoral, and Guy Bertrand
pp 499 - 504; DOI:
10.1021/ic00302a024
PDF
Spin cluster excitations of titanium(2+)-manganese(2+) and manganese(2+)-titanium(2+)-manganese(2+) in magnesium chloride studied by site-selective optical spectroscopy
Markus Herren, Stuart M. Jacobsen, and Hans U. Guedel
pp 504 - 509; DOI:
10.1021/ic00302a025
PDF
Deformations in mixed-valence copper(I)-copper(II) polymers
Paul Sherwood and Roald Hoffmann
pp 509 - 518; DOI:
10.1021/ic00302a026
PDF
Reactivity of Fe(CO)4(H)MPh3 (M = Si, Ge) and mechanism of substitution by two-electron-donor ligands: implications for the mechanism of hydrosilylation of olefins catalyzed by iron pentacarbonyl
Gianfranco Bellachioma, Giuseppe Cardaci, Ernest Colomer, Robert J. P. Corriu, and Andre Vioux
pp 519 - 525; DOI:
10.1021/ic00302a027
PDF
Rate law and product distribution for the nitrosation of pentaammineazidocobalt(2+) revisited
W. G. Jackson and B. H. Dutton
pp 525 - 531; DOI:
10.1021/ic00302a028
PDF
Formation of racemic and meso isomers of mono- and dihydroxo-bridged dinuclear ions by hydrolysis of the cis-aquahydroxobis(1,2-ethanediamine)rhodium(III) ion
Morten J. Bjerrum, Karen Kaas, Erik Larsen, Bente Nielsen, and Johan Springborg
pp 532 - 538; DOI:
10.1021/ic00302a029
PDF
Octahedral metal carbonyls. 66. Rates and mechanism of chelate ring displacement from tetracarbonyltungsten complexes of dithiaalkanes forming seven- and eight-membered chelating rings
Gerard R. Dobson and Jose E. Cortes
pp 539 - 544; DOI:
10.1021/ic00302a030
PDF
Natural bond orbital (NBO) analysis of substituent effects in borazine derivatives
Joel T. Nelson and William J. Pietro
pp 544 - 548; DOI:
10.1021/ic00302a031
PDF
Hard ligands as donors to soft metals. 4. Cationic bis(solvent) complexes of palladium(II) and platinum(II) containing monodentate tertiary phosphine ligands
Frank R. Hartley, Stephen G. Murray, and Alan Wilkinson
pp 549 - 554; DOI:
10.1021/ic00302a032
PDF
Selective oxidations of olefins catalyzed by platinum(II) complexes. Use of tert-butyl hydroperoxide and potassium caroate as oxidants: ketone vs epoxide formation
Giorgio Struku, Riccardo Sinigalia, Andrea Zanardo, Francesco Pinna, and Rino A. Michelin
pp 554 - 559; DOI:
10.1021/ic00302a033
PDF
Effects of replacing oxygen by sulfur at the endogenous bridging center on the redox properties of binuclear copper(II) complexes
Alan M. Bond, Masaaki Haga, Ian S. Creece, Richard Robson, and Jenny C. Wilson
pp 559 - 566; DOI:
10.1021/ic00302a034
PDF
Oxidation-reduction of carbonylcobalt cation-anion pairs in coupling to dimeric cobalt carbonyls
K. Y. Lee and J. K. Kochi
pp 567 - 578; DOI:
10.1021/ic00302a035
PDF
Reactions of the 17-electron bis(dimethylglyoximato)(triphenylphosphine)rhodium(II) radical with cobalt(III) complexes
Kevin R. Howes, Andreja Bakac, and James H. Espenson
pp 579 - 581; DOI:
10.1021/ic00302a036
PDF
Reactions of sulfur dioxide with photochemically generated polypyridyl complexes of chromium(II). Calculation of the sulfur dioxide/sulfur dioxide radical anion self-exchange rate constant
Carol A. Simmons, Andreja Bakac, and James H. Espenson
pp 581 - 584; DOI:
10.1021/ic00302a037
PDF
Kinetics of silver(I)-catalyzed oxidation of formic acid by the (ethylenebis(biguanidine))silver(III) cation in acid perchlorate media
Rupendranath Banerjee, Kaushik Das, Amitava Das, and Subrata Dasgupta
pp 585 - 588; DOI:
10.1021/ic00302a038
PDF
Iron porphyrin models of peroxidase enzyme intermediates: the hypochlorite oxidation of deuteroferriheme
Ricardo E. Rodriguez and Henry C. Kelly
pp 589 - 593; DOI:
10.1021/ic00302a039
PDF
Experimental and theoretical study of tetrakis(di-p-tolylformamidinato)dimolybdenum and [Mo2(form)4]+ (form- = [(p-tol)NCHN(p-tol)]-)
F. Albert Cotton, Xuejun Feng, and Marek Matusz
pp 594 - 601; DOI:
10.1021/ic00302a040
PDF
Electron self-exchange of hexakis(2,6-diisopropylphenyl isocyanide) chromium(0,I) in dichloromethane
Kim A. Anderson and Scot Wherland
pp 601 - 604; DOI:
10.1021/ic00302a041
PDF
Pressure and temperature effects on the ruthenocene/bromoruthenocene electron self-exchange in deuterated acetonitrile
Karl Kirchner, Harold W. Dodgen, Scot Wherland, and John P. Hunt
pp 604 - 605; DOI:
10.1021/ic00302a042
PDF
Reactions of an azidoborane with phosphines: synthesis of (borylimino)phosphoranes
Bei Li Li, Purnendu Mukherjee, and Robert H. Neilson
pp 605 - 607; DOI:
10.1021/ic00302a043
PDF
Undesirable reactions in bleomycin biomimetic catalysis systems caused by iodosobenzene
Richard S. Magliozzo and Jack Peisach
pp 608 - 611; DOI:
10.1021/ic00302a044
PDF
Detailed study of the quintet .dblharw. singlet spin transition in bis(selenocyanato)bis(2,2'-bi-2-thiazoline) iron(II)
E. Koenig, G. Ritter, J. Dengler, and J. Nelson
pp 611 - 613; DOI:
10.1021/ic00302a045
PDF
The ternary system magnesium-cobalt-hydrogen
E. Yu. Ivanov, I. G. Konstanchuk, A. A. Stepanov, Yan Jie, M. Pezat, and B. Darriet
pp 613 - 615; DOI:
10.1021/ic00302a046
PDF
Synthesis, structure, and physical properties of tetrakis(.mu.-diphenyl phosphato)dimolybdenum(II)
Janet R. Morrow and William C. Trogler
pp 615 - 618; DOI:
10.1021/ic00302a047
PDF
Solid-state structure of [Li(.mu.-OAr-2,6-Ph2)3Sn] (OAr-2,6-Ph2 = 2,6-diphenylphenoixde): a cage compound containing a pyramidal lithium atom
Glen D. Smith, Phillip E. Fanwick, and Ian P. Rothwell
pp 618 - 620; DOI:
10.1021/ic00302a048
PDF
Synthesis and characterization of the gadolinium(3+) complex of DOTA-propylamide: a model DOTA-protein conjugate
A. Dean Sherry, Rodney D. Brown, Carlos F. G. C. Geraldes, Seymour H. Koenig, Kah-Tiong Kuan, and Marga Spiller
pp 620 - 622; DOI:
10.1021/ic00302a049
PDF

Issue 4


P-Phenylenediimido complexes of rhenium(V) and their coupling reactions: novel multimetallic chains
Eric A. Maatta and Changmin Kim
pp 623 - 624; DOI:
10.1021/ic00303a001
PDF
Structure of an L-tyrosyl-L-histidine-copper complex involving an axial copper(II)-phenol OH bonding. Implication for substrate binding at the active site of tyrosinase
Hideki Masuda, Akira Odani, and Osamu Yamauchi
pp 624 - 625; DOI:
10.1021/ic00303a002
PDF
New layered phases achieved with centered zirconium chloride clusters. The stoichiometry Zr6Cl16
Robin P. Ziebarth and John D. Corbett
pp 626 - 631; DOI:
10.1021/ic00303a003
PDF
Encapsulation of heavy transition metals in iodide clusters. Synthesis, structure, and bonding of the unusual cluster phase yttrium iodide-ruthenium (Y6I10Ru)
Timothy Hughbanks and John D. Corbett
pp 631 - 635; DOI:
10.1021/ic00303a004
PDF
Iodine-127 Moessbauer studies of oxygen-bonded iodine complexes. 1. Tris(carboxylato)iodine(III) derivatives. Crystal and molecular structure of tris(acetato)iodine(III)
Thomas Birchall, Christopher S. Frampton, and Pratibha Kapoor
pp 636 - 639; DOI:
10.1021/ic00303a005
PDF
Electronic calculations of large copper oxide clusters
R. C. Baetzold
pp 640 - 644; DOI:
10.1021/ic00303a006
PDF
Divalent rhenium coordination to two radical Schiff-base quinone ligands
Lynn A. DeLearie, R. Curtis Haltiwanger, and Cortlandt G. Pierpont
pp 644 - 650; DOI:
10.1021/ic00303a007
PDF
Mixed-metal selenides: synthesis and characterization of the (diselenido)(tetraselenotungstato)nickelate(2-) and bis(tetraselenotungstato)metalate(2-) (metal = nickel, palladium) anions
Mohammad A. Ansari, Chung Nin Chau, Charles H. Mahler, and James A. Ibers
pp 650 - 654; DOI:
10.1021/ic00303a008
PDF
Synthesis of a novel macrobicyclic ligand, 15-thia-1,5,8,12-tetraazabicyclo[10.5.2]nonadecane, and its nickel(II) and copper(II) complexes. X-ray crystal structures of [Cu(L1)](ClO4)2 and [Ni(L1)(ClO4)]ClO4
D. G. Fortier and Alex McAuley
pp 655 - 662; DOI:
10.1021/ic00303a009
PDF
Silver(II) complexes of hindered N-heterocyclic ligands. Electron spin resonance of nitrato(6,6'-dimethyl-2,2'-bipyridine)silver(II) and nitrato(2,9-dimethyl-1,10-phenanthroline)silver(II) ions
G. Swarnabala and M. V. Rajasekharan
pp 662 - 666; DOI:
10.1021/ic00303a010
PDF
Microwave spectra and molecular structures of 3H-3-azacyclotriboroxane and 3-oxacyclotriborazane
Yoshiyuki Kawashima, Harutoshi Takeo, and Chi Matsumura
pp 666 - 669; DOI:
10.1021/ic00303a011
PDF
Thermal rearrangement studies on ethyl and chloro diethyl derivatives of closo-2,4-C2B5H7: elimination of a 1,2-substituent-shift mechanistic hypothesis and further support of the DSD cage rearrangement mechanism
Wonwoo Nam, Zahid J. Abdou, Han Lee, Tereso Banuelos, and Thomas Onak
pp 669 - 675; DOI:
10.1021/ic00303a012
PDF
Reactions of chlorine fluorides and oxyfluorides with the nitrate anion and alkali metal fluoride catalyzed decomposition of chlorine pentafluoride
Karl O. Christe, William W. Wilson, and Richard D. Wilson
pp 675 - 677; DOI:
10.1021/ic00303a013
PDF
A trinucleating oxygen-containing ligand with two different coordination sites and its heterotrinuclear complexes
F. Teixidor, J. Colomer, J. Casabo, J. Rius, E. Molins, and C. Miravitlles
pp 678 - 681; DOI:
10.1021/ic00303a014
PDF
Phosphoranide ligands with variable coordination modes. Synthesis, properties, and x-ray crystal structures of (.eta.2-8bH-2a,4a,6a,8a-tetraaza-8b-phosphapentaleno[1,bcd]pentalene)chloro(triphenylphosphine)platinum(IV) tetrafluoroborate and [(H2cyclenP)PtCl2PPh3]Cl
Dilip V. Khasnis, Michael Lattman, and Upali Siriwardane
pp 681 - 686; DOI:
10.1021/ic00303a015
PDF
Steric, inductive, and ring-strain effects in chelation thermodynamics and kinetics: reactions of copper(II) ion with N-alkyl-substituted diamino diamides
Min Shiun Chao and Chung Sun Chung
pp 686 - 692; DOI:
10.1021/ic00303a016
PDF
Chelating ditelluroether complexes of palladium and platinum: synthesis and multinuclear NMR studies. Structure of dibromo(meso-1,3-bis(phenyltelluro)propane)palladium(II): [Pd{meso-PhTe(CH2)3TePh}Br2]
Tim Kemmitt, William Levason, and Michael Webster
pp 692 - 696; DOI:
10.1021/ic00303a017
PDF
Synthesis and molecular and electronic structure of stable salts containing the radical anions [Fe4(CO)12CC(O)R]2- (R = CH3, CH2C6H5)
Jiandang Wang, Ann M. Crespi, Michal Sabat, Suzanne Harris, Carrie Woodcock, and Duward F. Shriver
pp 697 - 703; DOI:
10.1021/ic00303a018
PDF
Cluster synthesis. 24. Synthesis and characterization of new sulfur-containing tungsten-iron carbonyl cluster complexes
Richard D. Adams, James E. Babin, Jin Guu Wang, and Wengan Wu
pp 703 - 709; DOI:
10.1021/ic00303a019
PDF
Direct evidence of heme-tert-butyl peroxide adduct formation demonstrated by simultaneous ESR and optical measurements
Kunihiko Tajima, Junichi Jinno, Kazuhiko Ishizu, Hiromu Sakurai, and Hiroaki Ohya-Nishiguchi
pp 709 - 715; DOI:
10.1021/ic00303a020
PDF
Metal chelation with natural products: isomaltol complexes of aluminum, gallium, and indium
Tammy G. Lutz, David J. Clevette, Steven J. Rettig, and Chris Orvig
pp 715 - 719; DOI:
10.1021/ic00303a021
PDF
Oxoperoxo(citrato)- and dioxo(citrato)vanadates(V): synthesis, spectra, and structure of a hydroxyl oxygen bridged dimer K2[VO(O2)(C6H6O7)]2.2H2O
Cirila Djordjevic, Myunghi Lee, and Ekk Sinn
pp 719 - 723; DOI:
10.1021/ic00303a022
PDF
Synthesis and chemical characterization of complexes containing semiquinone units bridged by pentaoxodimolybdate groups. Structural and electrochemical studies of [(n-C4H9)4N]2[Mo4O10(C6H2O4)2] and [(n-C4H9)4N]3[Mo6O15(C6O6)2] and of an analogous tetraoxydibenzofuran complex, [(n-C4H9)4N]2[Mo4O10(C12H4O5)2], prepared from metal-mediated radical coupling of 1,2,4-trihydroxybenzene precursors
Shuncheng Liu, Shahid N. Shaikh, and Jon Zubieta
pp 723 - 732; DOI:
10.1021/ic00303a023
PDF
Systematic design of chemical oscillators. 47. Kinetics and mechanism of the oxidation of hexacyanoferrate(II) by bromate
Gyula Rabai and Irving R. Epstein
pp 732 - 736; DOI:
10.1021/ic00303a024
PDF
Kinetics of the acid dissociation of oligopeptide complexes of copper(II) and nickel(II): a study on general-acid catalysis with "noncoordinating" 2,6-lutidine type buffers
Maria Hauroeder, Monika Schuetz, Klaus J. Wannowius, and Horst Elias
pp 736 - 742; DOI:
10.1021/ic00303a025
PDF
Spectroscopic studies of cyclometalated palladium(II) complexes: optical absorption and emission of single-crystal cis-bis(benzo[h]quinolinato)palladium(II)
R. Schwarz, G. Gliemann, P. Jolliet, and A. Von Zelewsky
pp 742 - 746; DOI:
10.1021/ic00303a026
PDF
Electronic, infrared, Raman, and resonance Raman spectra of the dirhodium tetracarboxylate complexes Rh2(O2CR)4(PPh3)2 (R = H, CH3, C2H5, C3H7)
Robin J. H. Clark and Andrew J. Hempleman
pp 746 - 752; DOI:
10.1021/ic00303a027
PDF
Analysis of the vibrational fine structure in the electronic spectrum of the planar tetrachlorocuprate(II) ion in N-(2-ammonioethyl)morpholinium tetrachlorocuprate(II): evidence for a pseudo tetrahedral distortion in the 2A1g excited electronic state
Robbie G. McDonald, Mark. J. Riley, and Michael A. Hitchman
pp 752 - 758; DOI:
10.1021/ic00303a028
PDF
Intervalence transfer in pentammineruthenium complexes of .alpha.,.omega.-dipyridyl polyenes
S. Woitellier, J. P. Launay, and C. W. Spangler
pp 758 - 762; DOI:
10.1021/ic00303a029
PDF
Properties of atoms in molecules: krypton and xenon and their bonds to nitrogen and fluorine in hydrogen cyanide complexes with noble gas fluorides, HCN-NgF+, NgF+ and NgF2 (Ng = noble gas)
Preston J. MacDougall, Gary J. Schrobilgen, and Richard F. W. Bader
pp 763 - 769; DOI:
10.1021/ic00303a030
PDF
Ab initio study of progressive ligand substitution in octahedral transition-metal complexes
L. G. Vanquickenborne, M. Hendrickx, and I. Hyla-Kryspin
pp 770 - 773; DOI:
10.1021/ic00303a031
PDF
Synthesis, structure, and electronic properties of tris(propane-1,3-dithiolato) and tris(ethylene-1,2-dithiolato) complexes of niobium(V) and tantalum(V)
Kazuyuki Tatsumi, Ichiro Matsubara, Yoitsu Sekiguchi, Akira Nakamura, and Carlo Mealli
pp 773 - 780; DOI:
10.1021/ic00303a032
PDF
Synthesis, structure, and spectroscopic properties of octahedral complexes of tungsten(VI), -(V), and -(IV) containing 2,6-diphenylphenoxide ligation
Judith L. Kerschner, Phillip E. Fanwick, Ian P. Rothwell, and John C. Huffman
pp 780 - 786; DOI:
10.1021/ic00303a033
PDF
Photosubstitution reactions of terpyridine complexes of ruthenium(II)
Huey Fen Suen, S. W. Wilson, M. Pomerantz, and J. L. Walsh
pp 786 - 791; DOI:
10.1021/ic00303a034
PDF
Rapid, high-resolution, reversed-phase HPLC separation of highly charged polyoxometalates using ion-interaction reagents and competing ions
A. D. Kirk, W. Riske, R. G. Finke, D. K. Lyon, and B. Rapko
pp 792 - 797; DOI:
10.1021/ic00303a035
PDF
Synthesis and chemistry of (.eta.3-pentadienyl)iron tricarbonyl halides
Gregory M. Williams and Duane E. Rudisill
pp 797 - 800; DOI:
10.1021/ic00303a036
PDF
Synthesis and characterization of air-stable chromium(II) complexes with 1,4,8,11-tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane
Eiji Asato, Sigeo Kida, and Ichiro Murase
pp 800 - 802; DOI:
10.1021/ic00303a037
PDF
Spectroscopic characterization of cobalt(II)-substituted Achromobacter pseudoazurin: similarity of the metal center in Co(II)-pseudoazurin to those in Co(II)-plastocyanin and Co(II)-plantacyanin
Shinnichiro Suzuki, Takeshi Sakurai, Sohsuke Shidara, and Hidekazu Iwasaki
pp 802 - 804; DOI:
10.1021/ic00303a038
PDF
Reactions of N,N'-dimethylurea with boron-nitrogen compounds
L. Komorowski and Kurt Niedenzu
pp 804 - 806; DOI:
10.1021/ic00303a039
PDF
Synthesis and characterization of the organozirconium and organohafnium complexes [(.eta.5-C5Me5)MCl]3O(OH)3Cl and [(.eta.5-C5Me5)MCl]3O(OH)4
Laura M. Babcock, Victor W. Day, and Walter G. Klemperer
pp 806 - 810; DOI:
10.1021/ic00303a040
PDF
Synthesis, structure, and magnetic properties of a dodecamanganese(II) complex afforded by a binucleating acyclic N2O3 Schiff base [Erratum to document cited in CA109(22):203743M]
Dominique Luneau, Jean Michel Savariault, and Jean Pierre Tuchagues
pp 810 - 810; DOI:
10.1021/ic00303a041
PDF
Crystal structures of three phases of tetramethylammonium trichlorocuprate(II) (TMCuC) [Erratum to document cited in CA108(10):85593S]
Roger D. Willett, Marcus R. Bond, W. G. Haije, O. P. M. Soonieus, and W. J. A. Maaskant
pp 810 - 810; DOI:
10.1021/ic00303a042
PDF

Issue 5


Synthesis and x-ray structure of the first dinuclear homoleptic chromium(II) amide, {[(iso-Pr)2N]Cr[.mu.-(iso-Pr)2N]}2
Jilles J. H. Edema, Sandro Gambarotta, and Anthony L. Spek
pp 811 - 812; DOI:
10.1021/ic00304a001
PDF
Use of bis(2,2'-bipyridyl-d8)ruthenium(II) dichloride to facilitate NMR structural assignments in complexes with diimine ligands
Sara Chirayil and Randolph P. Thummel
pp 812 - 813; DOI:
10.1021/ic00304a002
PDF
Photoelimination of benzoyl chloride from (benzoyl)chlorobis(triphenylphosphine)palladium(II) and -platinum(II)
Mitsuru Kubota, Robert N. Keil, and Keith A. Hall
pp 813 - 814; DOI:
10.1021/ic00304a003
PDF
Reaction of the cis-diamminediaquaplatinum(II) cation with N-acetylglycine
Trevor G. Appleton, John R. Hall, and Paul D. Prenzler
pp 815 - 819; DOI:
10.1021/ic00304a004
PDF
Inhibition of phosphoryl-transferring enzymes by aluminum-ATP
Norbert C. Furumo and Ronald E. Viola
pp 820 - 823; DOI:
10.1021/ic00304a005
PDF
Synthesis and proton NMR studies of the electronic and magnetic properties of low-spin ferric isocyanide tetraphenylporphyrin complexes
G. Simonneaux, F. Hindre, and M. Le Plouzennec
pp 823 - 825; DOI:
10.1021/ic00304a006
PDF
Resonance Raman spectroscopy of iron(II) superstructured porphyrins: influence of porphyrin distortions on carbonyl and dioxygen ligand dissociation
Alain Desbois, Michel Momenteau, and Marc Lutz
pp 825 - 834; DOI:
10.1021/ic00304a007
PDF
Synthesis and characterization of technetium(V) complexes with N-(thiocarbamoyl)benzamidines. X-ray crystal structure of bis[N-(N,N-diethylthiocarbamoyl)benzamidinato]oxotechnetium(V) chloride, [TcO(et2tcb)2]Cl
U. Abram, R. Muenze, J. Hartung, L. Beyer, R. Kirmse, K. Koehler, J. Stach, H. Behm, and P. T. Beurskens
pp 834 - 839; DOI:
10.1021/ic00304a008
PDF
Electrophilic cleavage of carbon-fluorine bonds in hydrido trifluoromethyl complexes of platinum(II) by proton acids. Synthesis of hydrido carbene and hydrido carbonyl derivatives and x-ray structures of trans-PtH(CF3)(PPh3)2 (180 K) and trans-[PtH[cyclic](COCH2CH2O)(PPh3)2]BF4 (298 K)
Rino A. Michelin, Renzo Ros, Giuseppe Guadalupi, Gabriella Bombieri, Franco Benetollo, and Gervais Chapuis
pp 840 - 846; DOI:
10.1021/ic00304a009
PDF
"Chelate-assisted" oxidative addition of the carbon-sulfur bond in 8-quinoline thioesters to chlorotris(triphenylphosphine)rhodium
Alan Shaver, Haewon L. Uhm, Eric Singleton, and David C. Liles
pp 847 - 851; DOI:
10.1021/ic00304a010
PDF
Temperature, pressure, and viscosity dependence of outer-sphere electron-transfer processes. Reduction of aquapentaamminecobalt(III) by hexacyanoferrate(II)
I. Krack and Rudi Van Eldik
pp 851 - 855; DOI:
10.1021/ic00304a011
PDF
Equilibrium of 17-electron and 19-electron organometallic radicals derived from carbonylmanganese anions and cations
D. J. Kuchynka and J. K. Kochi
pp 855 - 863; DOI:
10.1021/ic00304a012
PDF
Electrocatalytic reduction of nitrate in sodium hydroxide solution in the presence of low-valent cobalt-cyclam species
Hu Lin Li, William C. Anderson, James Q. Chambers, and David T. Hobbs
pp 863 - 868; DOI:
10.1021/ic00304a013
PDF
Solvent effects on the long-axis intraligand transition of tris(2,2'-bipyridine)ruthenium(2+) and related compounds
Steven J. Milder
pp 868 - 872; DOI:
10.1021/ic00304a014
PDF
Electronic structure of platinum complexes (.eta.5-C5H5)Pt(CH3)3 and (.eta.5-C5(CH3)5)Pt(CH3)3 from UV photoelectron spectra
D. S. Yang, G. M. Bancroft, R. J. Puddephatt, B. E. Bursten, and S. D. McKee
pp 872 - 877; DOI:
10.1021/ic00304a015
PDF
Transverse and longitudinal Zeeman effect on [tetraphenylphosphonium tetrachloroferrate(1-)]: assignment of the ligand field transitions and the origin of the 6A1 ground-state zero-field splitting
Joseph C. Deaton, Matthew S. Gebhard, and Edward I. Solomon
pp 877 - 889; DOI:
10.1021/ic00304a016
PDF
Excited-state properties of dioxorhenium(V). Generation and reactivity of dioxorhenium(VI)
H. Holden Thorp, J. Van Houten, and Harry B. Gray
pp 889 - 892; DOI:
10.1021/ic00304a017
PDF
5-(Perfluoroalkyl)tetrazoles: .eta.5 ligands in solution and .mu.-2,3-.eta.2 ligands in solid complexes
Earnest Obed John, Roger D. Willett, Brian Scott, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 893 - 897; DOI:
10.1021/ic00304a018
PDF
Synthesis and characterization of cyanoborane adducts of dialkyl ((dialkylamino)methyl)phosphonates
M. P. Kaushik, M. R. M. D. Charandabi, M. L. Ettel, T. J. Lofthouse, and Karen W. Morse
pp 897 - 899; DOI:
10.1021/ic00304a019
PDF
Addition reactions of a silylated imino(methylene)phosphorane
Donn A. DuBois and Robert H. Neilson
pp 899 - 903; DOI:
10.1021/ic00304a020
PDF
Fluorine-oxygen exchange reactions in iodine pentafluoride, iodine heptafluoride, and iodine pentafluoride oxide
Karl O. Christe, William W. Wilson, and Richard D. Wilson
pp 904 - 908; DOI:
10.1021/ic00304a021
PDF
Calorimetric studies of americium(III) complexation by amino carboxylates
E. N. Rizkalla, J. C. Sullivan, and Gregory R. Choppin
pp 909 - 911; DOI:
10.1021/ic00304a022
PDF
Synthesis and characterization of mononuclear and dinuclear bis(2,2'-bipyridine)ruthenium(II) complexes containing sulfur-donor ligands
M. A. Greaney, C. L. Coyle, M. A. Harmer, A. Jordan, and E. I. Stiefel
pp 912 - 920; DOI:
10.1021/ic00304a023
PDF
Synthesis and structural investigation of polyoxomolybdate coordination compounds displaying a tetranuclear core. Crystal and molecular structures of [Bu4N]2[Mo4O10(OMe)2(OC6H4O)2] and to the diazenido complexes [Bu4N]2[Mo4O6(OMe)2(HNC6H4O)2(NNC6H5)4] and [Bu4N]2[Mo4O6(OMe)2(C10H6O2)2(NNC6H5)4]. Comparison to a binuclear complex with the [Mo2(OMe)2(NNC6H5)4]2+ core, [Mo2(OMe)2(H2NC6H4O)]
Hyunkyu Kang, Shuncheng Liu, Shahid N. Shaikh, Terrence Nicholson, and Jon Zubieta
pp 920 - 933; DOI:
10.1021/ic00304a024
PDF
Crystal structure and properties of the rare-earth-metal rhodium carbides R8Rh5C12 (R = yttrium, gadolinium-thulium)
Rolf Dieter Hoffmann, Wolfgang Jeitschko, Manfred Reehuis, and Stephen Lee
pp 934 - 938; DOI:
10.1021/ic00304a025
PDF
Bis(2,2'-bipyridine)bis(isothiocyanato)ruthenium. Solvate (solvate = acetonitrile, DMSO) and related compounds: crystal structure, VTFTIR and NMR study
R. H. Herber, Guijuan Nan, J. A. Potenza, H. J. Schugar, and A. Bino
pp 938 - 942; DOI:
10.1021/ic00304a026
PDF
Photoelectron spectra and molecular properties. 112. Photoelectron and photoionization mass spectra of the fluoroamines NH3-nFn
H. Baumgaertel, H. W. Jochims, E. Ruehl, H. Bock, R. Dammel, J. Minkwitz, and R. Nass
pp 943 - 949; DOI:
10.1021/ic00304a027
PDF
Alkene epoxidation by ruthenium(II) phosphine complexes. A kinetic investigation
Mario Bressan and Antonino Morvillo
pp 950 - 953; DOI:
10.1021/ic00304a028
PDF
Oxidation of hexaaquairidium(III) and related studies: preparation and properties of iridium(III), iridium(IV), and iridium(V) dimers as aqua ions
Sylvia E. Castillo-Blum, David T. Richens, and A. Geoffrey Sykes
pp 954 - 960; DOI:
10.1021/ic00304a029
PDF
Metal atom synthesis of metallaboron clusters. 11. Synthesis and characterization of (.eta.-C5R5) cobaltathiaborane clusters (R = H, Me)
Sang Ook Kang, Patrick J. Carroll, and Larry G. Sneddon
pp 961 - 964; DOI:
10.1021/ic00304a030
PDF
Synthesis and x-ray structure analysis of the tetracapped octahedral ruthenium carbido cluster [N(PPh3)2]2[Ru10C(CO)24]
Teiji Chihara, Ryuhei Komoto, Kimiko Kobayashi, Hiroshi Yamazaki, and Yoshiki Matsuura
pp 964 - 967; DOI:
10.1021/ic00304a031
PDF
Electron-transfer series of gold clusters: PtAu8(PPh3)82+/+/0, Au9[P(p-MeOC6H4)3]83+/2+/+, and Au9(PPh3)83+/2+/+
Johannes G. M. Van der Linden, Annie M. Roelofsen, and Gerard H. W. Ipskamp
pp 967 - 970; DOI:
10.1021/ic00304a032
PDF
Kinetics of the reduction of cobalt(III) amine complexes by 1-hydroxy-1-methylethyl radicals
Keiji Kusaba, Hiroshi Ogino, Andreja Bakac, and James H. Espenson
pp 970 - 972; DOI:
10.1021/ic00304a033
PDF
Singlet oxygen production by energy transfer from the chromium complex Cr(tacn)(NCS)3, (tacn = 1,4,7-triazacyclononane)
Alexander David Kirk, C. Namasivayam, William Riske, and Dusan Ristic-Petrovic
pp 972 - 974; DOI:
10.1021/ic00304a034
PDF
Comparison of subnanosecond transients from cobalt(III) linkage isomers: ligand field triplets versus the radical pair
A. D. Kirk, C. H. Langford, and D. K. Sharma
pp 974 - 975; DOI:
10.1021/ic00304a035
PDF
Mechanistic information on base hydrolysis and base-promoted linkage isomerization reactions of chromium(III) amine complexes from volumes of activation
Pilar Guardado, Geoffrey A. Lawrance, and Rudi Van Eldik
pp 976 - 978; DOI:
10.1021/ic00304a036
PDF
Rate constants for the scavenging of tris(bipyridine)ruthenium(3+) by EDTA in aqueous solution
Morton Z. Hoffman
pp 978 - 980; DOI:
10.1021/ic00304a037
PDF
The synthesis of tetrakis(trifluoromethyl)lead
Timothy J. Juhlke, Jeffrey I. Glanz, and Richard J. Lagow
pp 980 - 981; DOI:
10.1021/ic00304a038
PDF
Time-dependent photoselection results for ruthenium(II) diimine complexes
M. K. De Armond and M. L. Myrick
pp 981 - 982; DOI:
10.1021/ic00304a039
PDF
Synthesis of (1,2-benzenediolato(2-)-O,O')oxobis(1-piperidinolato(1-)-O,N)molybdenum(VI), [MoO(C5H10NO)2(C6H4O2)], and structure determination by correlated proton-carbon-13 two-dimensional NMR spectroscopy and x-ray crystallography [Erratum to document cited in CA103(24):204757g]
Stuart Bristow, John H. Enemark, C. David Garner, Martin Minelli, Gareth A. Morris, and Richard B. Ortega
pp 982 - 982; DOI:
10.1021/ic00304a040
PDF

Issue 6


Coenzyme B12 dependent diol dehydratase model studies: chemical evidence against cobalt(B12) participation in the rearrangement step
Yun Wang and Richard G. Finke
pp 983 - 986; DOI:
10.1021/ic00305a001
PDF
Nonmetal redox kinetics: hypochlorite and hypochlorous acid reactions with sulfite
Kimber D. Fogelman, Dennis M. Walker, and Dale W. Margerum
pp 986 - 993; DOI:
10.1021/ic00305a002
PDF
Kinetics of dissociation of trivalent actinide chelates of trimethylenediamine-N,N,N',N'-tetraacetic acid [TMDTA]
Anthony C. Muscatello, Gregory R. Choppin, and Willem D'Olieslager
pp 993 - 997; DOI:
10.1021/ic00305a003
PDF
Conformational interconversion rates of 1,2-diamine chelates: determination by paramagnetic NMR spectra of low-spin iron(III) complexes
Yoshitaka Kuroda, Noriko Tanaka, Masafumi Goto, and Tomoya Sakai
pp 997 - 1003; DOI:
10.1021/ic00305a004
PDF
Energetics of metal complex isomerization reactions
Brian F. G. Johnson and Alison Rodger
pp 1003 - 1006; DOI:
10.1021/ic00305a005
PDF
FT-IR and 2-D NOE phosphorus-31 NMR spectroscopic studies on stereochemically nonrigid, octahedral organochromium(0) complexes
Ashraf A. Ismail, Francoise Sauriol, and Ian S. Butler
pp 1007 - 1012; DOI:
10.1021/ic00305a006
PDF
Photosubstitution in tris chelate complexes of ruthenium(II) containing the ligands 2,2'-bipyrazine, 2,2'-bipyrimidine, 2,2'-bipyridine, and 4,4'-dimethyl-2,2'-bipyridine: energy gap control
Helen B. Ross, Massoud Boldaji, D. Paul Rillema, Charles B. Blanton, and Russell P. White
pp 1013 - 1021; DOI:
10.1021/ic00305a007
PDF
Complexes of ruthenium(II) with (2,2'-bipyrimidine)tricarbonylchlororhenium and {benzo[1,2-6:3,4-b':5,6-b"]tripyrazine}hexacarbonyldichloridirhenium as ligands: syntheses and redox and luminescence properties
Ram Sahai, D. Paul Rillema, Randy Shaver, Shawn Van Wallendael, Donald C. Jackman, and Massoud Boldaji
pp 1022 - 1028; DOI:
10.1021/ic00305a008
PDF
Crystal structures and solution electronic absorption and MCD spectra for perchlorate and halide salts of binuclear gold(I) complexes containing bridging Me2PCH2PMe2 (dmpm) or Me2PCH2CH2PMe2 (dmpe) ligands
Huey Rong C. Jaw, M. Meral Savas, Robin D. Rogers, and W. Roy Mason
pp 1028 - 1037; DOI:
10.1021/ic00305a009
PDF
Moessbauer study and nonlinear excitations in the antiferromagnetic chain of rubidium manganese iron fluoride hydrate [Rb2Mn1-xFexF5.cntdot.H2O (x.ltoreq.0.50)
Juergen Pebler
pp 1038 - 1044; DOI:
10.1021/ic00305a010
PDF
Color and electronic structure of manganese(V) and manganese(VI) in tetrahedral oxo coordination. A spectroscopic investigation
Herbert Lachwa and Dirk Reinen
pp 1044 - 1053; DOI:
10.1021/ic00305a011
PDF
Spectroscopic studies of cyclometalated platinum(II) complexes: optical absorption and emission of single-crystal cis-bis(benzo[h]quinolinato)platinum(II)
R. Schwarz, G. Gliemann, P. Jolliet, and A. Von Zelewsky
pp 1053 - 1059; DOI:
10.1021/ic00305a012
PDF
EPR-derived electronic characteristics of zerovalent manganese carbonyl di(tertiary phosphine) radicals
Gail B. Rattinger, R. Linn Belford, Howard Walker, and T. L. Brown
pp 1059 - 1066; DOI:
10.1021/ic00305a013
PDF
Heat capacity and phase transition of the mixed-valence compound, hexakis(acetato)oxotris(pyridine)triiron chloroform solvate
Yuki Kaneko, Motohiro Nakano, Michio Sorai, Ho G. Jang, and David N. Hendrickson
pp 1067 - 1073; DOI:
10.1021/ic00305a014
PDF
Conjugation in the 3-connected net: the aluminum diboride and thorium disilicide structures and their transition-metal derivatives
Chong Zheng and Roald Hoffmann
pp 1074 - 1080; DOI:
10.1021/ic00305a015
PDF
Electrocatalytic activity of electropolymerized films of bis(vinylterpyridine)cobalt(2+) for the reduction of carbon dioxide and oxygen
H. C. Hurrell, A. L. Mogstad, D. A. Usifer, K. T. Potts, and H. D. Abruna
pp 1080 - 1084; DOI:
10.1021/ic00305a016
PDF
Synthesis and characterization of (catecholato)bis(.beta.-diketonato)vanadium(IV) complexes
Clifford J. Hawkins and Themistoklis A. Kabanos
pp 1084 - 1087; DOI:
10.1021/ic00305a017
PDF
Synthesis of polyhedral phosphaboranes: crystal structure of 6-(C2H5)3N.cntdot.2-PB9H8
John L. Little, John G. Kester, John C. Huffman, and Lee J. Todd
pp 1087 - 1091; DOI:
10.1021/ic00305a018
PDF
Steric effects in polypyrazolylborate ligands. Poly(3-isopropylpyrazolyl)borates: ligands of intermediate steric requirements
Swiatoslaw Trofimenko, Joseph C. Calabrese, Peter J. Domaille, and Jeffery S. Thompson
pp 1091 - 1101; DOI:
10.1021/ic00305a019
PDF
Reactions of the rhenium triphenylphosphine polyhydrides Re2H8(PPh3)4 and ReH7(PPh3)2 with acetic acid/acetic anhydride. Isolation and characterization of the rhenium(I) carbonyl complexes Re(O2CCH3)(CO)1+x(PPh3)3-x (x = 0,1) and the homoleptic dirhenium(III) carboxylate complex Re2(.mu.-O2CCH3)4(O2CCH3)2
Charles J. Cameron, Phillip E. Fanwick, Malee Leeaphon, and Richard A. Walton
pp 1101 - 1104; DOI:
10.1021/ic00305a020
PDF
Gold and silver hydrides: synthesis of heterobimetallic iridium-M (M = gold, silver) complexes and x-ray crystal structures of [(PPh3)Au(.mu.-H)IrH2(PPh3)3](BF4) and [(PPh3)Ag(.mu.-H)IrH2(PPh3)3](CF3SO3)
Alberto Albinati, Clemens Anklin, Philipp Janser, Hans Lehner, Dominique Matt, Paul S. Pregosin, and Luigi M. Venanzi
pp 1105 - 1111; DOI:
10.1021/ic00305a021
PDF
Solution studies of complexes of the types trans-PtCl2L(1,4-diazine) and trans-Lcl2Pt(.mu.-1,4-diazine)PtCl2L (L = phosphine, C2H4). X-ray structures of Pt2Cl4L2(ppz) (L = C2H4, PEt3; ppz - 2,5-dimethylpyrazine) and the relative trans influence of alkene and tertiary phosphine ligands
Alberto Albinati, Francesco Isaia, Werner Kaufmann, Carla Sorato, and Luigi M. Venanzi
pp 1112 - 1122; DOI:
10.1021/ic00305a022
PDF
The electron-deficient planar tetrairon cluster octacarbonyltetrakis(pyridine)tetrairon
Carlo Mealli, Davide Maria Proserpio, Giuseppe Fachinetti, Tiziana Funaioli, Giovanni Fochi, and Pier Francesco Zanazzi
pp 1122 - 1127; DOI:
10.1021/ic00305a023
PDF
Magnetic and spectroscopic properties of copper(II) compounds with alkyl-disubstituted triazoles. X-ray structure of bis[.mu.-4-amino-3,5-bis(aminomethyl)-1,2,4-triazole-N',N1,N2,N'']bis[aquabromocopper(II)] dibromide-2-water-methanol
Winifred M. E. Koomen-Van Oudenniel, Rudolf A. G. De Graaff, Jaap G. Haasnoot, Rob Prins, and Jan Reedijk
pp 1128 - 1133; DOI:
10.1021/ic00305a024
PDF
Metallomacrocycles: synthesis, x-ray structure, electrochemistry, and ESR spectroscopy of mononuclear and heterodinuclear complexes
Frank C. J. M. Van Veggel, Sybolt Harkema, Martinus Bos, Willem Verboom, Catherina J. Van Staveren, Gerrit J. Gerritsma, and David N. Reinhoudt
pp 1133 - 1148; DOI:
10.1021/ic00305a025
PDF
Chemical and electrochemical reactivity of nickel(II,I) thiolate complexes: examples of ligand-based oxidation and metal-centered oxidative addition
H. J. Krueger and R. H. Holm
pp 1148 - 1155; DOI:
10.1021/ic00305a026
PDF
Limits of direct transmetalation of polynuclear copper(II) complexes with M(NS).eta. reagents. Scissor transmetalators. Synthesis and properties of the trimers (.mu.3-O)(N,py)3Cu3X4 (N = N,N-diethylnicotinamide; py = pyridine; X = Cl, Br)
Atieh Abu-Raqabah, Geoffrey Davies, Mohamed A. El-Sayed, Ahmed El-Toukhy, and Maher Henary
pp 1156 - 1166; DOI:
10.1021/ic00305a027
PDF
Preparation and characterization of a binuclear iron-.mu.-dioxygen complex: [(Ph3PO)4FeOOFe(OPPh3)4.cntdot.2H2O](ClO4)4
Donald T. Sawyer, M. Steven McDowell, Lee Spencer, and Paul K. S. Tsang
pp 1166 - 1170; DOI:
10.1021/ic00305a028
PDF
Theoretical study of the cis-trans isomerism in disubstituted d6 metal carbonyls
C. Daniel and A. Veillard
pp 1170 - 1173; DOI:
10.1021/ic00305a029
PDF
Thiolato-technetium complexes. 2. Synthesis, characterization, electrochemistry, and spectroelectrochemistry of the technetium(III) complexes trans-[Tc(SR)2(DMPE)]+, where R is an alkyl or benzyl group and DMPE is 1,2-bis(dimethylphosphino)ethane
Takumi Konno, Jon R. Kirchhoff, William R. Heineman, and Edward Deutsch
pp 1174 - 1179; DOI:
10.1021/ic00305a030
PDF
Electronic structures of the Ru2(RNNNR)4, Rh2(RNCHNR)4, and Co2(RNNNR)4 molecules: ordering and separation of M-M .delta.* and .pi.* orbitals
F. Albert Cotton and Xuejun Feng
pp 1180 - 1183; DOI:
10.1021/ic00305a031
PDF
Five-coordinate complexes of 21-thiaporphyrin. Preparations, spectra, and structures of iron(II), nickel(II), and copper(II) complexes
Lechoslaw Latos-Grazynski, Jerzy Lisowski, Marilyn M. Olmstead, and Alan L. Balch
pp 1183 - 1188; DOI:
10.1021/ic00305a032
PDF
Polynuclear zinc(II) complexes with large polyazacycloalkanes. 2. Equilibrium studies and crystal structure of the binuclear complex [Zn2LCl2](Cl)ClO4.cntdot.H2O (L = 1,4,7,10,13,16,19,22-octaazacyclotetracosane)
Andrea Bencini, Antonio Bianchi, Paolo Dapporto, Enrique Garcia-Espana, Mauro Micheloni, and Piero Paoletti
pp 1188 - 1191; DOI:
10.1021/ic00305a033
PDF
X-ray crystallographic characterization of hydrogen-bonding interactions in piperidinium chloride and piperidinium tetrachloroaluminate: relevance to the structure of room-temperature melts
Michele V. Gaudet, Michael J. Zaworotko, and Peter S. White
pp 1191 - 1193; DOI:
10.1021/ic00305a034
PDF
Fundamental studies on phosphorus-31 relaxation mechanisms: the importance of chemical shift anisotropy and its implications for phosphorus-31 NMR studies of organometallic compounds
Leslie H. Randall and Arthur J. Carty
pp 1194 - 1196; DOI:
10.1021/ic00305a035
PDF
High-field magic-angle-spinning carbon-13 NMR spectroscopy of tetracobalt dodecacarbonyl
Silvio Aime, Mauro Botta, Roberto Gobetto, and Brian E. Hanson
pp 1196 - 1198; DOI:
10.1021/ic00305a036
PDF
Failure to observe peroxide in YBa2Cu3O7, La1.8Sr0.2CuO4, La2CuO4, and La2NiO4 by reaction with permanganate
Daniel C. Harris and Terrell A. Vanderah
pp 1198 - 1201; DOI:
10.1021/ic00305a037
PDF
Hydroxide-induced reduction of elemental sulfur (S8) to trisulfur anion radical (S3.bul.-)
Masashi Hojo and Donald T. Sawyer
pp 1201 - 1202; DOI:
10.1021/ic00305a038
PDF

Issue 7


Comparison between molybdenum-molybdenum and tungsten-tungsten bonding in oxide clusters: the crystal structure of zinc molybdenum tungsten oxide (Zn2MoW2O8) determined by time-of-flight powder neutron diffraction
Anthony K. Cheetham, Simon J. Hibble, and Helen R. Wakerley
pp 1203 - 1204; DOI:
10.1021/ic00306a001
PDF
The synthesis and structural characterization of the first gallacarborane sandwich
Marc A. Bandman, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 1204 - 1206; DOI:
10.1021/ic00306a002
PDF
A ligand-imposed cradle geometry for a dicobalt tetracarbonyl tetratertiary phosphine complex
Scott A. Laneman, Frank R. Fronczek, and George G. Stanley
pp 1206 - 1207; DOI:
10.1021/ic00306a003
PDF
Magnetic structures and properties of .alpha.-chromium phosphate and .alpha.-chromium arsenate
J. Paul Attfield, Peter D. Battle, Anthony K. Cheetham, and David C. Johnson
pp 1207 - 1213; DOI:
10.1021/ic00306a004
PDF
The richness of structures available to CpMS4MCp complexes
Wolfgang Tremel, Roald Hoffmann, and Eluvathingal D. Jemmis
pp 1213 - 1224; DOI:
10.1021/ic00306a005
PDF
Dependence of bond angles upon bond distances in simple covalent hydrides, halides, and oxides
N. Colin Baird
pp 1224 - 1227; DOI:
10.1021/ic00306a006
PDF
Enhanced excited-state basicities of coordinated bridging bis(diimines) (BL) in ruthenium complexes Ru(bpy)2(BL)2+ (bpy = 2,2'-bipyridine)
William Hosek, Steven A. Tysoe, Harry D. Gafney, A. David Baker, and Thomas C. Strekas
pp 1228 - 1231; DOI:
10.1021/ic00306a007
PDF
Reduction of carbon dioxide and other substrates using photochemical reactions of the decacarbonylditungstate(2-) complex
Ned D. Silavwe, Alan S. Goldman, Robin Ritter, and David R. Tyler
pp 1231 - 1236; DOI:
10.1021/ic00306a008
PDF
Interactions of nickel and manganese carbonyls with oxide surfaces: formation of reduced, oxidized, and zerovalent metal species
Michael P. Keyes, Liz U. Gron, and Kenneth L. Watters
pp 1236 - 1242; DOI:
10.1021/ic00306a009
PDF
Preparation and characterization of tungsten phenoxo W(OR)4Cl2 complexes (R = pentafluorophenyl, 2,6-dichlorophenyl) and some of their reduction products, including an x-ray study of W(O-2,6-C6H3Cl2)4Cl(Et2O)
Richard M. Kolodziej, Richard R. Schrock, and John C. Dewan
pp 1243 - 1248; DOI:
10.1021/ic00306a010
PDF
A new mixed molybdenum-tungsten dinuclear complex, bis(.mu.-oxo)(.mu.-ethylenediaminetetraacetato-N,N')oxomolybdenum(V)oxotungstate(V)
Shinji Ikari, Yoichi Sasaki, Akira Nagasawa, Chizuko Kabuto, and Tasuku Ito
pp 1248 - 1254; DOI:
10.1021/ic00306a011
PDF
Synthesis, molecular structure, and electrochemical properties of two geometric isomers of tetrakis(.mu.-2-anilinopyridinato)dirhodium complexes
J. L. Bear, C. L. Yao, L. M. Liu, F. J. Capdevielle, J. D. Korp, T. A. Albright, S. K. Kang, and K. M. Kadish
pp 1254 - 1262; DOI:
10.1021/ic00306a012
PDF
Coordination chemistry of sterically hindered thiolate ligands. Preparation and structural characterization of the oligomeric homoleptic complexes [o-trimethylsilylbenzenethiolato]copper dodecamer and [o-trimethylsilylbenzenethiolato]silver octamer and a comparison to the structure of the cadmium mononuclear species (Et4N)2[Cd(SC6H4-o-SiMe3)4]
Eric Block, Michael Gernon, Hyunkyu Kang, Gabriel Ofori-Okai, and Jon Zubieta
pp 1263 - 1271; DOI:
10.1021/ic00306a013
PDF
Magneto-structural correlations and metal-metal bonding in exchange-coupled nonahalodimolybdate (A3Mo2X9; X = chlorine, bromine, iodine) complexes
Robert Stranger, Peter W. Smith, and Ian E. Grey
pp 1271 - 1278; DOI:
10.1021/ic00306a014
PDF
Preparation and properties of dioxomolybdenum alkoxides, phenoxide, and siloxides prepared by the cocondensation reaction of molybdenum trioxide with alkoxy- or (aryloxy)silanes
Gyu Shik Kim, David Huffman, and Carroll W. DeKock
pp 1279 - 1283; DOI:
10.1021/ic00306a015
PDF
Pillaring of layered titanates by polyoxo cations of aluminum
Soofin Cheng and Tzun Chin Wang
pp 1283 - 1289; DOI:
10.1021/ic00306a016
PDF
Isomerization of binuclear amidate-bridged platinum(II) amine complexes: a platinum-195 NMR investigation
Thomas V. O'Halloran and Stephen J. Lippard
pp 1289 - 1295; DOI:
10.1021/ic00306a017
PDF
Restudy of the action of sulfur dioxide on dry trimethylamine oxide: iodine oxidation and Lewis acid chemistry of the most reactive product, (CH3)2(H)NCH2SO3
Anton B. Burg
pp 1295 - 1300; DOI:
10.1021/ic00306a018
PDF
Lewis-base adducts of Group 11 metal(I) compounds. 49. Structural characterization of hexameric and pentameric (triphenylphosphine)copper(I) hydrides
Candiera F. Albert, Peter C. Healy, John D. Kildea, Colin L. Raston, Brian W. Skelton, and Allan H. White
pp 1300 - 1306; DOI:
10.1021/ic00306a019
PDF
Kinetics and mechanism of hydrogen peroxide reactions of diperoxo(amine)chromium(IV) complexes: evidence for formation of an oxodiperoxochromium(VI) intermediate
C. K. Ranganathan, T. Ramasami, D. Ramaswamy, and M. Santappa
pp 1306 - 1310; DOI:
10.1021/ic00306a020
PDF
Coordination chemistry and redox properties of polypyridyl complexes of vanadium(II)
John C. Dobson and Henry Taube
pp 1310 - 1315; DOI:
10.1021/ic00306a021
PDF
Equilibrium and kinetic studies of monoaqua complexes of platinum(II). 3. Acid-base properties and dimerization of platinum amino acid DMSO aqua {[Pt(amino acid)(Me2SO)(OH2)]+} species
Luther E. Erickson, Ingrid E. Burgeson, Eric Eidsmoe, and Russell G. Larsen
pp 1315 - 1320; DOI:
10.1021/ic00306a022
PDF
Bis(triethylphosphine)gold(I) chloride: ionization in aqueous solution, reduction in vitro of the external and internal disulfide bonds of bovine serum albumin and antiarthritic activity
Anvarhusein A. Isab, Anne L. Hormann, David T. Hill, Don E. Griswold, Michael J. DiMartino, and C. Frank Shaw
pp 1321 - 1326; DOI:
10.1021/ic00306a023
PDF
Magnetic properties of the nickel enzymes urease, nickel-substituted carboxypeptidase A and nickel-substituted carbonic anhydrase
Patrick A. Clark and Dean E. Wilcox
pp 1326 - 1333; DOI:
10.1021/ic00306a024
PDF
Binding of pyridine and benzimidazole to a cadmium "expanded porphyrin": solution and x-ray structural studies
Jonathan L. Sessler, Toshiaki Murai, and Vincent Lynch
pp 1333 - 1341; DOI:
10.1021/ic00306a025
PDF
X-ray absorption spectroscopic studies of the sulfide complexes of hemerythrin
Michael J. Maroney, Robert C. Scarrow, Lawrence Que, A. Lawrence Roe, Gudrun S. Lukat, and Donald M. Kurtz
pp 1342 - 1348; DOI:
10.1021/ic00306a026
PDF
X-ray absorption edge spectroscopy of copper(I) complexes. Coordination geometry of copper(I) in the reduced forms of copper proteins and their derivatives with carbon monoxide
Ninian J. Blackburn, Richard W. Strange, Jan Reedijk, Anne Volbeda, Amjad Farooq, Kenneth D. Karlin, and Jon Zubieta
pp 1349 - 1357; DOI:
10.1021/ic00306a027
PDF
Observation of S = 2 EPR signals from ferrous iron-thiolate complexes. Relevance to rubredoxin-type sites in proteins
Mark T. Werth, Donald M. Kurtz, Barry D. Howes, and Hanh Huynh Boi
pp 1357 - 1361; DOI:
10.1021/ic00306a028
PDF
pH dependence of rate constants for reactions of cytochrome c with inorganic redox partners and mechanistic implications
P. L. Drake, R. T. Hartshorn, J. McGinnis, and A. G. Sykes
pp 1361 - 1366; DOI:
10.1021/ic00306a029
PDF
Reactions of ferrocenes and ferrocenium ions with ground and excited states of tris(2,2'-bipyridine)chromium ions
Shaoyung Lee, Andreja Bakac, and James H. Espenson
pp 1367 - 1369; DOI:
10.1021/ic00306a030
PDF
Excited-state properties of (.mu.-pyridyl)(.mu.-hydrido)octacarbonyldirhenium and related dirhenium carbonyl complexes
Raghunandan K. Menon and Theodore L. Brown
pp 1370 - 1379; DOI:
10.1021/ic00306a031
PDF
Pressure-induced spin-state phase transitions in dichloro- and dibromobis[cis-1,2-bis{(diphenylphosphino)ethylene}]iron
James K. McCusker, Maruta Zvagulis, Harry G. Drickamer, and David N. Hendrickson
pp 1380 - 1384; DOI:
10.1021/ic00306a032
PDF
Dirhenium complexes containing pairs of bridging acetate and bis(diphenylphosphino)amine ligands. Cis and trans isomers of the type [Re2(O2CCH3)2X2(Ph2PNHPPh2)2]n+ (X = Cl, Br: n = p, 1)
Daniel R. Derringer, Phillip E. Fanwick, Justin Moran, and Richard A. Walton
pp 1384 - 1389; DOI:
10.1021/ic00306a033
PDF
Oxidative addition of phenols to bis(tricyclohexylphosphine)palladium. Synthesis and structural characterization of trans-[Pd(PCy3)2(H)(OC6H5)].C6H5OH (1) and trans-[Pd(PCy3)2(H)(OC6F5)].C6F5OH (2)
C. Di Bugno, M. Pasquali, P. Leoni, P. Sabatino, and D. Braga
pp 1390 - 1394; DOI:
10.1021/ic00306a034
PDF
Crystal structure and mechanism of water exchange on nonaaquatetraoxotrimolybdenum(4+) from x-ray and oxygen-17 NMR studies
David T. Richens, Lothar Helm, Pierre Andre Pittet, Andre E. Merbach, Francesco Nicolo, and Gervais Chapuis
pp 1394 - 1402; DOI:
10.1021/ic00306a035
PDF
Effect of ring size on the dissociaton kinetics of copper(II)-tetraamine complexes
Lien Huei Chen and Chung Sun Chung
pp 1402 - 1405; DOI:
10.1021/ic00306a036
PDF
Spectroscopic and solution properties of the cobalt(III) hexaimidazole ion
Gil Navon and Ruth Panigel
pp 1405 - 1407; DOI:
10.1021/ic00306a037
PDF
New classes of monomeric and dimeric square-planar chromium(II) aryloxides: syntheses and structures
Jilles J. H. Edema, Sandro Gambarotta, Fre Van Bolhuis, Wilberth J. J. Smeets, and Anthony L. Spek
pp 1407 - 1410; DOI:
10.1021/ic00306a038
PDF
1:1 Adducts of lead(II) thiocyanate with 1,10-phenanthroline and 2,2',6',2"-terpyridine
Lutz M. Engelhardt, Brenda M. Furphy, Jack M. Harrowfield, Jennifer M. Patrick, and Allan H. White
pp 1410 - 1413; DOI:
10.1021/ic00306a039
PDF
Resonance Raman spectra and electrochemistry of mononuclear and dinuclear (bis(pyridinyl)triazolato)ruthenium compounds
Ronald Hage, Jaap G. Haasnoot, Derk J. Stufkens, Theo L. Snoeck, Johannes G. Vos, and Jan Reedijk
pp 1413 - 1414; DOI:
10.1021/ic00306a040
PDF
Preparation, molecular structure, and magnetism of bis(.mu.-carbonate)-.mu.-oxobis[1,4,7-trimethyl-1,4,7-triazacyclononane]diiron 4.25 hydrate
Stefan Drueke, Karl Wieghardt, Bernhard Nuber, and Johannes Weiss
pp 1414 - 1417; DOI:
10.1021/ic00306a041
PDF
Synthesis and characterization of a new potentially ditopic receptor, 1,4,7,10-tetraoxa-13,16,19,22-tetraazacyclotetracosane, and the x-ray crystal structure of its mononuclear copper(II) complex
Jonathan L. Sessler, John W. Sibert, Jeffrey D. Hugdahl, and Vincent Lynch
pp 1417 - 1419; DOI:
10.1021/ic00306a042
PDF
Crystal and molecular structure of (N,N'-dimethyl-2,11-diaza[3.3](2,6)pyridinophane)copper dichloride monohydrate complex
Frank R. Fronczek, Antonino Mamo, and Sebastiano Pappalardo
pp 1419 - 1422; DOI:
10.1021/ic00306a043
PDF
Tri- and tetranuclear palladium-cobalt clusters containing bridging Ph2PCH2PPh2 (dppm) ligands. Crystal structures of bis[.mu.-bis(diphenylphosphine)methane]di-.mu.3-carbonylpentacarbonyl dicobaltdipalladium and [Pd2Co(.mu.3-CO)2(CO)2(.mu.-dppm)2][PF6] [Erratum to document cited in CA108(18):160320f]
Pierre Braunstein, Claude De Meric de Bellefon, Michel Ries, Jean Fischer, Salah Eddine Bouaoud, and Daniel Grandjean
pp 1422 - 1422; DOI:
10.1021/ic00306a044
PDF
Anionic iron carbido carbonyl clusters with sulfur dioxide ligands [Erratum to document cited in CA108(24):215296k]
P. L. Bogdan, M. Sabat, S. A. Sunshine, C. Woodcock, and D. F. Shriver
pp 1422 - 1422; DOI:
10.1021/ic00306a045
PDF
Stability of synthetic zeolite ZSM-5 to dealumination with chromium(III) salt solutions [Erratum to document cited in CA109(24):221305z]
W. E. Garwood, P. Chu, N. Y. Chen, and J. C. Bailar
pp 1422 - 1422; DOI:
10.1021/ic00306a046
PDF

Issue 8


Organometal hydroxide route to [(C5Me5)Rh]4(V6O19)
H. K. Chae, Walter G. Klemperer, and V. W. Day
pp 1423 - 1424; DOI:
10.1021/ic00307a001
PDF
Synthesis and characterization of a series of antimony-containing iron carbonyl complexes: [Et4N]3[SbFe4(CO)16], [Et4N]2[HSbFe4(CO)13], [Et4N][H2SbFe4(CO)13], and [Et4N]2[ClSbFe3(CO)12]
Shifang Luo and Kenton H. Whitmire
pp 1424 - 1431; DOI:
10.1021/ic00307a002
PDF
Synthesis and structure of [PPN]2[Tl2Fe6(CO)24]: completion of a series of thallium-iron carbonyl clusters
Juanita M. Cassidy and Kenton H. Whitmire
pp 1432 - 1434; DOI:
10.1021/ic00307a003
PDF
Synthesis and structure of Lewis base adducts of thallium iron carbonyl, [Et4N]2[Tl2Fe4(CO)16]
Juanita M. Cassidy and Kenton H. Whitmire
pp 1435 - 1439; DOI:
10.1021/ic00307a004
PDF
Cluster synthesis. 25. Synthesis and characterization of new mixed-metal cluster complexes by metal-metal exchange. Reactions of the sulfido cluster complexes M3(CO)9(.mu.3-CO)(.mu.3-S) (M = iron, ruthenium and osmium) with W(CO)5L (L = CO or PMe2Ph)
Richard D. Adams, James E. Babin, Pradeep Mathur, K. Natarajan, and Jin Guu Wang
pp 1440 - 1445; DOI:
10.1021/ic00307a005
PDF
Cobalt(I), -(II), and -(III) complexes of a tetraaza 14-membered macrocycle, 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene (L). Crystal and molecular structures of [CoL(CO)]ClO4, trans-CoLCl2, and cis-[CoL(CO3)]ClO4
David J. Szalda, Etsuko Fujita, and Carol Creutz
pp 1446 - 1450; DOI:
10.1021/ic00307a006
PDF
Diphos-dithiophosphate-carboxylate variations on the molybdenum-sulfur (Mo2S26+) core
Ana C. Lizano, John F. Richardson, and Mark E. Noble
pp 1451 - 1456; DOI:
10.1021/ic00307a007
PDF
Conformational preferences in six-coordinate, octahedral complexes of molybdenum(III). Synthesis and structure of MoX3(dppe)L [X = Cl, Br, I; dppe = bis(diphenylphosphino)ethane; L = tetrahydrofuran, acetonitrile, trimethylphosphine]
Beth E. Owens, Rinaldo Poli, and Arnold L. Rheingold
pp 1456 - 1462; DOI:
10.1021/ic00307a008
PDF
Solid-state phosphorus-31 NMR, far-IR, and structural studies on two-coordinate (tris(2,4,6-trimethoxyphenyl)phosphine)copper(I) chloride and bromide
Graham A. Bowmaker, John D. Cotton, Peter C. Healy, John D. Kildea, Sidik Bin Silong, Brian W. Skelton, and Allan H. White
pp 1462 - 1466; DOI:
10.1021/ic00307a009
PDF
Band electronic structure study of the electronic instability in the Magneli phase molybdenum oxide [Mo4O11]
Enric Canadell, Myung Hwan Whangbo, Claire Schlenker, and Claude Escribe-Filippini
pp 1466 - 1472; DOI:
10.1021/ic00307a010
PDF
Calculation of hydrogen-bonding interactions between ions in room-temperature molten salts
Chester J. Dymek and James J. P. Stewart
pp 1472 - 1476; DOI:
10.1021/ic00307a011
PDF
Electronic and CD spectra of catecholate and semiquinonate adducts of zinc(II) and nickel(II) tetraazamacrocyclic complexes
Cristiano Benelli, Andrea Dei, Dante Gatteschi, and Luca Pardi
pp 1476 - 1480; DOI:
10.1021/ic00307a012
PDF
Stability and structure of xanthosine-metal ion complexes in aqueous solution, together with intramolecular adenosine-metal ion equilibria
Yoshiaki Kinjo, Roger Tribolet, Nicolas A. Corfu, and Helmut Sigel
pp 1480 - 1489; DOI:
10.1021/ic00307a013
PDF
Manganese(II) as a probe of the active center of alkaline phosphatase
Charles Schulz, Ivano Bertini, Maria Silvia Viezzoli, Rodney D. Brown, Seymour H. Koenig, and Joseph E. Coleman
pp 1490 - 1496; DOI:
10.1021/ic00307a014
PDF
Alternative spin states in synthetic analogs of biological iron-sulfur [4Fe-4S]+ clusters: further cases of variable ground states and the structure of (Et4N)3[Fe4S4(S-o-C6H4S-tert-Bu)4], containing a reduced cluster with a compressed tetragonal distortion
M. J. Carney, G. C. Papaefthymiou, R. B. Frankel, and Richard H. Holm
pp 1497 - 1503; DOI:
10.1021/ic00307a015
PDF
Synthesis, characterization, and solid-state structure of a new hexachelating ligand and its complex with gallium(III)
Dennis A. Moore, Phillip E. Fanwick, and Michael J. Welch
pp 1504 - 1506; DOI:
10.1021/ic00307a016
PDF
Tridecahydrononaborate(2-) an arachno-[BnHn+4]2- dianion: synthesis, characterization, and molecular structure
Thomas D. Getman, Jeanette A. Krause, Philipp M. Niedenzu, and Sheldon G. Shore
pp 1507 - 1510; DOI:
10.1021/ic00307a017
PDF
NMR and electrochemical investigation of the redox and exchange reactions of tellurium(II) and tellurium(IV) dithiocarbamate complexes
Alan M. Bond, Dainis Dakternieks, Robert Di Giacomo, and Anthony F. Hollenkamp
pp 1510 - 1515; DOI:
10.1021/ic00307a018
PDF
New di- and trinuclear complexes of ruthenium with octahedra joined on faces or edges: Ru2Cl6(PBu3)3, Ru2Cl6(PBu3)4 and Ru3Cl8(PBu3)4 (Bu = CH3CH2CH2CH2)
F. Albert Cotton, Marek Matusz, and Raymund C. Torralba
pp 1516 - 1520; DOI:
10.1021/ic00307a019
PDF
Energy level tailoring in ruthenium(II) polyazine complexes based on calculated and experimental ligand properties
Sylvia D. Ernst and Wolfgang Kaim
pp 1520 - 1528; DOI:
10.1021/ic00307a020
PDF
Electronic spectra and photophysics of platinum(II) complexes with .alpha.-diimine ligands. Solid-state effects. 1. Monomers and ligand .pi. dimers
Vincent M. Miskowski and Virginia H. Houlding
pp 1529 - 1533; DOI:
10.1021/ic00307a021
PDF
Electrochemical assembly of metallopolymeric films via reduction of coordinated 5-chlorophenanthroline
Odette Fussa-Rydel, Hai Tao Zhang, Joseph T. Hupp, and Charles R. Leidner
pp 1533 - 1537; DOI:
10.1021/ic00307a022
PDF
Electron transfer. 97. The iron-catalyzed reduction of peroxide-bound chromium(IV) with ascorbic acid
S. K. Ghosh and E. S. Gould
pp 1538 - 1542; DOI:
10.1021/ic00307a023
PDF
Stereoselectivity in the reduction of tris(oxalato)cobaltate(3-) by tris(ethylenediamine)cobalt(2+) and its derivatives
Rosemary A. Marusak, Peter Osvath, Margaret Kemper, and A. Graham Lappin
pp 1542 - 1548; DOI:
10.1021/ic00307a024
PDF
Reactions of bis(dimethylglyoximato)cobalt(II) with iodoacetonitrile and pentaamine(iodoacetonitrile)cobalt(II)
E. Kita and R. B. Jordan
pp 1549 - 1553; DOI:
10.1021/ic00307a025
PDF
Synthesis, kinetics, and stereochemistry of the aquation of cis-[chlorosulfitobis(ethylenediamine)cobalt(III)]
W. Gregory Jackson, A. G. Kuzmission, J. N. Cooper, and J. C. Henry
pp 1553 - 1559; DOI:
10.1021/ic00307a026
PDF
Multinuclear magnetic resonance studies of the reactions of bidentate ligands with bis(diethyldithiocarbamato)platinum. Comparisons with the reactions of bis(diethyl dithiophosphato)platinum
Ray Colton and Jennifer Ebner
pp 1559 - 1563; DOI:
10.1021/ic00307a027
PDF
FXeOIOF4 and Xe(OIOF4)2: preparation and study by xenon-129 and fluorine-19 NMR spectroscopy and Raman spectroscopy and NMR characterization of LXeOIOF4 (L = -OTeF5, -OSO2F)
Robert G. Syvret and Gary J. Schrobilgen
pp 1564 - 1573; DOI:
10.1021/ic00307a028
PDF
Polyoxoanions derived from tungstosilicate, A-.beta.-SiW9O3410-: synthesis and crystallographic and tungsten-183 NMR characterization of Si2W18Zr3O71H311-, including its organic solvent soluble Bu4N+ salt
Richard G. Finke, Brian Rapko, and T. J. R. Weakley
pp 1573 - 1579; DOI:
10.1021/ic00307a029
PDF
Structural and magnetic studies of electrochemically crystallized halides of 1,4,5,8-tetraselenonaphthalene (TSeN)
Lewis A. Acampora, Boris S. Elman, Daniel J. Sandman, Susan Jansen, M. Thomas Jones, Raymond D. Rataiczak, and Bruce M. Foxman
pp 1579 - 1582; DOI:
10.1021/ic00307a030
PDF
Chloride-induced assembly of manganese(II) complexes having oligomeric and chain structures
B. C. Unni Nair, J. E. Sheats, R. Ponteciello, D. Van Engen, V. Petrouleas, and G. C. Dismukes
pp 1582 - 1587; DOI:
10.1021/ic00307a031
PDF
Synthesis and crystal structure of (hexamethyldibenzotetraazaannulenato)nickel-TCNQ. A mixed-stack donor-acceptor molecular solid
Peter J. Spellane, Leonard V. Interrante, Rudolph K. Kullnig, and Fook S. Tham
pp 1587 - 1590; DOI:
10.1021/ic00307a032
PDF
Control of spin state in iron(III) porphyrinates. The admixed intermediate-spin case. Crystal structure, Moessbauer, and susceptibility study of bis(3,5-dichloropyridine)(octaethylporphyrinato)iron(1+) perchlorate
W. Robert Scheidt, Sarah R. Osvath, Young Ja Lee, Christopher A. Reed, Ben Shaevitz, and Govind P. Gupta
pp 1591 - 1595; DOI:
10.1021/ic00307a033
PDF
A rhenium(I) bipyrimidine tricarbonyl complex containing methyl viologen as the sixth ligand: NMR and structural results
Linda N. Winslow, D. Paul Rillema, Jane H. Welch, and Phirtu Singh
pp 1596 - 1599; DOI:
10.1021/ic00307a034
PDF
Infrared spectroscopic studies of the reactions of copper and ammonia in cryogenic argon matrices
David W. Ball, Robert H. Hauge, and John L. Margrave
pp 1599 - 1601; DOI:
10.1021/ic00307a035
PDF
Template condensation of formaldehyde with triamines. Synthesis and characterization of nickel(II) complexes with the novel hexaaza macrotricyclic ligands 1,3,6,9,11,14-hexaazatricyclo[12.2.1.16,9]octadecane and 1,3,6,10,12,15-hexaazatricyclo[13.3.1.16,10]eicosane
Myunghyun Paik Suh, Whanchul Shin, Shin Geol Kang, Myoung Soo Lah, and Taek Mo Chung
pp 1602 - 1605; DOI:
10.1021/ic00307a036
PDF
Reduction by carbon dioxide radical [.CO2] of (1-methyl-4,4'-bipyridinium)pentaammine cobalt(III) perchlorate and kinetic behavior of the transient radical in aqueous solution
K. Tsukahara and Ralph G. Wilkins
pp 1605 - 1607; DOI:
10.1021/ic00307a037
PDF
A soluble alkoxyzinc hydride, [HZnOC(CH3)3]4. Synthesis and reactions with copper(I) alkoxides
Thomas L. Neils and James M. Burlitch
pp 1607 - 1609; DOI:
10.1021/ic00307a038
PDF
Crystal symmetry governing the metallic vs semiconducting properties of cesium molybdenum bronzes CsxMoO3 (x .simeq. 0.25, 0.33)
Enric Canadell and Myung Hwan Whangbo
pp 1609 - 1610; DOI:
10.1021/ic00307a039
PDF
Cobalt-carbon bond disruption enthalpies: the first reliable measurement of a Co-methyl BDE via solution thermochemical methods [Erratum to document cited in CA110(15):135469v]
Paul J. Toscano, Allen L. Seligson, Matthew T. Curran, Andrew T. Skrobutt, and David C. Sonnenberger
pp 1610 - 1610; DOI:
10.1021/ic00307a040
PDF
Synthesis of rhenium(II) porphyrin complexes and crystal structure of bis(trimethylphosphine)(tetra-p-tolylporphyrinato)rhenium(II)-toluene [Erratum to document cited in CA109(26):242984k]
James P. Collman, James M. Garner, Kimoon Kim, and James A. Ibers
pp 1610 - 1610; DOI:
10.1021/ic00307a041
PDF

Issue 9


The structure of d0 ML6 complexes
Sung Kwon Kang, Thomas A. Albright, and Odile Eisenstein
pp 1611 - 1613; DOI:
10.1021/ic00308a001
PDF
Binuclear polyhydrides of tantalum. Reductive desulfurization of a bridging thioether ligand and formation of a Ta2(.mu.-S) unit. X-ray crystal structure of bis[bis(diisopropylphosphino)propane]dichlorodi-.mu.-hydridodihydrido-.mu.-sulfidoditantalum
Michael D. Fryzuk and David H. McConville
pp 1613 - 1614; DOI:
10.1021/ic00308a002
PDF
Microwave spectrum, boron skeletal structure, and dipole moment of 5-fluoro-2,4-dicarboheptaborane(7) (C2B5H6F)
S. S. Durso, R. A. Sheeks, E. V. O'Gorman, and Robert A. Beaudet
pp 1615 - 1619; DOI:
10.1021/ic00308a003
PDF
Fluorination of boron chlorides and boron bromides by reaction with bis(trifluoromethyl)mercury, trichlorofluoromethane, or tribromofluoromethane: synthesis of BF2B5H8
D. A. Saulys, J. Castillo, and John A. Morrison
pp 1619 - 1624; DOI:
10.1021/ic00308a004
PDF
Synthesis and coordination properties of bis(bis(pentafluoroethyl)phosphino)ethane
Michael F. Ernst and Dean M. Roddick
pp 1624 - 1627; DOI:
10.1021/ic00308a005
PDF
Preparation and spectroscopic characterization of trifluoromethyl-substituted amides, phosphides and arsenides, M(CF3)2- (M = N, P, As)
R. Minkwitz and A. Liedtke
pp 1627 - 1630; DOI:
10.1021/ic00308a006
PDF
Spectroscopic and chemical studies of nickel(II) hydrides
Marcetta Y. Darensbourg, Maria Ludwig, and Charles G. Riordan
pp 1630 - 1634; DOI:
10.1021/ic00308a007
PDF
DRIFTS investigation of the decomposition of ruthenium clusters on carbon and the subsequent ruthenium/carbon catalysts
Jeremy J. Venter and M. Albert Vannice
pp 1634 - 1644; DOI:
10.1021/ic00308a008
PDF
Coordination compounds of indium. 46. Indium(I) derivatives of 3,5-di-tert-butyl-1,2-o-benzoquinone
Theodore A. Annan, David H. McConville, Bruce R. McGarvey, Andrzej Ozarowski, and Dennis G. Tuck
pp 1644 - 1648; DOI:
10.1021/ic00308a009
PDF
Epoxidation of olefins catalyzed by chelating diphosphine-platinum(II) complexes. Ring-size and ring-shape effects on the catalytic activity
Andrea Zanardo, Rino A. Michelin, Francesco Pinna, and Giorgio Strukul
pp 1648 - 1653; DOI:
10.1021/ic00308a010
PDF
Influence of atomic size on mechanism: displacement of chelating ligands coordinating through sulfur from their chromium and molybdenum carbonyl complexes
Hani H. Awad, Charles B. Dobson, Gerard R. Dobson, Johann G. Leipoldt, Karen Schneider, Rudi Van Eldik, and Helen Elizabeth Wood
pp 1654 - 1657; DOI:
10.1021/ic00308a011
PDF
Interfacial role in the kinetics of extraction of nickel(II) and zinc(II) with halogenated dithizones in aqueous chloroform systems
V. G. Chamupathi and Henry Freiser
pp 1658 - 1660; DOI:
10.1021/ic00308a012
PDF
Electron-transfer processes in the electrophilic cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes with iodine
Kunio Ishikawa, Shunichi Fukuzumi, and Toshio Tanaka
pp 1661 - 1665; DOI:
10.1021/ic00308a013
PDF
Photoredox processes in the 254-nm photochemistry of chromium(III) ammine complexes
Ronald R. Ruminski, Marguerite H. Healy, and William F. Coleman
pp 1666 - 1669; DOI:
10.1021/ic00308a014
PDF
Stabilization of homopolyatomic cations of iodine in anhydrous hydrogen fluoride
John Besida and Thomas A. O'Donnell
pp 1669 - 1673; DOI:
10.1021/ic00308a015
PDF
ESR study of the solution thermochromism resulting from low-temperature isomerization of pyrazolato-bridged dirhodium complexes generated via electrochemical oxidation
Clifton Woods, Louis J. Tortorelli, D. Paul Rillema, James L. E. Burn, and Jeffrey C. DePriest
pp 1673 - 1679; DOI:
10.1021/ic00308a016
PDF
Electronic structure of the 3.SIGMA.- states of silicon-oxygen compounds, SiOSi and SiSiO
Roger L. DeKock, Brian F. Yates, and Henry F. Schaefer
pp 1680 - 1684; DOI:
10.1021/ic00308a017
PDF
Insertion of vanadium-iron-sulfur, [VFe3S4]2+, and molybdenum-iron-sulfur, [MoFe3S4]3+, cores into a semirigid trithiolate cavitand ligand: regiospecific reactions at a vanadium site similar to that in nitrogenase
Stefano Ciurli and R. H. Holm
pp 1685 - 1690; DOI:
10.1021/ic00308a018
PDF
Molecular oxygen and carbon monoxide binding to "jellyfish" type iron(II) porphyrins
Yoshio Uemori and Eishin Kyuno
pp 1690 - 1694; DOI:
10.1021/ic00308a019
PDF
Thiolato-technetium complexes. 3. Synthesis and x-ray structural studies on the geometrical isomers cis- and trans-bis(p-chlorobenzenethiolato)bis(1,2-bis(dimethylphosphino)ethane)technetium(II)
Takumi Konno, Mary Jane Heeg, and Edward Deutsch
pp 1694 - 1700; DOI:
10.1021/ic00308a020
PDF
Synthesis and characterization of the new alkali metal germanium tellurium mixed oxides M2(GeTe)O6 (M = potassium, rubidium, cesium)
M. Amarilla, M. L. Veiga, C. Pico, M. Gaitan, and A. Jerez
pp 1701 - 1703; DOI:
10.1021/ic00308a021
PDF
Relative proton affinity of neutral ruthenium(II) complexes, [RuX2(bpy)2] (X = Cl, Br, I, NCS, CN, NO2), observed in liquid secondary-ion mass spectrometry spectra
Mikio Tanaka, Takashi Nagai, and Eiichi Miki
pp 1704 - 1706; DOI:
10.1021/ic00308a022
PDF
X-ray powder structure and Rietveld refinement of the monosodium exchanged monohydrate of .alpha.-zirconium phosphate, Zr(NaPO4)(HPO4).cntdot.H2O
Philip R. Rudolf and Abraham Clearfield
pp 1706 - 1710; DOI:
10.1021/ic00308a023
PDF
Donor-acceptor properties of ambient-temperature chloroaluminate melts
Thomas A. Zawodzinski and Robert A. Osteryoung
pp 1710 - 1715; DOI:
10.1021/ic00308a024
PDF
Crystal structures of three brilliantly triboluminescent centrosymmetric lanthanide complexes: piperidinium tetrakis(benzoylacetonato)europate, hexakis(antipyrine)terbium triiodide, and hexaaquadichloroterbium chloride
Arnold L. Rheingold and Wayne King
pp 1715 - 1719; DOI:
10.1021/ic00308a025
PDF
Oxo-bridged chromium(III) dimers derived from the reactions of anions (thiocyanate, cyanate, azide, cyanide, chloride) with the bis(.mu.-hydroxo)bis{tris(2-pyridylmethyl)amine)chromium(III)} ion
Boyd G. Gafford, Charles O'Rear, Jian H. Zhang, Charles J. O'Connor, and Robert A. Holwerda
pp 1720 - 1726; DOI:
10.1021/ic00308a026
PDF
Vanadium-51 NMR investigation of the interactions of vanadate with hydroxypyridines and pyridinecarboxylates in aqueous solution
Bruno Galeffi and Alan S. Tracey
pp 1726 - 1734; DOI:
10.1021/ic00308a027
PDF
Metal-nitroxyl interactions. 53. Effect of the metal-nitroxyl linkage on the electron-electron exchange interaction in spin-labeled complexes of copper(II), low-spin cobalt(II), vanadyl, and chromium(III)
Kundalika M. More, Gareth R. Eaton, Sandra S. Eaton, Olga H. Hankovszky, and Kalman Hideg
pp 1734 - 1743; DOI:
10.1021/ic00308a028
PDF
Synthesis and characterization of technetium(III) complexes containing 2,2'-bipyridine and 1,10-phenanthroline. X-ray crystal structures of cis(Cl),trans(P)-[TcCl2(P(CH3)2C6H5)2(bpy)]B(C6H5)4, cis(Cl),trans(P)-[TcCl2(P(CH3)2C6H5)2(phen)]B(C6H5)4, and cis(Cl),trans(P)-[TcCl2(P(CH3CH2)(C6H5)2)2(bpy)]SO3CF3
Bruce E. Wilcox, Douglas M. Ho, and Edward Deutsch
pp 1743 - 1751; DOI:
10.1021/ic00308a029
PDF
2,3-Dihydrothiophene (2,3-DHT) complexes of tungsten. The structure of W(CO)3(dppe)(2,3-DHT)
George N. Glavee, Lee M. Daniels, and Robert J. Angelici
pp 1751 - 1754; DOI:
10.1021/ic00308a030
PDF
Edge-sharing bioctahedral molecules without metal-metal bonds: the d6-d6 complexes bis[.mu.-bis(diphenylphosphino)methane]di-.mu.-halotetrahalodirhodium (halo = chloro, bromo)
F. Albert Cotton, Kim R. Dunbar, Cassandra T. Eagle, Larry R. Falvello, and Andrew C. Price
pp 1754 - 1757; DOI:
10.1021/ic00308a031
PDF
X-ray powder diffraction at the spin-state transition in N,N'-ethylenebis(3-carboxysalicylaldiminato)cobalt(II) complexes
Edgar Koenig, G. Ritter, J. Dengler, P. Thuery, and J. Zarembowitch
pp 1757 - 1759; DOI:
10.1021/ic00308a032
PDF
Applications of the quantitative analysis of ligand effects (QALE). Steric profiles for reactions involving "spectator" phosphorus(III) ligands
Klaas Eriks, Warren P. Giering, Hong Ye Liu, and Alfred Prock
pp 1759 - 1763; DOI:
10.1021/ic00308a033
PDF
Synthesis, characterization, and x-ray structure of the octahedral nickel(II) complex of a pentadentate hexaaza macrobicyclic ligand: chloro(9-methoxymethyl-1,4,6,9,11,14-hexaazabicyclo[12.2.1]heptadecane)nickel(II) perchlorate
Myunghyun Paik Suh, Jungwon Choi, Shin Geol Kang, and Whanchul Shin
pp 1763 - 1765; DOI:
10.1021/ic00308a034
PDF
Transition-metal silyl complexes. 29. Formation of dihydride complexes from hydrido(silyl)tetracarbonyliron derivatives
U. Schubert and M. Knorr
pp 1765 - 1766; DOI:
10.1021/ic00308a035
PDF

Issue 10


A K3-containing trigonal-bipyramidal cluster: synthesis of (KSCN)3.5HMPA by reaction of solid NH4SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K+ ions linked by three equatorial .mu.2-HMPA ligands and bicapped by two .mu.3-HMPA ligands
Donald Barr, Michael J. Doyle, Simon R. Drake, Paul R. Raithby, Ronald Snaith, and Dominic S. Wright
pp 1767 - 1768; DOI:
10.1021/ic00309a001
PDF
Tris(trimethylsilyl)silyl derivatives of tri-tert-butoxyzirconium and tri-tert-butoxyhafnium. X-ray crystal structure of (Me3CO)3ZrSi(SiMe3)3
Richard H. Heyn and T. Don Tilley
pp 1768 - 1769; DOI:
10.1021/ic00309a002
PDF
Synthesis and redox and structural chemistry of monomeric rhenium(IV) phenoxide complexes
Ian M. Gardiner, Michael A. Bruck, and David E. Wigley
pp 1769 - 1771; DOI:
10.1021/ic00309a003
PDF
Lewis base adducts of uranium triiodide: a new class of synthetically useful precursors for trivalent uranium chemistry
David L. Clark, Alfred P. Sattelberger, Simon G. Bott, and Raymond N. Vrtis
pp 1771 - 1773; DOI:
10.1021/ic00309a004
PDF
Spectroscopy and photochemistry of nickel(0)-.alpha.-diimine complexes. 1. Structural differences among NiL2 and Ni(CO)2L (L = .alpha.-diimine) complexes: molecular orbital calculations and an electronic absorption and resonance Raman study
Peter C. Servaas, Derk J. Stufkens, and Ad Oskam
pp 1774 - 1780; DOI:
10.1021/ic00309a005
PDF
Spectroscopy and photochemistry of nickel(0)-.alpha.-diimine complexes. 2. MLCT photochemistry of Ni(CO)2(R-DAB) (R = tert-Bu, 2,6-isoPr2Ph): evidence for two different photoprocesses
Peter C. Servaas, Derk J. Stufkens, and Ad Oskam
pp 1780 - 1787; DOI:
10.1021/ic00309a006
PDF
Intramolecular excited-state interactions of surfactant-active osmium(II) photosensitizers
Lou Ann Sacksteder, J. N. Demas, and B. A. DeGraff
pp 1787 - 1792; DOI:
10.1021/ic00309a007
PDF
Trichloroiron (FeCl3)-phosphine adducts with trigonal-bipyramidal geometry. Influence of the phosphine on the spin state
J. David Walker and Rinaldo Poli
pp 1793 - 1801; DOI:
10.1021/ic00309a008
PDF
REX calculations. 12. Iteration parameters for the 5f-element organometallics of thorium-neptunium. Geometries of thorium dioxide and uranyl ion revisited
Pekka Pyykko, Liisa J. Laakkonen, and Kazuyuki Tatsumi
pp 1801 - 1805; DOI:
10.1021/ic00309a009
PDF
Electronic configuration and orbital energies: the 3d-4s problem
L. G. Vanquickenborne, K. Pierloot, and D. Devoghel
pp 1805 - 1813; DOI:
10.1021/ic00309a010
PDF
Relaxation mechanism of germanium-73 in tetrabromogermane and tetraiodogermane at high temperature
Toshie Harazono, Katsumi Tanaka, and Yoshito Takeuchi
pp 1813 - 1815; DOI:
10.1021/ic00309a011
PDF
Moessbauer spectra and electronic ground-state calculations of strongly coupled ruthenium ammines bridged by pyrazine and p-benzoquinone diimine
Stefan Joss, Kai M. Hasselbach, Hans Beat Buergi, Rainer Wordel, Friedrich E. Wagner, and Andreas Ludi
pp 1815 - 1819; DOI:
10.1021/ic00309a012
PDF
Variable-temperature and -pressure vibrational spectra of o-carborane
Ralph M. Paroli, Nancy T. Kawai, Gabriel Lord, Ian S. Butler, and Denis F. R. Gilson
pp 1819 - 1823; DOI:
10.1021/ic00309a013
PDF
New synthesis of 1,2-ethano-o-carborane and the structure of 9-chloro-1,2-ethano-o-carborane
Robert P. L'Esperance, Zhen Hong Li, Donna Van Engen, and Maitland Jones
pp 1823 - 1826; DOI:
10.1021/ic00309a014
PDF
Low-temperature x-ray absorption spectroscopy of plastocyanin: evidence for copper-site photoreduction at cryogenic temperatures
James E. Penner-Hahn, Mitsuo Murata, Keith O. Hodgson, and Hans C. Freeman
pp 1826 - 1832; DOI:
10.1021/ic00309a015
PDF
Formation of gold(I) halide and thiocyanate complexes in pyridine and acetonitrile and the structures of gold(I) solvates in these solvents. A thermodynamic and EXAFS spectroscopic study
Sten Ahrland, Karin Nilsson, Ingmar Persson, Akio Yuchi, and James E. Penner-Hahn
pp 1833 - 1838; DOI:
10.1021/ic00309a016
PDF
Metalloporphyrin π- cation radicals. Intermolecular spin coupling in zinc tetraphenylporphyrin derivatives
Hungsun Song, Nigam P. Rath, Christopher A. Reed, and W. Robert Scheidt
pp 1839 - 1847; DOI:
10.1021/ic00309a017
PDF
Crystal structure and infrared and Raman spectra of potassium vanadyl sulfate (K4(VO)3(SO4)5)
R. Fehrmann, S. Boghosian, G. N. Papatheodorou, K. Nielsen, R. W. Berg, and N. J. Bjerrum
pp 1847 - 1853; DOI:
10.1021/ic00309a018
PDF
Monocyclic copper and silver tertiary alkanethiolates: formation and molecular structures of (CuSBu-tert)4(Ph3P)2, (AgSCMeEt2)8(Ph3P)2 and (AgSBu-tert)14(Ph3P)4 and structural principles
Ian G. Dance, Lyn J. Fitzpatrick, Donald C. Craig, and Marcia L. Scudder
pp 1853 - 1861; DOI:
10.1021/ic00309a019
PDF
Cadmium polysulfide complexes, [Cd(Sx)(Sy)]2-: syntheses, crystal and molecular structures, and cadmium-113 NMR studies
R. M. Herath Banda, Ian G. Dance, Trevor D. Bailey, Donald C. Craig, and Marcia L. Scudder
pp 1862 - 1871; DOI:
10.1021/ic00309a020
PDF
Synthesis of binucleating tetratertiary phosphine ligand system and the structural characterization of both meso and racemic diastereomers of {bis[(diethylphosphinoethyl)phenylphosphino]methane}tetrachlorodinickel
Scott A. Laneman, Frank R. Fronczek, and George G. Stanley
pp 1872 - 1878; DOI:
10.1021/ic00309a021
PDF
Thermal and photochemical reactivity of group VI open-mode bimetallic complexes based on a binucleating hexaphosphine ligand system. Crystallographic characterization of a novel ditungsten heptacarbonyl pentaphosphine compound
Suzanne E. Saum, Frank R. Fronczek, Scott A. Laneman, and George G. Stanley
pp 1878 - 1884; DOI:
10.1021/ic00309a022
PDF
Competing formation of bridging diphenylphosphido and bridging (diphenylphosphino)cyclopentadienyl ligands during the reaction of [M(CO)5PPh2]- (M = Cr, Mo, W) with CpRu(CO)2Cl. X-ray structure of (CO)5W(.mu.-C5H4PPh2)Ru(CO)2(.mu.-CO)2Ru(CO)CP.cntdot.CH2Cl2
Martine Cazanoue, Noel Lugan, Jean Jacques Bonnet, and Rene Mathieu
pp 1884 - 1887; DOI:
10.1021/ic00309a023
PDF
Axial vs equatorial substitution of triosmium dodecacarbonyl with anionic ligands. Crystal and molecular structures of PPN[Os3X(CO)11] (X = Br, I)
Janet L. Zuffa, Steven J. Kivi, and Wayne L. Gladfelter
pp 1888 - 1895; DOI:
10.1021/ic00309a024
PDF
Pyrrolyl, hydroxo, and carbonate organometallic derivatives of nickel(II). Crystal and molecular structure of [Ni(CH2C6H4-o-Me)(PMe3)(.mu.-OH)]2.cntdot.2,5-HNC4H2Me2
Ernesto Carmona, Jose M. Marin, Pilar Palma, Margarita Paneque, and Manuel L. Poveda
pp 1895 - 1900; DOI:
10.1021/ic00309a025
PDF
Preparation of (.eta.-C5H5)W(CO)2(PPh3)SR and the insertion of carbon disulfide to give the thioxanthates (.eta.-C5H5)W(CO)2S2CSR (R = CHMe2, CH2Ph, and 4-C6H4Me). Crystal structure of (.eta.-C5H5)W(CO)2S2CSCH2Ph
Alan Shaver, Bernadette Soo Lum, Peter Bird, and Kevin Arnold
pp 1900 - 1904; DOI:
10.1021/ic00309a026
PDF
Nuclear magnetic resonance studies of dicopper(II) complexes with binucleating ligands containing imidazoles
Masahiko Maekawa, Susumu Kitagawa, Megumu Munakata, and Hideki Masuda
pp 1904 - 1909; DOI:
10.1021/ic00309a027
PDF
Kinetic proof that the tetranuclear oxocopper(II) complex (py)3Cu4Cl4O2 initiates and catalyzes the oxidative coupling of 2,6-dimethylphenol by dioxygen in nitrobenzene
Mohamed A. El-Sayed, Atieh Abu-Raqabah, Geoffrey Davies, and Ahmed El-Toukhy
pp 1909 - 1914; DOI:
10.1021/ic00309a028
PDF
Preparation, structure, and magnetochemistry of hexanuclear manganese oxide complexes: chemically and thermally induced aggregation of aquahexakis(benzoato)oxobis(pyridine)trimanganese forming products containing the [Mn6O2]10+ core
Ann R. Schake, John B. Vincent, Qiaoying Li, Peter D. W. Boyd, Kirsten Folting, John C. Huffman, David N. Hendrickson, and George Christou
pp 1915 - 1923; DOI:
10.1021/ic00309a029
PDF
Synthesis, characterization, and aqueous proton relaxation enhancement of a manganese(II) heptaaza macrocyclic complex having pendant arms
Bianke K. Wagnon and Susan C. Jackels
pp 1923 - 1927; DOI:
10.1021/ic00309a030
PDF
Metal complexes of .alpha.-hydroxyimino phosphonic acid derivatives. Separation of E and Z isomers by metal chelation and the preparation and characterization of copper bis[(E)-(.alpha.-(hydroxyimino)benzyl)phosphonate]-water
Dan Gibson and Rafik Karaman
pp 1928 - 1932; DOI:
10.1021/ic00309a031
PDF
Molecular structure of bis(L-leucinato)zinc(II) and single-crystal EPR spectra of the substitutionally copper(II)-63-doped complex
C. A. Steren, R. Calvo, O. E. Piro, and B. E. Rivero
pp 1933 - 1938; DOI:
10.1021/ic00309a032
PDF
Electronic and steric effects in the dissociative displacement of thioethers from mixed phenyl(thioether)platinum(II) complexes
Giuseppe Alibrandi, Domenico Minniti, Luigi Monsu Scolaro, and Raffaello Romeo
pp 1939 - 1943; DOI:
10.1021/ic00309a033
PDF
Synthesis and characterization of anionic platinum(II) complexes containing the tridentate ligand pyridine-2,6-dicarboxylato (O-N-O) and the kinetics of chloride displacement from [Pt(O-N-O)Cl]-
Lucio Cattalini, Gavino Chessa, Giampaolo Marangoni, Bruno Pitteri, and Eloisa Celon
pp 1944 - 1947; DOI:
10.1021/ic00309a034
PDF
Electron transfer. 98. Copper(II) and vanadium(IV) catalysis of the reduction of peroxide-bound chromium(IV) with ascorbic acid
S. K. Ghosh and E. S. Gould
pp 1948 - 1951; DOI:
10.1021/ic00309a035
PDF
Direct detection of aluminosilicate species in aqueous solution by silicon-29 and aluminum-27 NMR spectroscopy
Stephen D. Kinrade and Thomas W. Swaddle
pp 1952 - 1954; DOI:
10.1021/ic00309a036
PDF
Pentaammineruthenium(III) complexes of neutral and anionic (2,3-dichlorophenyl)cyanamide: a spectroscopic analysis of ligand to metal charge-transfer spectra
Robert J. Crutchley and Mark L. Naklicki
pp 1955 - 1958; DOI:
10.1021/ic00309a037
PDF
Crystal and molecular structure and magnetic properties of the .mu.-azido-bridged low-spin cobalt(II) complex [(CH3C(CH2PPh2)3)Co(.mu.-N3)]2(BPh4)2.cntdot.2(CH3)2CO
Alessandro Bencini, Carlo A. Ghilardi, Stefano Midollini, and Annabella Orlandini
pp 1958 - 1962; DOI:
10.1021/ic00309a038
PDF
Tetracyanoquinodimethane salts of transition-metal complexes. Crystal and molecular structures and magnetic properties of tris(1,10-phenanthroline)zinc(II) bis(tetracyanoquinodimethanide) and tris(1,10-phenanthroline)copper(II) bis(tetracyanoquinodimethanide)
Alessandro Bencini, Stefano Midollini, and Claudia Zanchini
pp 1963 - 1969; DOI:
10.1021/ic00309a039
PDF
Synthesis, x-ray crystal structure, and magnetic properties of two dinuclear manganese(II) compounds containing nitronyl nitroxides, imino nitroxides, and their reduced derivatives
A. Caneschi, Dante Gatteschi, J. Laugier, P. Rey, and C. Zanchini
pp 1969 - 1975; DOI:
10.1021/ic00309a040
PDF
Magnetic phase transition and low-temperature EPR spectra of a one-dimensional ferrimagnet formed by manganese(II) and a nitronyl nitroxide
Andrea Caneschi, Dante Gatteschi, Jean Pierre Renard, Paul Rey, and Roberta Sessoli
pp 1976 - 1980; DOI:
10.1021/ic00309a041
PDF
Kinetics and mechanism of the ligand substitution reactions of N-(hydroxyethyl)ethylenediaminetriacetate complexes of ruthenium(III) in aqueous solution
H. C. Bajaj and R. Van Eldik
pp 1980 - 1983; DOI:
10.1021/ic00309a042
PDF
Cobalt-induced facile degradation of phenylurea to ammonia, carbon dioxide, and anilinium ion and other reactions of linkage isomeric cobalt(III) complexes of phenylurea
David P. Fairlie, W. Gregory Jackson, and George M. McLaughlin
pp 1983 - 1989; DOI:
10.1021/ic00309a043
PDF
NMR study of acid-base equilibria and other reactions of ammineplatinum complexes with aqua and hydroxo ligands
Trevor G. Appleton, John R. Hall, Stephen F. Ralph, and Craig S. M. Thompson
pp 1989 - 1993; DOI:
10.1021/ic00309a044
PDF
Effects of inorganic countercations on the fluorescence spectra of the tetrakis(1-phenyl-1,3-butanedionato)europium(III) anion
G. M. Murray, L. L. Pesterfield, N. A. Stump, and G. K. Schweitzer
pp 1994 - 1998; DOI:
10.1021/ic00309a045
PDF
Synthesis and reaction chemistry of the coordinatively unsaturated heterobimetallic complexes (CO)3(PPh3)Fe(.mu.-PCy2)Rh(PPh3)(CO) and (CO)4Fe(.mu.-PCy2)Rh(1,5-COD). Crystal and molecular structure of (CO)3(PPh3)Fe(.mu.-PCy2)Rh(PPh3)(CO)
Hilary A. Jenkins, Stephen J. Loeb, and Douglas W. Stephan
pp 1998 - 2003; DOI:
10.1021/ic00309a046
PDF
Highly condensed titanoxanes: synthesis of closo-(Cp*Ti)4O6 and its transformation to bicyclo-(Cp*Ti)4O5Cl2 with TiCl4 as an oxide acceptor reagent
L. M. Babcock and W. G. Klemperer
pp 2003 - 2007; DOI:
10.1021/ic00309a047
PDF
Cyclopentadienylvanadium carbonyl derivatives as precursors to vanadium carbide
Gilbert M. Brown and Leon Maya
pp 2007 - 2010; DOI:
10.1021/ic00309a048
PDF
Synthesis and crystal and molecular structure of the neutral copper rhodium cluster compound [Rh9(CO)19(NCMe){Cu(NCMe)2}]
Gianfranco Ciani, Massimo Moret, Alessandro Fumagalli, and Secondo Martinengo
pp 2011 - 2013; DOI:
10.1021/ic00309a049
PDF
Four-electron oxidations by dioxo complexes of osmium(VI)
John C. Dobson and Thomas J. Meyer
pp 2013 - 2016; DOI:
10.1021/ic00309a050
PDF
A redetermination of the crystal and molecular structure of tris(bipyridine)chromium(III) hexafluorophosphate
Kevin V. Goodwin, William T. Pennington, and John D. Petersen
pp 2016 - 2018; DOI:
10.1021/ic00309a051
PDF
Synthesis and study of the fluxional behavior of octahedral manganese(I) complexes with a monodentate 1,8-naphthyridine ligand. X-ray crystal structure of fac-[Mn(.eta.1-1,8-naph)(.eta.2-phen)(CO)3]ClO4.1/2CH2Cl2 (naph = 1,8-naphthyridine, phen = o-phenanthroline) [Erratum to document cited in CA109(26):242942v]
Maria Jose Bermejo, Jose Ignacio Ruiz, Xavier Solans, and Jordi Vinaixa
pp 2018 - 2018; DOI:
10.1021/ic00309a052
PDF
Reaction of carbon monoxide and an isonitrile with octakis(triphenylphosphine)octagoldplatinum(2+). Crystal structure of Pt(CO)(AuPPh3)8(NO3)2.2C4H10O.2CH2Cl2 [Erratum to document cited in CA109(22):203777a]
R. P. F. Kanters, P. P. J. Schlebos, J. J. Bour, W. P. Bosman, H. J. Behm, and J. J. Steggerda
pp 2018 - 2018; DOI:
10.1021/ic00309a053
PDF

Issue 11


Complex hydrogen-bonded cations. X-ray crystal structure of benzylammonium tetrachloroaluminate chloride, [((C6H5CH2)NH3)4Cl][AlCl4]3, and its relevance to the structure of basic chloroaluminate room-temperature melts
Raymond H. Dubois, Michael J. Zaworotko, and Peter S. White
pp 2019 - 2020; DOI:
10.1021/ic00310a001
PDF
Photoinduced enantioselective and catalytic reduction of tris(acetylacetonato)cobalt with a chiral ruthenium photosensitizer
Katsutoshi Ohkubo, Taisuke Hamada, Tohru Inaoka, and Hitoshi Ishida
pp 2021 - 2022; DOI:
10.1021/ic00310a002
PDF
Facile oxygen exchange by cobalt cluster oxide ions with water-oxygen-18 in the gas phase
J. J. Klaassen and D. B. Jacobson
pp 2022 - 2024; DOI:
10.1021/ic00310a003
PDF
Soluble polychalcogenide chemistry of indium. Synthesis and characterization of [In2Se21]4-, the first indium polyselenide
Mercouri G. Kanatzidis and Sandeep Dhingra
pp 2024 - 2026; DOI:
10.1021/ic00310a004
PDF
Heterobimetallic gold-palladium phosphine cluster complexes. X-ray crystal and molecular structure of [Au8Pd(PPh3)8](NO3)2
Larry N. Ito, Brian J. Johnson, Ann M. Mueting, and Louis H. Pignolet
pp 2026 - 2028; DOI:
10.1021/ic00310a005
PDF
Nucleophilic activation of metal carbonyl clusters. Isolation and structure of the elusive chloride adduct undecacarbonylchlorotriruthenate(1-)
Tyrena Chin-Choy, William T. A. Harrison, Nancy Keder, Galen D. Stucky, and Peter C. Ford
pp 2028 - 2029; DOI:
10.1021/ic00310a006
PDF
NMR Study of the reactions of the cis-diamminediaquaplatinum(II) cation with glutathione and amino acids containing a thiol group
Trevor G. Appleton, Jeffrey W. Connor, John R. Hall, and Paul D. Prenzler
pp 2030 - 2037; DOI:
10.1021/ic00310a007
PDF
Structurally diverse manganese(III) Schiff base complexes: chains, dimers, and cages
Joseph A. Bonadies, Martin L. Kirk, Myoung Soo Lah, Dimitri P. Kessissoglou, William E. Hatfield, and Vincent L. Pecoraro
pp 2037 - 2044; DOI:
10.1021/ic00310a008
PDF
Structurally diverse manganese(III) Schiff base complexes: solution speciation via paramagnetic proton NMR spectroscopy and electrochemistry
Joseph A. Bonadies, Michael J. Maroney, and Vincent L. Pecoraro
pp 2044 - 2051; DOI:
10.1021/ic00310a009
PDF
Crystal structures of two salts of N-(phosphonomethyl)glycine and equilibria with hydrogen and bicarbonate ions
Paul H. Smith, F. Ekkehardt Hahn, Alain Hugi, and Kenneth N. Raymond
pp 2052 - 2061; DOI:
10.1021/ic00310a010
PDF
Ferric ion sequestering agents. 21. Synthesis and spectrophotometric and potentiometric evaluation of trihydroxamate analogs of ferrichrome
Chiu Yuen Ng, Steven J. Rodgers, and Kenneth N. Raymond
pp 2062 - 2066; DOI:
10.1021/ic00310a011
PDF
Interactions of guanine derivatives with ethylenediamine and diethylenetriamine complexes of palladium(II) in solution: Pd binding sites of the guanine ring and formation of a cyclic adduct, [{Pd(en)(guanine ring)}4]
Kiyoshi Uchida, Akira Toyama, Yukiko Tamura, Michiaki Sugimura, Fumiyuki Mitsumori, Yukio Furukawa, Hideo Takeuchi, and Issei Harada
pp 2067 - 2073; DOI:
10.1021/ic00310a012
PDF
Synthesis and properties of metal-substituted myoglobins
J. A. Cowan and Harry B. Gray
pp 2074 - 2078; DOI:
10.1021/ic00310a013
PDF
The complexation of aluminum with N-substituted 3-hydroxy-4-pyridinones
David J. Clevette, William O. Nelson, Agneta Nordin, Chris Orvig, and Staffan Sjoeberg
pp 2079 - 2081; DOI:
10.1021/ic00310a014
PDF
Oxomolybdenum(IV,V,VI) complexes: structures, reactivities, and criteria of detection of binuclear (.mu.-oxo)molybdenum(V) products in oxygen atom transfer systems
Julia A. Craig, Edgar W. Harlan, Barry S. Snyder, Mark A. Whitener, and R. H. Holm
pp 2082 - 2091; DOI:
10.1021/ic00310a015
PDF
Nitrosyl-, halogeno-, and oxomolybdenum complexes with the ligand 1-thia-4,7-diazacyclononane (L). Crystal structures of [LMo(CO)2NO]PF6, [LMo(NO)2Cl]PF6, LMoCl3, and [L2Mo2O4]ZnCl4.cntdot.H2O
Peter Hoffmann and Rainer Mattes
pp 2092 - 2096; DOI:
10.1021/ic00310a016
PDF
Preparation and characterization of four- and five-coordinate rhodium(I) complexes. Crystal structures of chloro(2-phenylazo)pyridine)(norbornadiene)rhodium(I), (2,2'-bipyridyl)(norbornadiene)rhodium(I) chloride hydrate, and chloro(2,2'-bipyridyl)(norbornadiene)rhodium(I)
Jennifer J. Robertson, Anders Kadziola, Ronald A. Krause, and Sine Larsen
pp 2097 - 2102; DOI:
10.1021/ic00310a017
PDF
Electron transfer in the mixed-valence complexes (E)- and (Z)-1,2-bis(1'-ethyl-1-ferrocenyl)-1,2-dimethylethylene
Teng Yuan Dong, Tze Juine Ke, Shie Ming Peng, and Show Kei Yeh
pp 2103 - 2106; DOI:
10.1021/ic00310a018
PDF
Synthesis, characterization, and x-ray crystal structures of the divalent titanium complex Ti(.eta.2-BH4)2(dmpe)2 and the unidentate tetrahydroborate complex V(.eta.1-BH4)2(dmpe)2
James A. Jensen and Gregory S. Girolami
pp 2107 - 2113; DOI:
10.1021/ic00310a019
PDF
Vanadium(III) tetrahydroborates. Preparation, reaction chemistry, and crystal structures of V(BH4)3(PMe3)2 and the oxo dimer [V(BH4)2(PMe3)2]2O
James A. Jensen and Gregory S. Girolami
pp 2114 - 2119; DOI:
10.1021/ic00310a020
PDF
Synthesis and properties of nitrosyl complexes of molybdenum and tungsten containing halide and trimethylphosphine ligands. Crystal and molecular structures of MoCl3(NO)(PMe3)3 and MoCl(NO)(S2CPMe3-S,S',C)(PMe3)2
Ernesto Carmona, Enrique Gutierrez-Puebla, Angeles Monge, Pedro J. Perez, and Luis J. Sanchez
pp 2120 - 2127; DOI:
10.1021/ic00310a021
PDF
Coordination chemistry of higher oxidation states. 30. Five-coordinate cobalt(III) phosphine complexes. Spectroscopic and cobalt K-edge EXAFS studies
William Levason, J. Steven Ogden, and Mark D. Spicer
pp 2128 - 2131; DOI:
10.1021/ic00310a022
PDF
Crystal structures and properties of two sodides and an electride
Steven B. Dawes, Donald L. Ward, Odette Fussa-Rydel, Rui H. Huang, and James L. Dye
pp 2132 - 2136; DOI:
10.1021/ic00310a023
PDF
Synthesis and molecular structure of two members of a new family of zinc organophosphates
Y. Ortiz-Avila, P. R. Rudolf, and A. Clearfield
pp 2137 - 2141; DOI:
10.1021/ic00310a024
PDF
Exchange interaction in multinuclear transition-metal complexes. 13. Exchange coupling in Cu2L2Cl2.cntdot.2CH3OH (LH = 8-(salicylideneamino)quinoline), a new compound with a temperature-dependent structure
B. Chiari, Olivo Piovesana, T. Tarantelli, and P. F. Zanazzi
pp 2141 - 2145; DOI:
10.1021/ic00310a025
PDF
Luminescence and metal-metal interactions in binuclear gold(I) compounds
Christopher King, Ju Chun Wang, M. Nazrul I. Khan, and John P. Fackler
pp 2145 - 2149; DOI:
10.1021/ic00310a026
PDF
Syntheses and crystal structures (No gold-hydrogen interactions) of gold phosphine luminescent complexes, [Au2(dppm)2][BH3CN]2 and [Au2(dppm)2(I)][Au(CN)2] and [Au2(dppm)2(S2CNEt2)][BH3CN]
M. Nazrul I. Khan, Christopher King, Dwight D. Heinrich, John P. Fackler, and Leigh C. Porter
pp 2150 - 2154; DOI:
10.1021/ic00310a027
PDF
Photophysical properties of M(CO)4(.alpha.,.alpha.'-diimine) (M = molybdenum, tungsten) complexes
Kathleen A. Rawlins and Alistair J. Lees
pp 2154 - 2160; DOI:
10.1021/ic00310a028
PDF
Molecular and electronic structure of siladiimide and other allenic X=Y=X compounds
Mark S. Gordon, Michael W. Schmidt, and S. Koseki
pp 2161 - 2163; DOI:
10.1021/ic00310a029
PDF
Low-spin tetracyanoferrate(II) and -(III) complexes of meso-type 1,2-diamines: synthesis and steric effects on chelate-ring conformation and rate of ligand dehydrogenation
Yoshitaka Kuroda, Noriko Tanaka, Masafumi Goto, and Tomoya Sakai
pp 2163 - 2169; DOI:
10.1021/ic00310a030
PDF
Synthesis, structural characterization, and properties of the [Mo2O2S9]2- thio anion and the [Mo4O4S18]2-, [Mo2O2S8(SCH3)]-, and [Mo2O2S8Cl]- derivatives
A. I. Hadjikyriacou and D. Coucouvanis
pp 2169 - 2177; DOI:
10.1021/ic00310a031
PDF
Selective and sequential reduction of polyhalosilanes with alkyltin hydrides
John J. D'Errico and Kenneth G. Sharp
pp 2177 - 2180; DOI:
10.1021/ic00310a032
PDF
Reduction of rhenium pentachloride in the presence of methyldiphenylphosphine to give mer-ReCl3(PMePh2)3, ReCl(.eta.2-H2)(PMePh2)4, ReH3(PMePh2)4, or ReCl(CO)3(PMePh2)2, depending on conditions
F. Albert Cotton and Rudy L. Luck
pp 2181 - 2186; DOI:
10.1021/ic00310a033
PDF
Insertion of tetrafluoroethylene and trifluorochloroethylene into nitrogen-chlorine bonds. A new route to perfluoroazaalkenes
Ghulam Sarwar, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 2187 - 2189; DOI:
10.1021/ic00310a034
PDF
Metal ion recognition in ligands with negatively charged oxygen donor groups. Complexation of iron(III), gallium(III), indium(III), aluminum(III), and other highly charged metal ions
Ann Evers, Robert D. Hancock, Arthur E. Martell, and Ramunas J. Motekaitis
pp 2189 - 2195; DOI:
10.1021/ic00310a035
PDF
Electron-transfer reactions of manganese(II) and -(III) polyamino carboxylate complexes in aqueous media
Donal H. Macartney and David W. Thompson
pp 2195 - 2199; DOI:
10.1021/ic00310a036
PDF
Electronic structure of the oxidation catalyst cis(bipyridine)oxo(pyridine) ruthenium(IV) diperchlorate
John C. Dobson, Jeffrey H. Helms, Pascal Doppelt, B. Patrick Sullivan, William E. Hatfield, and Thomas J. Meyer
pp 2200 - 2204; DOI:
10.1021/ic00310a037
PDF
Wavelength-dependent photochemical ligand substitution in pentacarbonyl(ligand)tungsten (ligand = pyridine piperidine)
Carol Moralejo, Cooper H. Langford, and D. K. Sharma
pp 2205 - 2209; DOI:
10.1021/ic00310a038
PDF
A 1,10-phenanthroline adduct complex of bis(N,N-diethyldithiocarbamato)nickel(II)
F. P. Emmenegger
pp 2210 - 2214; DOI:
10.1021/ic00310a039
PDF
Synthesis and crystal and molecular structure of the dimetalated rhodium olefin complex [Rh2(H3CN(P(OCH3)2)2)4(.mu.-H3CO2CC.tplbond.CCO2CH3)](ClO4)2.cntdot.CH3OH
Joel T. Mague
pp 2215 - 2217; DOI:
10.1021/ic00310a040
PDF
Evidence for the existence of the chloropentakis(THF)magnesium(1+) cation. Crystal structures of [MgCl(THF)5][FeCl4].cntdot.THF and [MgCl(THF)5][AlCl4].cntdot.THF
Piotr Sobota, Tadeusz Pluzinski, Jozef Utko, and Tadeusz Lis
pp 2217 - 2219; DOI:
10.1021/ic00310a041
PDF
Open cluster configurations of [1,1-(PPh3)2-1-H-1,2,4-IrC2B8H10] and other formally Wadian 24-electron 11-vertex species
Karl Nestor, Xavier L. R. Fontaine, Norman N. Greenwood, John D. Kennedy, Jaromir Plesek, Bohumil Stibr, and Mark Thornton-Pett
pp 2219 - 2221; DOI:
10.1021/ic00310a042
PDF
Production of an optically active sulfoxide by use of colloidally dispersed .LAMBDA.-tris(2,2'-bipyridyl)ruthenium(II) montmorillonite as a photosensitizer
Tokihisa Hikita, Kenzi Tamaru, Akihiko Yamagishi, and Toschitake Iwamoto
pp 2221 - 2223; DOI:
10.1021/ic00310a043
PDF
Synthesis and characterization of ((trimethylsilyl)amido)gallium dibromide
W. Rodger Nutt, Jeffery S. Blanton, Franklin O. Kroh, and Jerome D. Odom
pp 2224 - 2226; DOI:
10.1021/ic00310a044
PDF
Synthesis, structure, and magnetic behavior of a new .mu.-phenoxo manganese(II) dimer
Derek J. Hodgson, Barbara J. Schwartz, and Thomas N. Sorrell
pp 2226 - 2228; DOI:
10.1021/ic00310a045
PDF
Kinetic study of the rhodium(I)-catalyzed decarbonylation of phenylacetyl chloride
Jack A. Kampmeier and T. Z. Liu
pp 2228 - 2231; DOI:
10.1021/ic00310a046
PDF
(.mu.-4,4'-Dimethyl-2,2'-bipyridine)bis(pentacarbonylchromium): isolation and reactivity of a novel complex relevant to Group 6 metal tetracarbonyl chelate formation
Bernadette S. Creaven, Friedrich Wilhelm Grevels, and Conor Long
pp 2231 - 2234; DOI:
10.1021/ic00310a047
PDF
New pathway to heterodinuclear complexes with equivalent coordination sites: application of the cis-trans isomerization of the oxamido group
J. P. Costes and J. P. Laurent
pp 2234 - 2236; DOI:
10.1021/ic00310a048
PDF
Surprisingly high stability of alkali-metal complexes of the ligand tris(2-pyridylmethyl)amine (TPA)
Hans Toftlund and Shihichi Ishiguro
pp 2236 - 2238; DOI:
10.1021/ic00310a049
PDF

Issue 12


Conversion of tris[bis(diphenylphosphino)ethane]tetrahydridodirhenium to its conjugate acid [Re2H5(dppe)3]+ involving the switch in coordination mode of a dppe ligand from chelating to bridging
Phillip E. Fanwick, Dawn R. Root, and Richard A. Walton
pp 2239 - 2240; DOI:
10.1021/ic00311a001
PDF
Theoretical study by the X.alpha. method of platinum(III) complex ions containing aquo and chloro ligands
A. Goursot, H. Chermette, W. L. Waltz, and J. Lilie
pp 2241 - 2247; DOI:
10.1021/ic00311a002
PDF
Photolytic and radiolytic study of platinum(III) complex ions containing aquo and chloro ligands
W. L. Waltz, J. Lilie, A. Goursot, and H. Chermette
pp 2247 - 2256; DOI:
10.1021/ic00311a003
PDF
Polyhedral skeletal electron pair theory of bare clusters. 1. Small silicon clusters
Tom Slee, Zhenyang Lin, and D. M. P. Mingos
pp 2256 - 2261; DOI:
10.1021/ic00311a004
PDF
EPR study of manganese(II) and copper(II) in single crystals of the spin-crossover complex hexakis(1-propyltetrazole)iron(2+) tetrafluoroborate(1-)
A. Ozarowski and B. R. McGarvey
pp 2262 - 2266; DOI:
10.1021/ic00311a005
PDF
Electron spin resonance, infrared spectroscopic, and molecular packing studies of the thermally induced conversion of semiconducting .alpha.- to superconducting .alpha.t-(BEDT-TTF)2I3
Hau H. Wang, John R. Ferraro, K. Douglas Carlson, Lawrence K. Montgomery, Urs Geiser, Jack M. Williams, Julia R. Whitworth, John A. Schlueter, Steve Hill, and et al.
pp 2267 - 2271; DOI:
10.1021/ic00311a006
PDF
Effects of conformational change in the acceptor on intramolecular electron transfer
Pingyun Chen, Maria Curry, and Thomas J. Meyer
pp 2271 - 2280; DOI:
10.1021/ic00311a007
PDF
Photochemistry of hetero-tris-chelated ruthenium(II) polypyridine complexes in dichloromethane
Wayne E. Jones, Robert A. Smith, Marsha T. Abramo, Michael D. Williams, and J. Van Houten
pp 2281 - 2285; DOI:
10.1021/ic00311a008
PDF
Preparation, photochemistry, and electronic structures of coumarin laser dye complexes of cyclopentadienylruthenium(II)
Robert S. Koefod and Kent R. Mann
pp 2285 - 2290; DOI:
10.1021/ic00311a009
PDF
Comparison of the electronic structures of homo- and heteronuclear butterfly clusters containing carbide, nitride, and oxide ligands. Crystal and molecular structure of bis[diphenylphosphine] iminium dodecacarbonylnitridotetraruthenate(1-)
Suzanne Harris, Margaret L. Blohm, and Wayne L. Gladfelter
pp 2290 - 2297; DOI:
10.1021/ic00311a010
PDF
Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV) oxides in aqueous solution. 1. Formation of transient iron(III)-sulfur(IV) complexes
Jochen Kraft and Rudi Van Eldik
pp 2297 - 2305; DOI:
10.1021/ic00311a011
PDF
Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV) oxides in aqueous solution. 2. Decomposition of transient iron(III)-sulfur(IV) complexes
Jochen Kraft and Rudi Van Eldik
pp 2306 - 2312; DOI:
10.1021/ic00311a012
PDF
Synthesis and reactivity of pyridine N-oxide complexes of cobalt(III)
William L. Purcell
pp 2312 - 2315; DOI:
10.1021/ic00311a013
PDF
Substitution kinetics of technetium oxo complex trans-[O2(Py)4Tc]+ in methanol, DMF, and MeOH/DMF mixtures (Py = pyridine, picoline, and lutidine)
Jun Lu and M. J. Clarke
pp 2315 - 2319; DOI:
10.1021/ic00311a014
PDF
Kinetics of the bis(2,9-dimethyl-1,10-phenanthroline)copper(I/II) self exchange reaction in solution
Hideo Doine, Yoshiko Yano, and Thomas W. Swaddle
pp 2319 - 2322; DOI:
10.1021/ic00311a015
PDF
Square-planar copper(II) chelate complexes of the ONN,X type (X = monodentate ligand): kinetics of ligand substitution as studied in acetone and the effect of water
Juergen Roeper, Helmut Paulus, and Horst Elias
pp 2323 - 2329; DOI:
10.1021/ic00311a016
PDF
Hydrolysis of phosphate triesters with copper(II) catalysts
Janet R. Morrow and William C. Trogler
pp 2330 - 2333; DOI:
10.1021/ic00311a017
PDF
Skeletally stabilized triphosphazanes: new classes of linear phosphazanes
Joseph M. Barendt, Elizabeth G. Bent, R. Curtis Haltiwanger, and Arlan D. Norman
pp 2334 - 2339; DOI:
10.1021/ic00311a018
PDF
Reactions of nitriles with polyhedral borane anions. Reductive cyclocondensation and carbon insertion reactions: syntheses of hypho-5-CH3-5,11,7,14-CNS2B7H9 and nido-6-CH3-5,6,9-C3B7H10
Sang Ook Kang, George T. Furst, and Larry G. Sneddon
pp 2339 - 2347; DOI:
10.1021/ic00311a019
PDF
Complexes of rhenium carbonyl containing ferrocenyl-derived ligands: tunable electron density at rhenium by control of the redox state of the ferrocenyl ligand
Timothy M. Miller, Kazi J. Ahmed, and Mark S. Wrighton
pp 2347 - 2355; DOI:
10.1021/ic00311a020
PDF
Asymmetric distannoxane dimers
David C. Gross
pp 2355 - 2359; DOI:
10.1021/ic00311a021
PDF
New adamantane-like mercury-chalcogen cages. 2. Synthetic and multinuclear (phosphorus-31, selenium-77, tellurium-125, mercury-199) magnetic resonance study of tellurolate-bridged mercury(II) clusters [(.mu.-TeR)6(HgPR'3)4]2+ and [(.mu.-TeR)6(Hg)(HgPR'3)3]2+ and related species with mixed-bridging chalcogenates
Philip A. W. Dean, Veeragathy Manivannan, and Jagadese J. Vittal
pp 2360 - 2368; DOI:
10.1021/ic00311a022
PDF
Iron(II) and copper(II) complexes of N-(2-(imidazol-3-yl)ethyl-6-(((2-(imidazol-3-yl)ethyl)amino)methyl)-2-pyridinecarboxamide, a bleomycin metal binding site analog with apical imidazole coordination
Thomas J. Lomis, Michael G. Elliott, Shirin Siddiqui, Maria Moyer, Richard R. Koepsel, and Rex E. Shepherd
pp 2369 - 2377; DOI:
10.1021/ic00311a023
PDF
Binding of fluoride to copper zinc superoxide dismutase
L. Banci, I. Bertini, C. Luchinat, A. Scozzafava, and P. Turano
pp 2377 - 2381; DOI:
10.1021/ic00311a024
PDF
An unusual mixed-metal cluster: synthesis and molecular structure of nonacarbonyltetrakis(triethylphosphine)ironpentaplatinum
Robert Bender, Pierre Braunstein, Daniel Bayeul, and Yves Dusausoy
pp 2381 - 2384; DOI:
10.1021/ic00311a025
PDF
Synthesis and characterization of [.mu.-bis(diphenylphosphino)methane]bis[.eta.1-bis(diphenylphosphino)methane]-.mu.-sulfidodiplatinum and its use in formation of tetranuclear platinum complexes with .mu.4-S ligands
Nasim Hadj-Bagheri and Richard J. Puddephatt
pp 2384 - 2388; DOI:
10.1021/ic00311a026
PDF
Bi- and trinuclear platinum-silver complexes with or without platinum-silver bonds. Molecular structure of [PPh3(C6Cl5)ClPt(.mu.-Cl)AgPPh3]
Rafael Uson, Juan Fornies, Milagros Tomas, Irene Ara, and Jose M. Casas
pp 2388 - 2392; DOI:
10.1021/ic00311a027
PDF
Preparation, structure and redox activity of nickel(II), palladium(II), and copper(II) cofacial binuclear bis(.beta.-keto-enamine) complexes
Julie R. Bradbury, Jacqueline L. Hampton, Daniel P. Martone, and Andrew W. Maverick
pp 2392 - 2399; DOI:
10.1021/ic00311a028
PDF
Reactivity of a lithium nickel acylate complex in THF
Joan L. Simunic and Allan R. Pinhas
pp 2400 - 2406; DOI:
10.1021/ic00311a029
PDF
Preparation and spectral properties of a series of bis(phosphite) alkyne complexes and x-ray crystal structure of [WI2(CO){P(OMe)3}2(.eta.2-MeC.tplbond.CMe)]
Paul K. Baker, Elaine M. Armstrong, and Michael G. B. Drew
pp 2406 - 2410; DOI:
10.1021/ic00311a030
PDF
Arene-to-alkyne linkage isomerizations of diphenylacetylene on pentaammineosmium
W. Dean Harman, James F. Wishart, and Henry Taube
pp 2411 - 2413; DOI:
10.1021/ic00311a031
PDF
.eta.6-Arene displacement by halide ions. Synthesis and structural characterization of chloro- and fluoro-bridged organonickel complexes [R2MX]22- (R = C6F5, SiCl3, X = halide)
Michael M. Brezinski, Jeorg Schneider, Lewis J. Radonovich, and Kenneth J. Klabunde
pp 2414 - 2419; DOI:
10.1021/ic00311a032
PDF
Reactivity of coordinated peroxide at a highly peroxygenated vanadium(V) center in an aqueous medium
Manabendra N. Bhattacharjee, Mihir K. Chaudhuri, and Nashreen S. Islam
pp 2420 - 2423; DOI:
10.1021/ic00311a033
PDF
Optical versus thermal electron transfer between iridium(I) maleonitriledithiolate complexes and methyl viologen
Elise Graham Megehee, Curtis E. Johnson, and Richard Eisenberg
pp 2423 - 2431; DOI:
10.1021/ic00311a034
PDF
Structure and reactivity of chromium(4+) tert-butoxide
Eric G. Thaler, Kristin Rypdal, Arne Haaland, and Kenneth G. Caulton
pp 2431 - 2434; DOI:
10.1021/ic00311a035
PDF
X-ray diffraction study of calcium(II) chloride hydrate melts: CaCl2.cntdot.RH2O (R = 4.0, 5.6, 6.0, and 8.6)
Toshio Yamaguchi, Shunichi Hayashi, and Hitoshi Ohtaki
pp 2434 - 2439; DOI:
10.1021/ic00311a036
PDF
Pillaring of montmorillonite by organotin cationic complexes
D. Petridis, T. Bakas, A. Simopoulous, and N. H. J. Gangas
pp 2439 - 2443; DOI:
10.1021/ic00311a037
PDF
Crystallographic and magnetic studies of an unusual Mo3O13 cluster compound, sodium molybdoindate [Na2In2Mo5O16]
B. T. Collins, S. M. Fine, J. A. Potenza, M. Greenblatt, and P. P. Tsai
pp 2444 - 2447; DOI:
10.1021/ic00311a038
PDF
Rhenium chalcogenides Tl4Re6X12 (X = S, Se): crystal growth, structure and properties
G. Huan, M. Greaney, P. P. Tsai, and M. Greenblatt
pp 2448 - 2451; DOI:
10.1021/ic00311a039
PDF
Resitivity anomalies of the diphosphate tungsten bronze Cs1-xP8W8O40(x = 0-0.46) and its partially substituted phases CsxAyP8W8O40 (A = Rb, Na) and CsP8W8-xMoxO40: synthesis, physical property measurements, and band electronic structure calculations
Enoch Wang, Martha Greenblatt, Idris El Idrissi Rachidi, Enric Canadell, and Myung Hwan Whangbo
pp 2451 - 2455; DOI:
10.1021/ic00311a040
PDF
Structural and electronic origin of the three-dimensional electrical properties of tungsten oxyphosphate, P8W12O52, and its inserted and substituted analogs AxP8W12O52 (A = Li, Na) and P8W12-xMoxO52
Enric Canadell, Idris El Idrissi Rachidi, Enoch Wang, Martha Greenblatt, and Myung Hwan Whangbo
pp 2455 - 2459; DOI:
10.1021/ic00311a041
PDF
Efficient reduction of dioxygen with ferrocene derivatives, catalyzed by metalloporphyrins in the presence of perchloric acid
Shunichi Fukuzumi, Seiji Mochizuki, and Toshio Tanaka
pp 2459 - 2465; DOI:
10.1021/ic00311a042
PDF
Resonance Raman spectra and spectroelectrochemical properties of mono- and polymetallic ruthenium complexes with 1,4,5,8,9,12-hexaazatriphenylene
A. Kirsch-De Mesmaeker, L. Jacquet, A. Masschelein, F. Vanhecke, and K. Heremans
pp 2465 - 2470; DOI:
10.1021/ic00311a043
PDF
Ligand-centered redox processes for manganese, iron and cobalt, MnL3, FeL3, and CoL3, complexes (L = acetylacetonate, 8-quinolinate, picolinate, 2,2'-bipyridyl, 1,10-phenanthroline) and for their tetrakis(2,6-dichlorophenyl)porphinato complexes[M(Por)]
Silvia A. Richert, Paul K. S. Tsang, and Donald T. Sawyer
pp 2471 - 2475; DOI:
10.1021/ic00311a044
PDF
Mixed platinum-rhodium carbonyl clusters. Synthesis and chemical characterization of the [PtRh6(.mu.3-CO)3(.mu.-CO)5(CO)8]2- anion and x-ray crystal structure of its tetrapropylammonium salt
Alessandro Fumagalli, Secondo Martinengo, Daniele Galli, Alberto Albinati, and Fabio Ganazzoli
pp 2476 - 2479; DOI:
10.1021/ic00311a045
PDF
Anaerobic complexation of cobalt(II) by [3k]aneNk (k = 7-12) polyazacycloalkanes
Andrea Bencini, Antonio Bianchi, Enrique Garcia-Espana, Mauro Micheloni, and Piero Paoletti
pp 2480 - 2482; DOI:
10.1021/ic00311a046
PDF
Molecular structure of hexakis(N,N'-diethylurea)manganese(II) tetrabromomanganate(II)
Jacqueline Delaunay and Rene P. Hugel
pp 2482 - 2485; DOI:
10.1021/ic00311a047
PDF
Synthesis and structural characterization of a new polymorph of tungsten(VI) sulfide tetrachloride, WSCl4
F. Albert Cotton, Piotr A. Kibala, and Robert B. W. Sandor
pp 2485 - 2487; DOI:
10.1021/ic00311a048
PDF
Assignment of the intense UV bands in the solution electronic spectrum of tetracyanonickelate(2-). MCD spectra for the 3.7- and 5.0-.mu.m-1 bands
W. Roy Mason
pp 2487 - 2489; DOI:
10.1021/ic00311a049
PDF
On photochemical observations in solutions of sulfur in liquid ammonia
P. Dubois, J. P. Lelieur, and G. Lepoutre
pp 2489 - 2491; DOI:
10.1021/ic00311a050
PDF
Dimeric complex of a reduced nitroxyl radical with bis(hexafluoroacetylacetonato)manganese(II)
Michael D. Carducci and Robert J. Doedens
pp 2492 - 2494; DOI:
10.1021/ic00311a051
PDF
"Electron-deficient" trigonal-planar tin- and lead-containing iron carbonyl complexes: [Et4N]2[E{Fe(CO)4}3] (E = Sn, Pb)
Juanita M. Cassidy and Kenton H. Whitmire
pp 2494 - 2496; DOI:
10.1021/ic00311a052
PDF
Uranium alkoxide chemistry. 3. tert-Butylisocyanide adducts of tris(2,6-di-tert-butylphenoxy)uranium(III)
William G. Van der Sluys and Alfred P. Sattelberger
pp 2496 - 2498; DOI:
10.1021/ic00311a053
PDF
2,4,6-Tris[(pentafluorothio)methyl]-1,3,5-trioxane
R. Winter, R. D. Willett, and Gary L. Gard
pp 2499 - 2501; DOI:
10.1021/ic00311a054
PDF
Pentakis(1,2-benzenedithiolato)dimolybdenum, the purple product in molybdenum-dithiol reactions: a novel molybdenum(V) dimer dithiolate structure
Thomas R. Halbert and Edward I. Stiefel
pp 2501 - 2503; DOI:
10.1021/ic00311a055
PDF
Isolation and characterization of the rhenium hydrido trimethylphosphine redox pair [Re2H5(PMe3)6](PF6)n (n = 1 or 2)
Dawn R. Root, Karen E. Meyer, and Richard A. Walton
pp 2503 - 2506; DOI:
10.1021/ic00311a056
PDF
Synthesis and structural investigation of polyoxomolybdate coordination compounds displaying a tetranuclear core. Crystal and molecular structures of [Bu4N]2[Mo4O10(OMe)2(OC6H4O)2] and to the diazenido complexes [Bu4N]2[Mo4O6(OMe)2(HNC6H4O)2(NNC6H5)4] and [Bu4N]2[Mo4O6(OMe)2(C10H6O2)2(NNC6H5)4]. Comparison to a binuclear complex with the [Mo2(OMe)2(NNC6H5)4]2+ core, [Mo2(OMe)2(H2NC6H4O)] [Erratum to document cited in CA110(14):127491f]
Hyunkyu Kang, Shuncheng Liu, Shahid N. Shaikh, Terrence Nicholson, and Jon Zubieta
pp 2506 - 2506; DOI:
10.1021/ic00311a057
PDF

Issue 13


A (.mu.-oxo)(.mu.-carboxylato)diiron(III) complex with distinct iron sites
Shiping Yan, David D. Cox, Linda L. Pearce, Carlos Juarez-Garcia, Lawrence Que, Jian H. Zhang, and Charles J. O'Connor
pp 2507 - 2509; DOI:
10.1021/ic00312a001
PDF
Excited states of polyoxometalates as oxidatively resistant initiators of hydrocarbon autoxidation. Selective production of hydroperoxides
R. Carlisle Chambers and Craig L. Hill
pp 2509 - 2511; DOI:
10.1021/ic00312a002
PDF
Kinetics of the homolytic dioxygen insertion into the cobalt-carbon bond in (nta)(H2O)CoIII-CH3-
Alexandra Sauer, Haim Cohen, and Dan Meyerstein
pp 2511 - 2512; DOI:
10.1021/ic00312a003
PDF
Chemistry of high-valent transition-metal polytellurides: preparation and structure of oxy tellurides and ditellurolenes of molybdenum and tungsten
Walter A. Flomer and Joseph W. Kolis
pp 2513 - 2517; DOI:
10.1021/ic00312a004
PDF
Photoreactivity of .sigma.-bonded metalloporphyrins. 1. Formation of zwitterionic indium and gallium porphyrin complexes in tetrahydrofuran
K. M. Kadish, G. B. Maiya, and Q. Y. Xu
pp 2518 - 2523; DOI:
10.1021/ic00312a005
PDF
Photoreactivity of .sigma.-bonded metalloporphyrins. 2. Germanium porphyrin complexes with .sigma.-bonded alkyl, aryl, or ferrocenyl groups. Intramolecular quenching of porphyrin excited triplet states by linked ferrocene
G. B. Maiya, J. M. Barbe, and K. M. Kadish
pp 2524 - 2527; DOI:
10.1021/ic00312a006
PDF
Electrochemical and spectral characterization of copper, zinc, and vanadyl meso-tetrakis(1-methylpyridinium-4-yl)porphyrin complexes in dimethylformamide
K. M. Kadish, C. Araullo, G. B. Maiya, D. Sazou, J. M. Barbe, and R. Guilard
pp 2528 - 2533; DOI:
10.1021/ic00312a007
PDF
Influence of trans axial ligands on five-coordinate .sigma.-bonded metalloporphyrins. Structural, electrochemical, and spectral investigations of (OEP)Ir(C3H7)(L) complexes
Karl M. Kadish, J. L. Cornillon, P. Mitaine, Y. J. Deng, and J. D. Korp
pp 2534 - 2542; DOI:
10.1021/ic00312a008
PDF
Electrochemistry of nickel picket fence porphyrin. Electrogeneration and spectral characterization of nickel complexes in unusual oxidation states
K. M. Kadish, D. Sazou, G. B. Maiya, B. C. Han, Y. M. Liu, A. Saoiabi, M. Ferhat, and R. Guilard
pp 2542 - 2547; DOI:
10.1021/ic00312a009
PDF
The triamminecopper(I) ion in aqueous solution. Spectral and photochemical evidence for charge-transfer-to-solvent (CTTS) behavior
Otto Horvath and Kenneth L. Stevenson
pp 2548 - 2551; DOI:
10.1021/ic00312a010
PDF
Homo- and heterobimetallic trihydride complexes stabilized by the tripodal phosphine ligand MeC(CH2PPh2)3: experimental and theoretical studies
Claudio Bianchini, Franco Laschi, Dante Masi, Carlo Mealli, Andrea Meli, Francesca M. Ottaviani, Davide M. Proserpio, Michal Sabat, and Piero Zanello
pp 2552 - 2560; DOI:
10.1021/ic00312a011
PDF
Isomers and isomerizations in heteroatomic and substituted P73- and related systems
Benjamin M. Gimarc and Jane J. Ott
pp 2560 - 2564; DOI:
10.1021/ic00312a012
PDF
Syntheses, absorption spectra, luminescence properties, and electrochemical behavior of mono- and binuclear ruthenium(II) complexes of isomeric bis(2-pyridyl)pyrazines
Sebastiano Campagna, Gianfranco Denti, Giuseppina De Rosa, Luigina Sabatino, Mauro Ciano, and Vincenzo Balzani
pp 2565 - 2570; DOI:
10.1021/ic00312a013
PDF
Far-IR spectra and normal-coordinate analyses of halogenopentaamminechromium(III) complexes
Hans Herbert Schmidtke and Manuela Rosner
pp 2570 - 2574; DOI:
10.1021/ic00312a014
PDF
Perturbations of the low-energy doublet excited state of chromium(III). Competing heavy-atom and macrocyclic ligand effects in thermally activated relaxation pathways
Ronald B. Lessard, John F. Endicott, Marc W. Perkovic, and L. A. Ochrymowycz
pp 2574 - 2583; DOI:
10.1021/ic00312a015
PDF
Ab initio MO study of carbon dioxide insertion into a copper(I)-hydrogen bond. Semiquantitative understanding of changes in geometry, bonding, and electron distribution during the reaction
Shigeyoshi Sakaki and Katsutoshi Ohkubo
pp 2583 - 2590; DOI:
10.1021/ic00312a016
PDF
Structure and properties of the hydride-containing cluster ion hydrido(triphenylphosphine)heptakis[(triphenylphosphine)gold]platinum(2+)
R. P. F. Kanters, J. J. Bour, P. P. J. Schlebos, W. P. Bosman, H. Behm, J. J. Steggerda, L. N. Ito, and L. H. Pignolet
pp 2591 - 2594; DOI:
10.1021/ic00312a017
PDF
Reactions of a phosphoranide platinum(II) complex with nucleophilic and electrophilic reagents and the x-ray crystal structures of (.eta.2-cyclenP)Pt[Co(CO)4]PPh3 and (.eta.2-cyclenP)Pt(I)PPh3
Dilip V. Khasnis, Michael Lattman, and Upali Siriwardane
pp 2594 - 2600; DOI:
10.1021/ic00312a018
PDF
Reactivity of ceric ammonium nitrate with sodium cyclopentadienide. The x-ray crystal structure of bis(dimethoxyethane)trinitratocerium
Peter S. Gradeff, Kenan Yunlu, Timothy J. Deming, Jeffrey M. Olofson, Joseph W. Ziller, and William J. Evans
pp 2600 - 2604; DOI:
10.1021/ic00312a019
PDF
Tetrakis(pyridine)tetrachloro(.mu.-chloro)(.mu.-hydrido)ditungsten (W-W) and its 4-ethylpyridine homolog. Compounds derived from a quadruply bonded dimer by ligand exchange and oxidative addition of hydrogen chloride
Richard T. Carlin and Robert E. McCarley
pp 2604 - 2608; DOI:
10.1021/ic00312a020
PDF
Synthesis and characterization of a new series of zinc phosphites
C. Yolanda Ortiz-Avila, Philip J. Squattrito, Minghuey Shieh, and Abraham Clearfield
pp 2608 - 2615; DOI:
10.1021/ic00312a021
PDF
Mercury complexes with one-dimensional chain structures. Syntheses and crystal structures of polymeric (acetato)(mercaptopyridinato)mercury, bis(mercaptopyridinato)mercury and bis(thioxodiphenylphosphinomethyl)mercury
Suning Wang and John P. Fackler
pp 2615 - 2619; DOI:
10.1021/ic00312a022
PDF
Structure and magnetic properties of bis[(2,6-diacetylpyridine dioxime)chlorocopper(II)] tetrachlorocuprate
Igor V. Vasilevsky, Ronald E. Stenkamp, Edward C. Lingafelter, Verner Schomaker, Roger D. Willett, and Norman J. Rose
pp 2619 - 2623; DOI:
10.1021/ic00312a023
PDF
Synthesis and structural characterization of three new trinuclear Group VI clusters
F. Albert Cotton, Piotr A. Kibala, Marek Matusz, Charla S. McCaleb, and Robert B. W. Sandor
pp 2623 - 2630; DOI:
10.1021/ic00312a024
PDF
Solid-state distortions of nominally square-planar palladium and platinum (R3P)2MX2 complexes as determined by a combination of carbon-13 {proton} and phosphorus-31{proton} NMR spectroscopy
Jeffrey A. Rahn, Daniel J. O'Donnell, Allen R. Palmer, and John H. Nelson
pp 2631 - 2635; DOI:
10.1021/ic00312a025
PDF
A new yttrium sesquichloride nitride, .beta.-Y2Cl3N, that is isostructural with the binary yttrium sesquichloride
H. Juergen Meyer, Nancy L. Jones, and John D. Corbett
pp 2635 - 2637; DOI:
10.1021/ic00312a026
PDF
Complexes of lanthanoid salts with macrocyclic ligands. 36. Macrocyclic effect in lanthanoid complexes with 12-, 15-, 18-, and 21-membered crown ethers
Jean Claude G. Buenzli and Francis Pilloud
pp 2638 - 2642; DOI:
10.1021/ic00312a027
PDF
Variable-pressure kinetic study of formation and dissociation of octahedral divalent metal ion monocomplexes in N,N-dimethylformamide: dissociative reaction mechanisms through the first row from manganese to nickel
Yves Ducommun, Peter J. Nichols, and Andre E. Merbach
pp 2643 - 2647; DOI:
10.1021/ic00312a028
PDF
New synthetic cobalt Schiff base complexes as oxygen carriers
Dian Chen, Arthur E. Martell, and Yizhen Sun
pp 2647 - 2652; DOI:
10.1021/ic00312a029
PDF
Cyclic voltammetry of mono- and diiron(II)Cyclopentadienyl complexes of thianthrene and related heterocycles
R. Quin Bligh, Roger Moulton, Allen J. Bard, Adam Piorko, and Ronald G. Sutherland
pp 2652 - 2659; DOI:
10.1021/ic00312a030
PDF
Boron-nitrogen compounds. 119. Reactions of boron heterocycles with pyrazole
C. Habben, L. Komorowski, W. Maringgele, A. Meller, and K. Niedenzu
pp 2659 - 2663; DOI:
10.1021/ic00312a031
PDF
A study of the carbon-13 chemical shift anisotropy in metal acetylides
T. M. Duncan
pp 2663 - 2668; DOI:
10.1021/ic00312a032
PDF
Reaction of dimethyl acetylenedicarboxylate with nonaselenidotungstate(2-) and decaselenidoditungstate(2-): synthesis and characterization of the [W(Se2C2(COOCH3)2)3]2- and [W2Se2(Se2C2(COOCH3)2)4]2- anions
Mohammad A. Ansari, Charles H. Mahler, and James A. Ibers
pp 2669 - 2674; DOI:
10.1021/ic00312a033
PDF
Spectroscopy and linkage isomerization kinetics of (chloranilato)bis(phosphine)palladium(II) compounds
Woo Yeong Jeong and Robert A. Holwerda
pp 2674 - 2679; DOI:
10.1021/ic00312a034
PDF
Chemistry of ferro- and ferriverdins. Iron redox and geometrical stereodynamism
Partha Basu, Suranjan Bhanja Choudhury, Samudranil Pal, and Animesh Chakravorty
pp 2680 - 2686; DOI:
10.1021/ic00312a035
PDF
Complex formation of aminopolyphosphonates. 2. Stability and structure of nitrilotris(methylenephosphonato) complexes of the divalent transition metal ions in aqueous solution
Kiyoshi Sawada, Tsutomu Araki, Toshio Suzuki, and Kunio Doi
pp 2687 - 2688; DOI:
10.1021/ic00312a036
PDF
Volume of activation for the axial substitution reaction of monoligated chloro(5,10,15,20-tetraphenylporphinato)chromium(III) via a limiting dissociative mechanism
Masahiko Inamo, Tatsumi Sumi, Nami Nakagawa, Shigenobu Funahashi, and Motoharu Tanaka
pp 2688 - 2691; DOI:
10.1021/ic00312a037
PDF
Intermediates in the early events of molybdate (Mo7O246-)-catalyzed photodehydrogenations: a picosecond-nanosecond flash-photochemical study
B. Kraut and G. Ferraudi
pp 2692 - 2694; DOI:
10.1021/ic00312a038
PDF

Issue 14


Base hydrolysis of triamminetrinitrocobalt
Shiv Singh and R. Shanker
pp 2695 - 2696; DOI:
10.1021/ic00313a001
PDF
Stability range of heterometal cubane-type clusters MFe3S4: assembly of double-cubane clusters with the rhenium-iron-sulfur [[ReFe3S4]] core
Stefano Ciurli, Michael J. Carney, R. H. Holm, and G. C. Papaefthymiou
pp 2696 - 2698; DOI:
10.1021/ic00313a002
PDF
High-pressure NMR study. 38. Water-exchange mechanisms on the terbium to thulium octaaqualanthanide(III) ions: a variable-pressure oxygen-17 NMR study
Cedric Cossy, Lothar Helm, and Andre E. Merbach
pp 2699 - 2703; DOI:
10.1021/ic00313a003
PDF
Kinetics and mechanism for reaction between ammine- and haloamminegold(III) complexes and thiocyanate. Competitive electron transfer and substitution
Sofi Elmroth, L. H. Skibsted, and Lars I. Elding
pp 2703 - 2710; DOI:
10.1021/ic00313a004
PDF
Titanium(III) reduction of axially substituted metal-metal-bonded diruthenium complexes
Anne C. Dema and Rathindra N. Bose
pp 2711 - 2713; DOI:
10.1021/ic00313a005
PDF
Reduction of (pyruvato)pentaamminecobalt(III) by chromium(II) and the chromium(III) pyruvate product
M. J. Sisley and R. B. Jordan
pp 2714 - 2717; DOI:
10.1021/ic00313a006
PDF
Arsenic(IV). A pulse-radiolysis study
Ulrik K. Klaening, Benon H. J. Bielski, and K. Sehested
pp 2717 - 2724; DOI:
10.1021/ic00313a007
PDF
Micellar effects on the aggregation of tetraanionic porphyrins. Spectroscopic characterization of free-base meso-tetrakis(4-sulfonatophenyl)porphyrin, (TPPS)H2, and (TPPS)M (M = zinc(II), copper(II), and vanadyl) in aqueous micellar media
Karl M. Kadish, G. B. Maiya, C. Araullo, and R. Guilard
pp 2725 - 2731; DOI:
10.1021/ic00313a008
PDF
Electrochemistry of niobium chloride and oxide chloride complexes in the basic aluminum chloride-1-methyl-3-ethylimidazolium chloride room-temperature ionic liquid
I Wen Sun and Charles L. Hussey
pp 2731 - 2737; DOI:
10.1021/ic00313a009
PDF
Comparison of the electronic structures of chromate, halochromates, and chromyl halides by the X.alpha. method
R. M. Miller, D. S. Tinti, and D. A. Case
pp 2738 - 2743; DOI:
10.1021/ic00313a010
PDF
Electronic structure of one-dimensional linear halogen-bridged gold chains
Christoph Janiak and Roald Hoffmann
pp 2743 - 2747; DOI:
10.1021/ic00313a011
PDF
Splitting of cluster orbitals
David J. Wales and D. Michael P. Mingos
pp 2748 - 2754; DOI:
10.1021/ic00313a012
PDF
Skeletal rearrangements in clusters. 2
David J. Wales, D. Michael P. Mingos, and Zhenyang Lin
pp 2754 - 2764; DOI:
10.1021/ic00313a013
PDF
Investigation of lithium-water interactions in acetonitrile solutions using proton nuclear magnetic resonance, Raman, and infrared spectroscopies and extended Hueckel molecular orbital calculations
R. Gerald Keil, David W. Johnson, Mark A. Fryling, and James F. O'Brien
pp 2764 - 2766; DOI:
10.1021/ic00313a014
PDF
A ligand-field probe of transition-metal-oxygen ligations
Neil D. Fenton and Malcolm Gerloch
pp 2767 - 2772; DOI:
10.1021/ic00313a015
PDF
Canted antiferromagnetism in single-crystal cobalt(II) oxydiacetate trihydrate
Brian R. Rohrs and William E. Hatfield
pp 2772 - 2775; DOI:
10.1021/ic00313a016
PDF
Rubidium(1+) and cesium(1+) incorporation mechanism and hydrate structures of layered hydrous titanium dioxide
Takayoshi Sasaki, Yu Komatsu, and Yoshinori Fujiki
pp 2776 - 2779; DOI:
10.1021/ic00313a017
PDF
Oxidative decarbonylation of metal carbonyls as a route to novel metal sulfur and selenium compounds. Structure of tris(tetraphenylphosphonium) tris(dithiocarbonato)chromate(3-)
S. C. O'Neal and J. W. Kolis
pp 2780 - 2783; DOI:
10.1021/ic00313a018
PDF
Synthesis and coordination properties of (sulfinylmethyl)phosphonates and (sulfonylmethyl)phosphonates. Crystal and molecular structure determinations for UO2(NO3)2[(iso-C3H7O)2P(O)CH2S(O)2C6H11]2 and Gd(NO3)3[(iso-C3H7O)2P(O)CH2S(O)(p-CH3C6H4)].H2O
S. Karthikeyan, R. R. Ryan, and R. T. Paine
pp 2783 - 2789; DOI:
10.1021/ic00313a019
PDF
Influence of .pi.-donation on N-methyl group exchange in zirconocene N,N-dimethyldithiocarbamates and N,N-dimethylthiocarbamates
Douglas A. Femec, Michael E. Silver, and Robert C. Fay
pp 2789 - 2796; DOI:
10.1021/ic00313a020
PDF
Metal cluster topology. 10. Polyhedral gallium cluster anions in intermetallic phases of gallium and alkali metals
R. B. King
pp 2796 - 2799; DOI:
10.1021/ic00313a021
PDF
Chemical vapor deposition experiments using new fluorinated acetylacetonates of calcium, strontium, and barium
A. P. Purdy, A. D. Berry, R. T. Holm, M. Fatemi, and D. K. Gaskill
pp 2799 - 2803; DOI:
10.1021/ic00313a022
PDF
Lewis base properties of 1.lambda.5,3.lambda.5-diphospha-5-thia-2,4,6-triazines: crystal and molecular structures of (Ph4P2N3SPh)Me+ CF3SO3-
Tristram Chivers, James Fait, and Stephen W. Liblong
pp 2803 - 2806; DOI:
10.1021/ic00313a023
PDF
Proton NMR study of the dissociation of the lanthanum cryptate of 4,7,13,16,21-pentaoxa-1,10-diazabicyclo[8.8.5]tricosane
Richard A. Torres and Patricia A. Baisden
pp 2807 - 2810; DOI:
10.1021/ic00313a024
PDF
Metal-templated synthesis of macrocyclic (triphosphine)molybdenum complexes
Bruce N. Diel, Paul F. Brandt, R. Curtis Haltiwanger, Michael L. J. Hackney, and Arlan D. Norman
pp 2811 - 2816; DOI:
10.1021/ic00313a025
PDF
Synthesis of bis(trifluoromethyl)phenylthallium and bis(trifluoromethyl)thallium acetate. Oxidative trifluoromethylation with bis(trifluoromethyl)thallium(III) compounds
H. K. Nair and J. A. Morrison
pp 2816 - 2820; DOI:
10.1021/ic00313a026
PDF
Redox reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2). The reductive coupling of nitriles with retention of a metal-metal-bonded dirhenium unit
David Esjornson, Daniel R. Derringer, Phillip E. Fanwick, and Richard A. Walton
pp 2821 - 2829; DOI:
10.1021/ic00313a027
PDF
Protonation of the 1,1-dithiolene ligands in the [Cu8(L)6]4- cubanes (L = [S2C:C(COOR)2]2-) and synthesis of the [Cu8(L)6-n(H-L)n]-(4-n) clusters. Synthesis and structural characterization of the [Cu10(H-L)6(L)2] decanuclear cluster
D. Coucouvanis, D. Swenson, N. C. Baenziger, R. Pedelty, M. L. Caffery, and S. Kanodia
pp 2829 - 2836; DOI:
10.1021/ic00313a028
PDF
Bimetallic complexes containing the bis(tetramethylcyclopentadienyl)ethane ligand
John F. Buzinkai and Richard R. Schrock
pp 2837 - 2846; DOI:
10.1021/ic00313a029
PDF
Electronic structure of piano-stool dimers. 8. Electronically induced conformational changes in high-valent bimetallic chalcogen complexes of the type [CpML]2(.mu.-L)2 (M = molybdenum rhenium; L = S, O)
Bruce E. Bursten and Roger H. Cayton
pp 2846 - 2853; DOI:
10.1021/ic00313a030
PDF
Stable paramagnetic dihydrido complexes of iridium(IV): synthesis, x-ray crystal structure, and behavior in solution of IrIV(H)2(Cl)2(P-iso-Pr3)2 (1) and IrIV(H)2(Cl)2(PCy3)2 (2)
Pasquale Mura, Annalaura Segre, and Silvana Sostero
pp 2853 - 2858; DOI:
10.1021/ic00313a031
PDF
Electron transfer in a series of cobalt clathrochelates in nonaqueous solution
Jacquelin Gribble and Scot Wherland
pp 2859 - 2863; DOI:
10.1021/ic00313a032
PDF
Lamellar inorganic ion exchangers. Alkali metal ion exchange on .alpha.- and .gamma.-titanium phosphate
Ricardo Llavona, Marta Suarez, Jose R. Garcia, and Julio Rodriguez
pp 2863 - 2868; DOI:
10.1021/ic00313a033
PDF
Coordination of "noncoordinating" anions: synthesis, characterization, and x-ray crystal structures of fluorine-bridged hexafluoroantimonate(1-), tetrafluoroborate(1-), and hexafluorophosphate(1-) adducts of [R3P(CO)3(NO)W]+. An unconventional order of anion donor strength
Robert V. Honeychuck and William H. Hersh
pp 2869 - 2886; DOI:
10.1021/ic00313a034
PDF
A new synthetic route to fluorodisilanes via selective reduction of halofluorodisilanes
John J. D'Errico and Kenneth G. Sharp
pp 2886 - 2888; DOI:
10.1021/ic00313a035
PDF
Theoretical study of the structures, relative stabilities, and infrared spectra of the isomeric NSO- anions
Suk Ping So
pp 2888 - 2890; DOI:
10.1021/ic00313a036
PDF
Synthesis and structural characterization of a mixed-ring rhenocene hydride complex, (.eta.5-cyclopentadienyl) (.eta.5-pentamethylcyclopentadienyl)hydridorhenium
Rocco A. Paciello, Paul Kiprof, Eberhardt Herdtweck, and Wolfgang A. Herrmann
pp 2890 - 2893; DOI:
10.1021/ic00313a037
PDF
Ground-state geometries and inversion barriers for simple complexes of early transition metals
Cynthia A. Jolly and Dennis S. Marynick
pp 2893 - 2895; DOI:
10.1021/ic00313a038
PDF
Metastable aluminum chloride, AlCl, as a solid and in solution
Matthias Tacke and Hansgeorg Schnoeckel
pp 2895 - 2896; DOI:
10.1021/ic00313a039
PDF
Reactions of hydrogen chloride and boron trichloride with (trimethylsilyl)amino groups
K. J. L. Paciorek, R. H. Kratzer, J. H. Nakahara, and W. Krone-Schmidt
pp 2896 - 2898; DOI:
10.1021/ic00313a040
PDF

Issue 15


Technetium-diphosphonate skeletal imaging agents: EXAFS structural studies in aqueous solution
John L. Martin, J. Yuan, Craig E. Lunte, R. C. Elder, William R. Heineman, and Edward Deutsch
pp 2899 - 2901; DOI:
10.1021/ic00314a001
PDF
An octacopper(II) complex with .mu.5-oxo, and tripod-like perchlorate ligands; formation and x-ray structure of the [Cu4(L)O(ClO4)]2(ClO4)2.2H2O dimer
Vickie McKee and Santokh S. Tandon
pp 2901 - 2902; DOI:
10.1021/ic00314a002
PDF
Conductive molecular crystals from three-dimensional building blocks: synthesis and characterization of tris(bis(ethylenedithio)tetrathiafulvalenium) bis(tris(2-thioxo-1,3-dithiole-4,5-dithiolato)vanadate), [ET]3[V(dmit)3]2, and the corresponding tetramethyltetraselenafulvalenium salt
William E. Broderick, Ellen M. McGhee, Martin R. Godfrey, Brian M. Hoffman, and James A. Ibers
pp 2902 - 2904; DOI:
10.1021/ic00314a003
PDF
Synthesis of a new one-dimensional sodium molybdenum phosphate polymer: structure of [(H3O)2NaMo6P4O24(OH)7]2-
Robert C. Haushalter and Frank W. Lai
pp 2904 - 2905; DOI:
10.1021/ic00314a004
PDF
Regioselectivity in the novel conversion of an aromatic carbon-fluorine bond into a carbon-hydrogen bond via an organonickel intermediate
Soonheum Park and D. Max Roundhill
pp 2905 - 2906; DOI:
10.1021/ic00314a005
PDF
Novel cubane-type molybdenum-tin cluster complexes [(H2O)9Mo3S4SnS4Mo3(H2O)9]8+ and Mo3SnS4(aq)6+
Haruo Akashi and Takashi Shibahara
pp 2906 - 2907; DOI:
10.1021/ic00314a006
PDF
Spectroscopy and x-ray crystal structure of luminescent bis[bis(diphenylphosphino)methane]tetracyanodiplatinum
Chi Ming Che, Vivian Wing Wah Yam, Wing Tak Wong, and Ting Fong Lai
pp 2908 - 2910; DOI:
10.1021/ic00314a007
PDF
Synthesis and crystal structure of bis[undecafluorodixenon(1+)] hexafluoronickelate(2-)
Adolf Jesih, Karel Lutar, Ivan Leban, and Boris Zemva
pp 2911 - 2914; DOI:
10.1021/ic00314a008
PDF
Encapsulation of lead sulfide molecular clusters into solid matrixes. Structural analysis with x-ray absorption spectroscopy
Karin Moller, Thomas Bein, Norman Herron, Walter Mahler, and Ying Wang
pp 2914 - 2919; DOI:
10.1021/ic00314a009
PDF
Preparation and crystal structure of the unusual double-helical copper(I) complex bis(2,6-bis(1-methylbenzimidazol-2-yl)pyridine)dicopper(I) naphthalene-1,5-disulfonate
Claude Piguet, Gerald Bernardinelli, and Alan F. Williams
pp 2920 - 2925; DOI:
10.1021/ic00314a010
PDF
Intercalation reactions of the neptunyl(VI) dication with hydrogen uranyl phosphate and hydrogen neptunyl phosphate host lattices
Peter K. Dorhout, Richard J. Kissane, Kent D. Abney, Larry R. Avens, P. Gary Eller, and Arthur B. Ellis
pp 2926 - 2930; DOI:
10.1021/ic00314a011
PDF
Ferromagnetic behavior in linear charge-transfer complexes. Structural and magnetic characterization of octamethylferrocene salts: [Fe(C5Me4H)2].bul.+ [A].bul.- (A = TCNE, TCNQ)
Joel S. Miller, Daniel T. Glatzhofer, Dermot M. O'Hare, William M. Reiff, Animesh Chakraborty, and Arthur J. Epstein
pp 2930 - 2939; DOI:
10.1021/ic00314a012
PDF
Magnetic coupling in zero- and one-dimensional magnetic systems formed by nickel(II) and nitronyl nitroxides. Magnetic phase transition of a ferrimagnetic chain
Andrea Caneschi, Dante Gatteschi, Jean Pierre Renard, Paul Rey, and Roberta Sessoli
pp 2940 - 2944; DOI:
10.1021/ic00314a013
PDF
Bi- and polynuclear complexes with short-bite ligands bridging metal atoms. [(.eta.5-C5H5)Rh(.mu.-CH3O2CC2CO2CH3)(.mu.-Ph2Ppy)Rh(CO)(.mu.-Cl)]2: synthesis, x-ray crystal structure, structural dynamics, and reactions with carbon monoxide and sulfur dioxide
Enrico Rotondo, Sandra Lo Schiavo, Giuseppe Bruno, Carmela Grazia Arena, Roberto Gobetto, and Felice Faraone
pp 2944 - 2949; DOI:
10.1021/ic00314a014
PDF
Synthesis and reactivity of titanium/cobalt complexes with Ti-O-C-Co bridges
Joseph S. Merola, Kathryn S. Campo, and Robert A. Gentile
pp 2950 - 2954; DOI:
10.1021/ic00314a015
PDF
Multinuclear NMR studies of molybdenum and tungsten carbonyl isocyanide complexes
Martin Minelli and Walter J. Maley
pp 2954 - 2958; DOI:
10.1021/ic00314a016
PDF
Crystal structure and carbon-13 and platinum-195 NMR spectra of an .alpha.-pyrrolidonate-bridged binuclear platinum(II) complex, [Pt2(NH3)4(C4H6NO)2]2(PF6)3(NO3).cntdot.H2O
Kazuko Matsumoto, Hiroshi Miyamae, and Hiroshi Moriyama
pp 2959 - 2964; DOI:
10.1021/ic00314a017
PDF
Resonance Raman spectra and excited-state lifetimes for a series of 3,3'-polymethylene-2,2'-bipyridine complexes of ruthenium(II)
Thomas C. Strekas, Harry D. Gafney, Steven A. Tysoe, Randolph P. Thummel, and Francois Lefoulon
pp 2964 - 2967; DOI:
10.1021/ic00314a018
PDF
Dependence of spectroscopic, electrochemical, and excited-state properties of tris chelate ruthenium(II) complexes on ligand structure
Yuji Kawanishi, Noboru Kitamura, and Shigeo Tazuke
pp 2968 - 2975; DOI:
10.1021/ic00314a019
PDF
Intensity distributions within the "d-d" spectra of tetrakis(diphenylmethylarsine oxide)(nitrato)cobalt(II) and tetrakis(diphenylmethylarsine oxide)(nitrato)nickel(II) nitrates
Neil D. Fenton and Malcolm Gerloch
pp 2975 - 2983; DOI:
10.1021/ic00314a020
PDF
Molecular hydrogen complex vs dihydride in ML4 + H2 systems. Influence of the ML4 fragment geometry
Feliu Maseras, Miquel Duran, Agusti Lledos, and Juan Bertran
pp 2984 - 2988; DOI:
10.1021/ic00314a021
PDF
Platinum(III) in the REOA mechanism of tetrachloroplatinate(2-) and hexachloroplatinate(2-): a pulse-radiolysis study
E. Bothe and R. K. Broszkiewicz
pp 2988 - 2991; DOI:
10.1021/ic00314a022
PDF
Quenching of the doublet excited state of tris(polypyridine)chromium(III) ions by oxalate ions: an example of irreversible electron transfer
Carl R. Steffan, Andreja Bakac, and James H. Espenson
pp 2992 - 2995; DOI:
10.1021/ic00314a023
PDF
Photochemical cleavage of carbonate in cyclopentadiene carbonate rhodium complex (CpRh(CO3).cntdot.2H2O)
Maher Henary, William C. Kaska, and Jeffrey I. Zink
pp 2995 - 2997; DOI:
10.1021/ic00314a024
PDF
A copper(I) N,N,N',N'',N''-pentamethyldiethylenetriamine complex and its carbon monoxide adduct in aqueous solutions
Eiichi Kimura, Tohru Koike, Mutsuo Kodama, and Dan Meyerstein
pp 2998 - 3001; DOI:
10.1021/ic00314a025
PDF
Syntheses of pentaammineosmium(III) and -osmium(II) complexes: pentaammine(trifluoromethanesulfonato-O)osmium(III)
Peter A. Lay, Roy H. Magnuson, and Henry Taube
pp 3001 - 3007; DOI:
10.1021/ic00314a026
PDF
Synthesis and structures of new six-coordinate 16- and 17-valence-electron rhenium phosphine complexes and their use in preparing seven-coordinate mixed RNC/CO rhenium(III) compounds
Steve Warner and Stephen J. Lippard
pp 3008 - 3013; DOI:
10.1021/ic00314a027
PDF
Steric effects of polymethylene chain length on the liquid-liquid extraction of copper(II) with bis(4-acylpyrazol-5-one) derivatives
Shoji Miyazaki, Hiroshi Mukai, Shigeo Umetani, Sorin Kihara, and Masakazu Matsui
pp 3014 - 3017; DOI:
10.1021/ic00314a028
PDF
Synthetic and spectroscopic investigations of anions containing the 1,3,2,4,5-dithiadiazastannole ring: x-ray crystal structure of [Ph4As][SnMe2ClS2N2]
Tristram Chivers, James Fait, and Kenneth J. Schmidt
pp 3018 - 3020; DOI:
10.1021/ic00314a029
PDF
Synthesis and reactivity of tricarbonyl(1,4,7-trithiacyclononane)manganese(1+): kinetics and mechanism of its formation and the crystal structure of [LMn(CO)3]3(PF6)2Br.2H2O (L = 1,4,7-trithiacyclononane)
Horst Elias, Gerald Schmidt, Heinz Josef Kueppers, Markus Saher, Karl Wieghardt, Bernhard Nuber, and Johannes Weiss
pp 3021 - 3024; DOI:
10.1021/ic00314a030
PDF
Variable-pressure kinetic and equilibrium study of monocomplex formation of copper(II) and zinc(II) with 2-chloro-1,10-phenanthroline in aqueous solution
Gabor Laurenczy, Yves Ducommun, and Andre E. Merbach
pp 3024 - 3028; DOI:
10.1021/ic00314a031
PDF
Thermal decomposition of the halide and pseudohalide derivatives of bis(cyclopentadienyl)titanium(IV)
Gilbert M. Brown
pp 3028 - 3032; DOI:
10.1021/ic00314a032
PDF
Synthesis of new metallacycles of rhenium(VII) oxides: migration of trimethylsilyl group to form the cis-dioxo cyclometallaphosphoranimino phosphane NPPh2CH2PPh2Re(O)2(OSiMe3)2 and arsane NPPh2(CH2)2AsPh2Re(O)2(OSiMe3)2
Kattesh V. Katti and Ronald G. Cavell
pp 3033 - 3036; DOI:
10.1021/ic00314a033
PDF
Pentaammineruthenium(II), pentaammineosmium(II), and (N-(hydroxyethyl)ethylenediaminetriacetato)ruthenate(II) complexes of styrenes
Michael G. Elliott, Songsheng Zhang, and Rex E. Shepherd
pp 3036 - 3043; DOI:
10.1021/ic00314a034
PDF
Energy factors governing the partial irreversibility of lithium intercalation in layered trichalcogenides MX3 (M = Ti, Zr, Hf; X = S, Se) and the structural changes in the intercalated species Li3MX3
Enric Canadell, Claudine Thieffry, Yves Mathey, and Myung Hwan Whangbo
pp 3043 - 3047; DOI:
10.1021/ic00314a035
PDF
Chemical bonding topology of binary and ternary transition-metal polyphosphides
R. B. King
pp 3048 - 3051; DOI:
10.1021/ic00314a036
PDF
Calculation of the theoretical magnetic susceptibility of the four S = 5/2 spin system. Application to tetranuclear manganese(II) complexes
J. Aussoleil, P. Cassoux, P. De Loth, and J. P. Tuchagues
pp 3051 - 3056; DOI:
10.1021/ic00314a037
PDF
Resonance Raman spectra of electronically excited tris[bis(diphenylphosphino)methane]dipalladium and -diplatinum complexes (M = Pd, Pt)
Pierre D. Harvey, Richard F. Dallinger, William H. Woodruff, and Harry B. Gray
pp 3057 - 3059; DOI:
10.1021/ic00314a038
PDF
Electronic spectra of the d6 binary carbonyl complexes hexacarbonylmanganese(1+), hexacarbonylchromium and hexacarbonylvanadate(1-): an ab initio analysis
K. Pierloot, J. Verhulst, P. Verbeke, and L. G. Vanquickenborne
pp 3059 - 3063; DOI:
10.1021/ic00314a039
PDF
Unusual structures of dilithiosilanes and disodiosilanes. Ionicity of the silicon-alkali-metal bond
Andrzej Rajca, Peng Wang, Andrew Streitwieser, and Paul v. R. Schleyer
pp 3064 - 3070; DOI:
10.1021/ic00314a040
PDF
NMR investigation of the Rh24+ complex Rh2(form)2(O2CCF3)2(H2O)2 (form = N,N'-Di-p-tolylformamidinate) in the presence of phosphorus donors. Evidence for the interconversion from the axial to equatorial adducts
Enrico Rotondo, Brian E. Mann, Pasquale Piraino, and Giuseppe Tresoldi
pp 3070 - 3073; DOI:
10.1021/ic00314a041
PDF
Isolation and identification of a trans-bis(bipyridine) complex of rhodium(III). Crystal structure of [trans-Rh(bpy)2(Cl)]2(H5O3)(ClO4)3: evidence for a H5O3 bridging group
G. Krueger, A. Roodt, J. G. Leipoldt, and Rudy Van Eldik
pp 3073 - 3076; DOI:
10.1021/ic00314a042
PDF
Crystal and molecular structure of [Cu(bcp)2]BF4.cntdot.CH3OH (bcp = 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)
Frank K. Klemens, Phillip E. Fanwick, Jodi K. Bibler, and David R. McMillin
pp 3076 - 3079; DOI:
10.1021/ic00314a043
PDF
Powder EPR of tris(diethylthioselenocarbamato) - and tris(diethyldiselenocarbamato)iron(III) diluted in the analogous cobalt(III) and indium(III) complex matrixes
Wolfgang Dietzsch, Norman V. Duffy, Edward Gelerinter, and Ekk Sinn
pp 3079 - 3081; DOI:
10.1021/ic00314a044
PDF
Solid-state emission of dicyanoplatinum(II) and -palladium(II) complexes of substituted 2,2'-bipyridines and 1,10-phenanthroline and x-ray crystal structures of isomorphous M(bpy)(CN)2 (bpy = 2,2'-bipyridine; M = Pt, Pd)
Chi Ming Che, Li Yan He, Chung Kwong Poon, and Thomas C. W. Mak
pp 3081 - 3083; DOI:
10.1021/ic00314a045
PDF
Iridium(I) insertion into an aromatic carbon-hydrogen bond. Synthesis and structure of [Ir(H)(CO)(bq)(PPh3)2]PF6 (bq = 7,8-benzoquinolinato)
Francesco Neve, Mauro Ghedini, Antonio Tiripicchio, and Franco Ugozzoli
pp 3084 - 3086; DOI:
10.1021/ic00314a046
PDF
Synthesis and structure of the cluster cation tris-.mu.-[bis(diphenylphosphino)methane]-.mu.3-sulfido[(triphenylphosphine)gold]-.mu.3-(chlorosilver)triplatinum(1+), containing both platinum-gold and platinum-silver bonds [Erratum to document cited in CA109(26):243021f]
Graeme Douglas, Michael C. Jennings, Kenneth W. Muir, Ljubica Manojlovic-Muir, and Richard J. Puddephatt
pp 3086 - 3086; DOI:
10.1021/ic00314a047
PDF

Issue 16


Structure, synthesis, and characterization of chiral secondary diphosphine platinum(II) mono- and dimeric complexes: molecular structure of [Pt2Cl4(SMe2)2{(R*,R*)-.mu.-HtBuPCH2PtBuH}]
John C. Huffman and Brian R. Lloyd
pp 3087 - 3089; DOI:
10.1021/ic00315a001
PDF
Large intensity enhancement of the spin-forbidden 4A2g .fwdarw. 2Eg transition in chromium(III)-semiquinone complexes
C. Benelli, A. Dei, D. Gatteschi, H. U. Guedel, and L. Pardi
pp 3089 - 3091; DOI:
10.1021/ic00315a002
PDF
Photochemical grafting of triiron dodecacarbonyl to silica. Formation of a surface-bound anionic trinuclear cluster
Sadaaki Yamamoto, Robert M. Lewis, Hajime Hotta, and Haruo Kuroda
pp 3091 - 3092; DOI:
10.1021/ic00315a003
PDF
Dihydrobis(pyrazolyl)borate complexes of gallium. X-ray crystal structure of [H2B(pz)2]2GaCl (pz = pyrazolyl ring)
Daniel L. Reger, Steven J. Knox, and Lukasz Lebioda
pp 3092 - 3093; DOI:
10.1021/ic00315a004
PDF
Reversible carbon monoxide binding to iron(III) isobacteriochlorins
Eric P. Sullivan and Steven H. Strauss
pp 3093 - 3095; DOI:
10.1021/ic00315a005
PDF
Synthesis and structure of bis(2,6-diisopropylphenoxo)tris(4-phenylpyridine)titanium: a compound containing both reduced and nonreduced 4-phenylpyridine ligands bound to titanium
Loren D. Durfee, John E. Hill, Judith L. Kerschner, Phillip E. Fanwick, and Ian P. Rothwell
pp 3095 - 3096; DOI:
10.1021/ic00315a006
PDF
High-valent iron phthalocyanine five- and six-coordinated .mu.-carbido dimers
Claudio Ercolani, Marcello Gardini, Virgil L. Goedken, Giovanna Pennesi, Gentilina Rossi, Umberto Russo, and Pierluigi Zanonato
pp 3097 - 3099; DOI:
10.1021/ic00315a007
PDF
Electronic structure and relative stability of isomers of thiophosphorus compounds, HPX2, HPXY, and ClPX2 (X, Y = O, S)
S. Mathieu, J. Navech, and J. C. Barthelat
pp 3099 - 3107; DOI:
10.1021/ic00315a008
PDF
The nature of the redox orbital in cis-bis(2,2'-bipyridine)dicyanoruthenium
J. B. Cooper and D. W. Wertz
pp 3108 - 3113; DOI:
10.1021/ic00315a009
PDF
Electron-transfer catalyzed substitution in carbonyl complexes. Part 5. Electron-transfer autocatalytic formation, intramolecular charge transfer, and qualitatively different solvatochromism of .sigma. and .pi. transition-metal carbonyl complexes with polynitrile ligands
Barbara Olbrich-Deussner, Wolfgang Kaim, and Renate Gross-Lannert
pp 3113 - 3120; DOI:
10.1021/ic00315a010
PDF
Bonding in transition-metal clusters
David J. Wales and Anthony J. Stone
pp 3120 - 3127; DOI:
10.1021/ic00315a011
PDF
Metal-nitroxyl interactions. 54. EPR spectra of high-spin iron(III) complexes of spin-labeled tetraphenylporphyrins in frozen solution
Lee Fielding, Kundalika M. More, Gareth R. Eaton, and Sandra S. Eaton
pp 3127 - 3131; DOI:
10.1021/ic00315a012
PDF
Synthesis, spectral, and redox properties of three triply bridged complexes of ruthenium
Antoni Llobet, Maria E. Curry, Howard T. Evans, and Thomas J. Meyer
pp 3131 - 3137; DOI:
10.1021/ic00315a013
PDF
Models for multicenter catalysts. 3. Facile hydride rearrangements in A-frame and related complexes and the structure of [RhIr(H)2(CO)2(.mu.-Cl)(DPM)2][BF4].cntdot.CH2Cl2, the product of hydrogen addition at one metal center in the A-frame pocket
Brian A. Vaartstra and Martin Cowie
pp 3138 - 3147; DOI:
10.1021/ic00315a014
PDF
Bonding of sulfur dioxide to the metallamacrocycle dicarbonyldichlorobis[.mu.-bis(diphenylphosphinomethyl)phenylarsine]diiridium and its gold(I) adduct [Ir2Au(CO)2Cl2(.mu.-(Ph2PCH2)2AsPh)2]+
Alan L. Balch, Brian J. Davis, and Marilyn M. Olmstead
pp 3148 - 3153; DOI:
10.1021/ic00315a015
PDF
Aluminum and gallium complexes of 1-ethyl-3-hydroxy-2-methyl-4-pyridinone: a new exoclathrate matrix
William O. Nelson, Steven J. Rettig, and Chris Orvig
pp 3153 - 3157; DOI:
10.1021/ic00315a016
PDF
Characterization of open clusters with linked germanium-diiron or diiron-tin triangles: structures of Ge2Fe6(CO)23, Sn2Fe6(CO)23 and Ge2Fe7(CO)26
Skelte G. Anema, Kenneth M. Mackay, and Brian K. Nicholson
pp 3158 - 3164; DOI:
10.1021/ic00315a017
PDF
Synthesis, characterization, and reactivity of iron carbonyl clusters containing bismuth or antimony. Crystal structures of isomorphous [Et4N][BiFe3Cr(CO)17] and [Et4N][SbFe3Cr(CO)17] and the ring complex Bi2Fe2(CO)8Me2
Kenton H. Whitmire, Minghuey Shieh, and Juanita Cassidy
pp 3164 - 3170; DOI:
10.1021/ic00315a018
PDF
Magnetism of alternating bimetallic chains: application to triaqua(oxamido-N-benzoato-N-propionato)coppermanganese monohydrate
Yu Pei, Keitaro Nakatani, Olivier Kahn, Jorunn Sletten, and Jean Pierre Renard
pp 3170 - 3175; DOI:
10.1021/ic00315a019
PDF
Nickel(II) complexes of [3k]aneNk polyazacycloalkanes (k = 7-12). Solution and solid-state studies
Andrea Bencini, Antonio Bianchi, Manuel Castello, Paolo Dapporto, Juan Faus, Enrique Garcia-Espana, Mauro Micheloni, Piero Paoletti, and Paola Paoli
pp 3175 - 3181; DOI:
10.1021/ic00315a020
PDF
Pentacoordinated molecules. 77. Intramolecular ligand exchange of pentacoordinated anionic silicates, RSiF4-, via silicon-29 and fluorine-19 NMR spectroscopy. Solution- and solid-state structures
Stephen E. Johnson, Roberta O. Day, and Robert R. Holmes
pp 3182 - 3189; DOI:
10.1021/ic00315a021
PDF
Pentacoordinated molecules. 78. Intramolecular ligand exchange of pentacoordinated anionic silicates, R2SiF3-, via silicon-29 and fluorine-19 NMR spectroscopy. Solution- and solid-state structures
Stephen E. Johnson, Jeffrey S. Payne, Roberta O. Day, Joan M. Holmes, and Robert R. Holmes
pp 3190 - 3198; DOI:
10.1021/ic00315a022
PDF
The first polyhydrides stabilized only by N-donor ligands, hexahydro[hydrotris(pyrazolyl)borato]rhenium and heptahydro[dipyrazolylmethane]rhenium
Douglas G. Hamilton, Xiao Liang Luo, and Robert H. Crabtree
pp 3198 - 3203; DOI:
10.1021/ic00315a023
PDF
Reactions of the dirhenium(II) complexes Re2Cl4(PR3)4 with lithium aluminum hydride. A convenient synthetic route to the dirhenium octahydride complexes Re2H8(PR3)4
Phillip E. Fanwick, Dawn R. Root, and Richard A. Walton
pp 3203 - 3209; DOI:
10.1021/ic00315a024
PDF
Strong interaction between an aliphatic carbon-hydrogen bond and a metal atom: the structure of (diethylbis(1-pyrazolyl)borato)allyldicarbonylmolybdenum(II)
F. Albert Cotton and Rudy L. Luck
pp 3210 - 3213; DOI:
10.1021/ic00315a025
PDF
Solution studies of the cobalt(II) N-rac- and N-meso-Col2+ isomers and molecular and crystal structures of the low-spin, five-coordinate cobalt(II) macrocyclic complexes N-rac-[CoL(H2O)](ClO4)2.cntdot.0.6H2O (1) and N-rac-[CoL(OC103)]ClO4 (2) (L = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4, 11-diene)
David J. Szalda, Carolyn L. Schwarz, John F. Endicott, Etsuko Fujita, and Carol Creutz
pp 3214 - 3219; DOI:
10.1021/ic00315a026
PDF
Synthesis of (1,3-disilylpropenyl)phosphines
Bruce A. Boyd and Robert H. Neilson
pp 3219 - 3224; DOI:
10.1021/ic00315a027
PDF
Electron transfer. 99. Reductions of oxyhalogens with dimeric molybdenum(V)
D. E. Linn, S. K. Ghosh, and E. S. Gould
pp 3225 - 3228; DOI:
10.1021/ic00315a028
PDF
Exchange reactions and microscopic reversibility: a reply
Theodore L. Brown
pp 3229 - 3230; DOI:
10.1021/ic00315a029
PDF
One-dimensional magnetism of a linear chain compound containing yttrium(III) and a nitronyl nitroxide radical
Cristiano Benelli, Andrea Caneschi, Dante Gatteschi, Luca Pardi, and Paul Rey
pp 3230 - 3234; DOI:
10.1021/ic00315a030
PDF
Crystal and molecular structures of encapsulated ruthenium(II) and ruthenium(III) ions with virtually identical geometries
Paul Bernhard, Hans Beat Buergi, Andrea Raselli, and Alan M. Sargeson
pp 3234 - 3239; DOI:
10.1021/ic00315a031
PDF
Gas-phase electron diffraction study of bis(dimethyldithiocarbamato)copper(II), [Cu(S2CNMe2)2], and bis(dimethyldithiocarbamato)zinc(II), [Zn(S2CNMe2)2]
Kolbjoern Hagen, Catherine J. Holwill, and David A. Rice
pp 3239 - 3242; DOI:
10.1021/ic00315a032
PDF
Proton NMR and optical spectra and magnetic properties of four-coordinated intermediate-spin, five-coordinated high-spin, and six-coordinated low-spin iron(II) hemes encapsulated in aqueous detergent micelles: model for hemoproteins
Okhil K. Medhi, Shyamalava Mazumdar, and Samaresh Mitra
pp 3243 - 3248; DOI:
10.1021/ic00315a033
PDF
Optical spectroscopic and structural properties of vanadium(3+)-doped fluoride, chloride, and bromide elpasolite lattices
Christian Reber, Hans U. Guedel, Gerd Meyer, Thomas Schleid, and Claude A. Daul
pp 3249 - 3258; DOI:
10.1021/ic00315a034
PDF
Formation of binary and ternary complexes of cadmium(II) with halide ions and 2,2'-bipyridine in N,N-dimethylformamide
Shinichi Ishiguro, Kazuhiko Ozutsumi, Makoto Miyauchi, and Hitoshi Ohtaki
pp 3258 - 3262; DOI:
10.1021/ic00315a035
PDF
Improved synthesis, redox chemistry, and magnetism of the mixed-valence isopolyanion of vanadate V10O264-
Steven M. Baxter and Peter T. Wolczanski
pp 3263 - 3264; DOI:
10.1021/ic00315a036
PDF
Influence of remote substituents on the properties of bis(terpyridyl)ruthenium(II) complexes
Randolph P. Thummel, Vidyadhar Hegde, and Yurngdong Jahng
pp 3264 - 3267; DOI:
10.1021/ic00315a037
PDF
An update of pseudoplanar, bibridged CunX2n+22-, CunX2n+1L-, and CunX2nL2 oligomer stacking patterns: structure of 1,2-dimethylpyridinium bis(.mu.-chloro)trichloroaquadicuprate(II)
Marcus R. Bond and Roger D. Willett
pp 3267 - 3269; DOI:
10.1021/ic00315a038
PDF
Reactions of coordinated dinitrogen. 23. Cis and trans isomers of bis(dinitrogen)tetrakis(dimethylphenylphosphine)molybdenum
T. Adrian George, Robyn K. Hayes, Modher Y. Mohammed, and Christopher J. Pickett
pp 3269 - 3270; DOI:
10.1021/ic00315a039
PDF
Kinetics of substitution reactions of binuclear platinum(III) pyrophosphito- and sulfato-bridged complexes
Chi Ming Che, Chang Fan Lo, Tai Chu Lau, Chung Kwong Poon, and Harry B. Gray
pp 3270 - 3272; DOI:
10.1021/ic00315a040
PDF
Electrochemical oxidation of the (sarcophagine)ruthenuim(2+) ion and its relation to the disproportionation of Ru(sar)3+ in aqueous solution
Paul Bernhard and Fred C. Anson
pp 3272 - 3274; DOI:
10.1021/ic00315a041
PDF

Issue 17


Steric activity of the central atom free valence electron pairs in free hexafluorobromate(1-) and hexafluoroiodate(1-) ions
Karl O. Christe and William W. Wilson
pp 3275 - 3277; DOI:
10.1021/ic00316a001
PDF
An example of intramolecular electron-transfer assistance in a bimolecular redox reaction: peroxydisulfate oxidation of (.mu.-1,2-bis(4-pyridyl)ethane)pentaammineruthenium(III) pentacyanoferrate(II) via its electronic isomer
Jose A. Olabe and Albert Haim
pp 3277 - 3278; DOI:
10.1021/ic00316a002
PDF
Facile substitution of triphenylphosphine in Wilkinson's catalyst by Sn(N-tert-Bu)2SiMe2. Syntheses and molecular structures of square-planar and homoleptic trigonal-bipyramidal stannylene complexes of rhodium(I)
Michael Veith, Lothar Stahl, and Volker Huch
pp 3278 - 3280; DOI:
10.1021/ic00316a003
PDF
Synthesis, structure, and reactivity of cerium(III) alkoxides. 2. Thermal decomposition of Ce(OC-tert-Bu3)3 and the structure of [Ce(OCH-tert-Bu2)3]2
Hilmar A. Stecher, Ayusman Sen, and Arnold L. Rheingold
pp 3280 - 3282; DOI:
10.1021/ic00316a004
PDF
Thermodynamics and dynamics of the equilibrium between carbonyl-bridged and nonbridged isomers of phosphine carbonyl cobalt complexes [Co2(CO)4(.mu.-R2PCH2PR2)2]4 (R = methyl, phenyl)
David J. Elliot, Hameed A. Mirza, Richard J. Puddephatt, David G. Holah, Alan N. Hughes, Ross H. Hill, and Wenjia Xia
pp 3282 - 3283; DOI:
10.1021/ic00316a005
PDF
Synthesis of tris(triphenylsiloxy)yttrium and derivatives: crystal structure of [Y(OSiPh3)3(THF)3].cntdot.THF
Michael J. McGeary, Paul S. Coan, Kirsten Folting, William E. Streib, and Kenneth G. Caulton
pp 3283 - 3284; DOI:
10.1021/ic00316a006
PDF
Synthesis and structure of the ruthenium carbonyl "boride" cluster HRu6(CO)17B
Fung E. Hong, Tim J. Coffy, Deborah A. McCarthy, and Sheldon G. Shore
pp 3284 - 3285; DOI:
10.1021/ic00316a007
PDF
Molecular structures of gaseous trifluoro(methyl)sulfurane, CH3SF3, and trifluoro(trifluoromethyl)sulfurane, CF3SF3: experimental determination by electron diffraction and ab initio calculations
Anthony J. Downs, G. Sean McGrady, Elizabeth A. Barnfield, David W. H. Rankin, Heather E. Robertson, James E. Boggs, and Kerwin D. Dobbs
pp 3286 - 3292; DOI:
10.1021/ic00316a008
PDF
Electronic structure of asymmetric metal-metal multiple bonds: the d2-d6 molybdenum phosphine-alkoxide complexes X4Mo-Mo(Ph3)4 (X = OH, Cl)
Bruce E. Bursten and William F. Schneider
pp 3292 - 3296; DOI:
10.1021/ic00316a009
PDF
Theoretical study of the bonding in sulfur- and oxygen-containing molybdenum species of the general formula MoSnO4-n2- (n = 0-4)
B. D. El-Issa, A. A. M. Ali, and H. Zanati
pp 3297 - 3305; DOI:
10.1021/ic00316a010
PDF
Detailed spectrophotometric study of the copper(II) halides in anhydrous methanol
M. A. Khan, J. Meullemeestre, M. J. Schwing, and F. Vierling
pp 3306 - 3309; DOI:
10.1021/ic00316a011
PDF
Ruthenium(II) complexes of 3,6-bis(2-pyridyl)pyridazine: synthesis, characterization, and effect of the nonchromophoric ligands on the photophysical and photochemical properties
Gianfranco Denti, Luigina Sabatino, Giuseppina De Rosa, Antonino Bartolotta, Gaetano Di Marco, Vittorio Ricevuto, and Sebastiano Campagna
pp 3309 - 3313; DOI:
10.1021/ic00316a012
PDF
Ferromagnetic phase transitions of two one-dimensional ferrimagnets formed by manganese(II) and nitronyl nitroxides cis octahedrally coordinated
Andrea Caneschi, Dante Gatteschi, Jean Pierre Renard, Paul Rey, and Roberta Sessoli
pp 3314 - 3319; DOI:
10.1021/ic00316a013
PDF
Preparation and x-ray crystal structure of 1,4-diiodo-cyclo-hexaselenium bis(hexafluoroarsenate)-bis(sulfur dioxide), Se6I2(AsF6)2.cntdot.2SO2, and (Se6I)n.cntdot.nMF6 (M = As, Sb) containing the catena-poly[cyclohexaselenium(1+)-4:1-.mu.-iodo] cation
W. A. Shantha Nandana, Jack Passmore, Peter S. White, and Chi Ming Wong
pp 3320 - 3328; DOI:
10.1021/ic00316a014
PDF
Preparation and structural characterization of a six-coordinate 21-thiaporphyrin complex: RhIII(STPP)Cl2 (STPP = tetraphenyl-21-thiaporphyrin anion)
Lechoslaw Latos-Grazynski, Jerzy Lisowski, Marilyn M. Olmstead, and Alan L. Balch
pp 3328 - 3331; DOI:
10.1021/ic00316a015
PDF
Preparation and characterization of (acetonitrile)trichlorobis(triphenylphosphine)technetium and its reactions with small .pi.-accepting ligands
Ronald M. Pearlstein, William M. Davis, Alun G. Jones, and Alan Davison
pp 3332 - 3334; DOI:
10.1021/ic00316a016
PDF
Efficient syntheses of dioxorhenium(V) complexes
John C. Brewer and Harry B. Gray
pp 3334 - 3336; DOI:
10.1021/ic00316a017
PDF
Synthesis, protonation sequence, and NMR studies of polyazamacrocyclic methylenephosphonates
C. F. G. C. Geraldes, A. D. Sherry, and W. P. Cacheris
pp 3336 - 3341; DOI:
10.1021/ic00316a018
PDF
Evidence for the donor capacity of nitrogen in acyclic aminophosphines: a multinuclear NMR study
R. K. Kanjolia, D. K. Srivastava, C. L. Watkins, and Larry K. Krannich
pp 3341 - 3345; DOI:
10.1021/ic00316a019
PDF
Insertion of nitriles into the nitrogen-chlorine bond. Synthesis of polyfluoro- and (perfluoroalkyl)tetrazanes
Ghulam Sarwar, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 3345 - 3349; DOI:
10.1021/ic00316a020
PDF
Oxidation of trivalent plutonium in acid solution by xenon difluoride and by the fluoroxysulfate ion, SO4F-
Richard L. Cook, Mary Woods, James C. Sullivan, and Evan H. Appelman
pp 3349 - 3351; DOI:
10.1021/ic00316a021
PDF
Oxidation of aqueous tris(bipyridine)ruthenium(2+) by the fluoroxysulfate ion, SO4F-
Richard L. Cook, Mary Woods, James C. Sullivan, and Evan H. Appelman
pp 3352 - 3354; DOI:
10.1021/ic00316a022
PDF
Luminescence study of complexation of europium and dicarboxylic acids
Pierre P. Barthelemy and Gregory R. Choppin
pp 3354 - 3357; DOI:
10.1021/ic00316a023
PDF
Electron-exchange and electron-transfer reactions involving the tetrakis(acetato)bis(acetonitrile)dirhodium(0)/(1+) couple in acetonitrile
Manuel A. S. Aquino, Daniel A. Foucher, and Donal H. Macartney
pp 3357 - 3361; DOI:
10.1021/ic00316a024
PDF
Entropy contribution to the nickel(III)/nickel(II) redox change in six-coordinating systems. Investigation of the role of the negative charge of the ligand in the stabilization of high oxidation states of the metal center
Luigi Fabbrizzi, Mario Mariani, Barbara Seghi, and Francesca Zanchi
pp 3362 - 3366; DOI:
10.1021/ic00316a025
PDF
Water exchange of trans-dichlorodiaquaplatinum(II) and tetraaquaplatinum(II) studied by an oxidative-addition quenching technique. Isotopic shifts and platinum-195 NMR chemical shifts for mixed chloro-aqua complexes of platinum(II) and platinum(IV)
Oesten Groening and Lars I. Elding
pp 3366 - 3372; DOI:
10.1021/ic00316a026
PDF
Di(phosphine)-bridged complexes of palladium. Parahydrogen-induced polarization in hydrogenation reactions and structure determination of tris(.mu.-bis(diphenylphosphino)methane)dipalladium, Pd2(dppm)3
Rein U. Kirss and Richard Eisenberg
pp 3372 - 3378; DOI:
10.1021/ic00316a027
PDF
Synthesis, characterization and magnetic properties of .mu.-oxalato- and .mu.-oxamido-bridged copper(II) dimers. Crystal and molecular structures of [Cu2(mepirizole)2(C2O4)(H2O)2](PF6)2.cntdot.mepirizole.cntdot.3H2O and [Cu2(mepirizole)2(C2O4)(NO3)2(H2O)]2[Cu2(mepirizole)2(C2O4)(NO3)2]
L. Soto, J. Garcia, E. Escriva, J. P. Legros, J. P. Tuchagues, F. Dahan, and A. Fuertes
pp 3378 - 3386; DOI:
10.1021/ic00316a028
PDF
Stereochemical change in the mercury(2+)-, silver(+)- and chlorine-induced and spontaneous reactions of pentaamminecobalt(III)-acido species: a reexamination
Nicola E. Brasch, David A. Buckingham, Charles R. Clark, and Kim S. Finnie
pp 3386 - 3390; DOI:
10.1021/ic00316a029
PDF
A water-stable gadolinium(III) complex derived from a new pentadentate "expanded porphyrin" ligand
Jonathan L. Sessler, Toshiaki Murai, and Gregory Hemmi
pp 3390 - 3393; DOI:
10.1021/ic00316a030
PDF
Protein coats of ferritin can sequester large amounts of ferrous iron
J. S. Rohrer, R. B. Frankel, G. C. Papaefthymiou, and Elizabeth C. Theil
pp 3393 - 3395; DOI:
10.1021/ic00316a031
PDF
Temperature and pressure effects on EPR zero-field splitting of Cu2Cl62- dimers in bis[tetraphenylstibonium]hexachlorodicuprate(2-) crystals
D. Gatteschi, J. Goslar, W. Hilczer, S. K. Hoffmann, and C. Zanchini
pp 3395 - 3396; DOI:
10.1021/ic00316a032
PDF
Formation of reactive cationic iron clusters by halogen exchange and abstraction from nonacarbonylbis(.mu.3-fluoromethylidyne) triiron with Lewis acids
Dieter Lentz and Heike Michael
pp 3396 - 3398; DOI:
10.1021/ic00316a033
PDF

Issue 18


Synthesis and characterization of thallium tin ethoxide ([Tl2Sn(OEt)6]n), a one-dimensional polymer in the solid state
Mark J. Hampden-Smith, Debbie E. Smith, and Eileen N. Duesler
pp 3399 - 3401; DOI:
10.1021/ic00317a001
PDF
Ligand exchange and reduction reactions of oxochromate(V) complexes: characterization of the common chromium(V) intermediates in the reductions of chromium(VI) and of trans-bis(2-ethyl-2-hydroxybutanoato(2-))oxochromate(V) by oxalic acid
Rodney P. Farrell, Robert J. Judd, Peter A. Lay, Richard Bramley, and Ji Ying Ji
pp 3401 - 3403; DOI:
10.1021/ic00317a002
PDF
Stepwise, metal-assisted decarboxylation promoted by manganese: reactivity relationship between manganese and vanadium
Xinhua Li and Vincent L. Pecoraro
pp 3403 - 3410; DOI:
10.1021/ic00317a003
PDF
Monocapped tris(dioxime) complexes of technetium(III): synthesis and structural characterization of TcX(dioxime)3B-R (X = Cl, Br; dioxime = dimethylglyoxime, cyclohexanedione dioxime; R = CH3, C4H9)
Elizabeth N. Treher, Lynn C. Francesconi, Jack Z. Gougoutas, Mary F. Malley, and Adrian D. Nunn
pp 3411 - 3416; DOI:
10.1021/ic00317a004
PDF
Chemistry of bis(platinum) complexes. Formation of trans derivatives from tetraamine complexes
Nicholas Farrell and Yun Qu
pp 3416 - 3420; DOI:
10.1021/ic00317a005
PDF
Synthesis and spectroscopic characterization of bis-pocket porphyrins: tetrakis(2',6'-dinitrophenyl)porphyrin and catalytic activity of a manganese(III) chloride derivative in alkane oxidation
Carlos A. Quintana, Roger A. Assink, and John A. Shelnutt
pp 3421 - 3425; DOI:
10.1021/ic00317a006
PDF
Synthesis and structural characterization of a trimeric nickel(II) complex of N-(2-mercaptopropionyl)glycine
Narayan Baidya, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 3426 - 3432; DOI:
10.1021/ic00317a007
PDF
Synthesis, structure, and phosphorus-31 NMR spectra of octachlorotetrakis(phosphine)dimolybdenumditungsten, Mo2W2Cl8(PR3)4, rectangular clusters
Richard T. Carlin and Robert E. McCarley
pp 3432 - 3436; DOI:
10.1021/ic00317a008
PDF
Binuclear phosphido-bridged chromium-platinum, molybdenum-platinum, and tungsten-platinum complexes. Synthesis of (CO)4M(.mu.-PPh2)2Pt(PR3) complexes and effect of the M .fwdarw. Pt donor bond on the reactivity of the carbonyl ligands
John Powell, Christian Couture, Michael R. Gregg, and Jeffery F. Sawyer
pp 3437 - 3444; DOI:
10.1021/ic00317a009
PDF
Thermal and photochemical carbon-hydrogen bond reactions of alkenes in (tris(pyrazolyl)borato)iridium(I) complexes
Robins S. Tanke and Robert H. Crabtree
pp 3444 - 3447; DOI:
10.1021/ic00317a010
PDF
Six-nitrogen macrocyclic complexes of the dioxouranium(VI) and praseodymium(III) ions
F. Benetollo, G. Bombieri, L. De Cola, A. Polo, D. L. Smailes, and Lidia M. Vallarino
pp 3447 - 3452; DOI:
10.1021/ic00317a011
PDF
Intramolecular [4 + 2] Diels-Alder cycloaddition reactions of phospholes with vinylphosphines promoted by nickel
L. Solujic, Emil B. Milosavljevic, John H. Nelson, Nathaniel W. Alcock, and Jean Fischer
pp 3453 - 3460; DOI:
10.1021/ic00317a012
PDF
Diastereomeric selective formation of a linear diphosphazane: meso-iso-PrN[PhP(iso-PrNH)]2
Tara G. Hill, R. Curtis Haltiwanger, Timothy R. Prout, and Arlan D. Norman
pp 3461 - 3467; DOI:
10.1021/ic00317a013
PDF
Crystal structures of pentafluoroxenon(1+) tetrafluorometallate(1-) (metal = silver, gold) and their relevance to the basicity and oxidizability of tetrafluorometallate(1-)
Karel Lutar, Adolf Jesih, Ivan Leban, Boris Zemva, and Neil Bartlett
pp 3467 - 3471; DOI:
10.1021/ic00317a014
PDF
Effect of hydroxide ion on the kinetics of triethylenetetramine displacement of tripeptides from copper(II) complexes
Brigitte E. Schwederski and Dale W. Margerum
pp 3472 - 3476; DOI:
10.1021/ic00317a015
PDF
Methyl group steric effects on the kinetics of the copper(II)-tripeptide reactions with triethylenetetramine
Brigitte E. Schwederski, Franco Basile-D'Alessandro, Peter N. Dickson, Hsiupu D. Lee, John M. T. Raycheba, and Dale W. Margerum
pp 3477 - 3480; DOI:
10.1021/ic00317a016
PDF
Direct determination of self-exchange electron-transfer rate constants of nickel(III,II) complexes by nickel-61 ESR line broadening
Jean Fu Wang, Krishan Kumar, and Dale W. Margerum
pp 3481 - 3484; DOI:
10.1021/ic00317a017
PDF
The ruthenium(II) center and the phosphite-phosphonate tautomeric equilibrium
Rosana L. Sernaglia and Douglas W. Franco
pp 3485 - 3489; DOI:
10.1021/ic00317a018
PDF
Kinetic study of the modes of decomposition of pentaaquabenzylchromium(III)
P. Kita and Robert B. Jordan
pp 3489 - 3494; DOI:
10.1021/ic00317a019
PDF
Kinetics and mechanism of the decomposition of cobalt dioxygen complexes of the binucleating macrocyclic ligand BISBAMP [3,9,17,23,29,30-hexaaza-6,20-dioxatricyclo[23.3.1.111,15]triaconta-1(28),11,13,15(30),25(29),26-hexaene]
Manuel Garcia Basallote, Dian Chen, and Arthur E. Martell
pp 3494 - 3499; DOI:
10.1021/ic00317a020
PDF
Potentiometry of mixtures: metal chelate stability constants of 1-hydroxy-3-oxapentane-1,2,4,5-tetracarboxylic acid and 3,6-dioxaoctane-1,2,4,5,7,8-hexacarboxylic acid
Ramunas J. Motekaitis and Arthur E. Martell
pp 3499 - 3503; DOI:
10.1021/ic00317a021
PDF
Reaction dynamics of photosubstitution intermediates of the triruthenium carbonyl cluster Ru3(CO)12 as studied by flash photolysis with infrared detection
John A. Dibenedetto, David W. Ryba, and Peter Campbell Ford
pp 3503 - 3507; DOI:
10.1021/ic00317a022
PDF
Reductive quenching of ruthenium polypyridyl sensitizers by cyanometalate complexes
Thomas E. Mallouk, Jonathan S. Krueger, James E. Mayer, and Christopher M. G. Dymond
pp 3507 - 3510; DOI:
10.1021/ic00317a023
PDF
Gas-phase reactions of niobium(1+) and tantalum(1+) with alkanes and alkenes. Carbon-hydrogen bond activation and ligand-coupling mechanisms
Steven W. Buckner, Timothy J. MacMahon, Gary D. Byrd, and Ben S. Freiser
pp 3511 - 3518; DOI:
10.1021/ic00317a024
PDF
Calculation of excited-state distortions and the missing-mode effect from the high-resolution emission spectrum of trans-bis[bis(diphenylphosphino)ethane]bis(dinitrogen)tungsten
Londa J. Larson and Jeffrey I. Zink
pp 3519 - 3523; DOI:
10.1021/ic00317a025
PDF
Theoretical studies of inorganic and organometallic reaction mechanisms. 1. Cis labilization in carbonyl substitution reactions of hexacoordinate chromium(0) and manganese(I) pentacarbonyl complexes
Randall D. Davy and Michael B. Hall
pp 3524 - 3529; DOI:
10.1021/ic00317a026
PDF
[.mu.-1,1'-Bis(diphenylphosphino)ferrocene]bis(chlorogold): synthesis, iron-57 and gold-197 Moessbauer spectroscopy, x-ray crystal structure, and antitumor activity
David T. Hill, Gerald R. Girard, Francis L. McCabe, Randall K. Johnson, Paul D. Stupik, Jian H. Zhang, William M. Reiff, and Drake S. Eggleston
pp 3529 - 3533; DOI:
10.1021/ic00317a027
PDF
Voltamperometric and spectroscopic studies of the behavior of manganese(II) and manganese(III) porphyrins with dioxygen and superoxide. Evidence for the formation of mixed-valence dimeric manganese porphyrin
M. Perree-Fauvet, A. Gaudemer, J. Bonvoisin, J. J. Girerd, C. Boucly-Goester, and P. Boucly
pp 3533 - 3538; DOI:
10.1021/ic00317a028
PDF
Isomerization and solution structures of desferrioxamine B complexes of aluminum(3+) and gallium(3+)
Brandan Borgias, Alain D. Hugi, and Kenneth N. Raymond
pp 3538 - 3545; DOI:
10.1021/ic00317a029
PDF
Studies of the reduction of the nickel(II) complex of 5,10,15,20-tetraphenyl-21-thiaporphyrin to form corresponding nickel(I) complexes
Piotr Chmielewski, Maria Grzeszczuk, Lechoslaw Latos-Grazynski, and Jerzy Lisowski
pp 3546 - 3552; DOI:
10.1021/ic00317a030
PDF
Spectrophotometric study of the equilibria between nickel(II) Schiff base complexes and ammonium-like cations or sodium tetraphenylborate
Ambrogio Giacomelli, Taddeo Rotunno, Lucio Senatore, and Roberta Settambolo
pp 3552 - 3555; DOI:
10.1021/ic00317a031
PDF
Ligand-ligand interactions in metal complexes. Thermodynamic and spectroscopic investigation of simple and mixed copper(II) and zinc(II) substituted-malonate complexes with 2,2'-bipyridyl in aqueous solution
Paola Amico, Raffaele P. Bonomo, Rosario Cali, Vincenzo Cucinotta, Pier G. Daniele, Giorgio Ostacoli, and Enrico Rizzarelli
pp 3555 - 3561; DOI:
10.1021/ic00317a032
PDF
Reactions of hexachloroosmate(IV) with hydrazine hydrate: syntheses and properties of pentaammine(dinitrogen)osmium(II) chloride and decaammine(.mu.-nitrido)diosmium(IV) chloride
Peter A. Lay and Henry Taube
pp 3561 - 3564; DOI:
10.1021/ic00317a033
PDF
Intramolecular conversion of an azoalkane ligand to two nitrene ligands on a triiron cluster
Edward J. Wucherer, Miklos Tasi, Bernhard Hansert, Anne K. Powell, Maria Theresa Garland, Jean Francois Halet, Jean Yves Saillard, and Heinrich Vahrenkamp
pp 3564 - 3572; DOI:
10.1021/ic00317a034
PDF
Synthesis and structural characterization of the crown thioether 1,3,6,9,11,14-hexathiacyclohexadecane (16S6) and the copper(I) complex [Cu(16S6)][ClO4]
Broer De Groot and Stephen J. Loeb
pp 3573 - 3578; DOI:
10.1021/ic00317a035
PDF
Synthesis and structural characterization of the gold complex, [n-Bu4N]2[Au2(i-MNT)2] (i-MNT = 1,1-dicyanoethylene-2,2-dithiolate) and its oxidative-addition products [Ph4As]2[Au2(i-MNT)2Cl2], [n-Bu4N]2[Au2(i-MNT)2Br2], and [n-Bu4N][Au(i-MNT)2]. Spectral studies of the disproportionation of [n-Bu4N]2[Au2(i-MNT)2X2] (X = Cl-, Br-, I-) into [n-Bu4N][AuX2] and [n-Bu4N][Au(i-MNT)2]
M. Nazrul I. Khan, Suning Wang, and John P. Fackler
pp 3579 - 3588; DOI:
10.1021/ic00317a036
PDF
Synthesis, structure and electronic properties of octakis(.mu.3-sulfido)hexakis(triethylphosphine)hexatungsten as a tungsten analog of the molecular model for superconducting Chevrel phases
Taro Saito, Akihiko Yoshikawa, Tsuneaki Yamagata, Hideo Imoto, and Kei Unoura
pp 3588 - 3592; DOI:
10.1021/ic00317a037
PDF
A new lithium insertion compound (lithium,copper) tantalum oxide, (Li,Cu)TaO3, with the LiNbO3-type structure
Nobuhiro Kumada, Satoru Hosoda, Fumio Muto, and Nobukazu Kinomura
pp 3592 - 3595; DOI:
10.1021/ic00317a038
PDF
Structural identification of the reactive vanadium(III) intermediate formed in the electron-transfer reactions of [N'-(2-hydroxyethyl)ethylenediamine-N,N,N'-triacetato]aquavanadium(III) complex ([V(hedtra)(H2O)]) with halopentaamminecobalt(III) complexes: x-ray crystal structures of [V(hedtra)(H2O)].cntdot.2H2O and K[VO(hedtra)].cntdot.H2O
Hiroshi Ogino, Mamoru Shimoi, and Yoko Saito
pp 3596 - 3600; DOI:
10.1021/ic00317a039
PDF
Monomer-dimer equilibrium of copper(II) decanoate in benzene containing decanoic acid
Yukio Fujii, Noriyuki Nakasuka, Motoharu Tanaka, Hiromichi Yamada, and Masateru Mizuta
pp 3600 - 3602; DOI:
10.1021/ic00317a040
PDF
Isolation and characterization of bis(2,6-diisopropylphenoxo)bis(4-pyrrolidinopyridine)oxotitanium: a mononuclear aryloxide compound containing a terminal titanium(IV)-oxo group
John E. Hill, Phillip E. Fanwick, and Ian P. Rothwell
pp 3602 - 3604; DOI:
10.1021/ic00317a041
PDF
Temperature, pressure, and electrolyte dependence of the ferrocene/ferrocenium electron self-exchange in acetonitrile-d3
Karl Kirchner, Shu Qin Dang, Martin Stebler, Harold W. Dodgen, Scot Wherland, and John P. Hunt
pp 3604 - 3606; DOI:
10.1021/ic00317a042
PDF
Synthesis and characterization of a bis(oxo)-bridged MN(III)Mn(III) complex, bis(.mu.-oxo)bis[N,N'-bis((6-methylpyrid-2-yl)methyl)ethane-1,2-diamine]dimanganese(III) perchlorate
Patricia A. Goodson and Derek J. Hodgson
pp 3606 - 3608; DOI:
10.1021/ic00317a043
PDF
Lewis-acid behavior of silicon chloride and fluoride toward trimethylamine oxide
Anton B. Burg
pp 3608 - 3609; DOI:
10.1021/ic00317a044
PDF
Preparation and structure of the dimolybdenum(III) compound hexachlorotetrakis(triethylphosphine)dimolybdenum. An anomaly in metal-metal-bonded edge-sharing bioctahedral compounds
Humberto D. Mui and Rinaldo Poli
pp 3609 - 3612; DOI:
10.1021/ic00317a045
PDF
Synthesis of closo-1-methylphosphadodecaborane(12), B11H11PCH3 and nido-7-methylphosphaundecaborane(13), B10H12PCH3, from the [B11H13]2- anion and their molecular structures
Thomas D. Getman, Hai Bin Deng, Leh Yeh Hsu, and Sheldon G. Shore
pp 3612 - 3616; DOI:
10.1021/ic00317a046
PDF
Facile synthesis of M3(CO)9(.mu.3-Te)2 (M = Ru, Os) and the synthesis and characterization of the novel cluster Fe2Os3(CO)17(.mu.4-Te)(.mu.3-Te)
Pradeep Mathur, Ipe J. Mavunkal, and V. Rugmini
pp 3616 - 3618; DOI:
10.1021/ic00317a047
PDF

Issue 19


A soluble copper(II) alkoxide for solution-based syntheses of yttrium barium copper oxides (YBa2Cu3O7-x)
Subhash C. Goel, Keith S. Kramer, Patrick C. Gibbons, and William E. Buhro
pp 3619 - 3620; DOI:
10.1021/ic00318a001
PDF
Observations on the dynamics of hydrazine oxidation by permanganate in aqueous acidic solutions
Timothy G. Costner and N. Ganapathisubramanian
pp 3620 - 3622; DOI:
10.1021/ic00318a002
PDF
Vicinal-dioximate complexes of silver(III)
Louis J. Kirschenbaum, Rama K. Panda, Edward T. Borish, and Edoardo Mentasti
pp 3623 - 3628; DOI:
10.1021/ic00318a003
PDF
Equilibrium and structural studies of silicon(IV) and aluminum(III) in aqueous solution. 21. A potentiometric and aluminum-27 NMR study of the system proton-aluminum(3+)-molybdate (MoO42-)
Lars Olof Oehman
pp 3629 - 3632; DOI:
10.1021/ic00318a004
PDF
Crystallographic study and ligand substitution reactions of dirhodium(II) tris- and tetrakis(tritolylbenzoate)
Henry J. Callot, Anne Marie Albrecht-Gary, Malak Al Joubbeh, Bernard Metz, and Francois Metz
pp 3633 - 3640; DOI:
10.1021/ic00318a005
PDF
Systematic substituent effects on dissociative substitution kinetics of ruthenium carbonyl, Ru(CO)4L, complexes (L = phosphorus, arsenic, and antimony donor ligands)
Lezhan Chen and Anthony J. Poe
pp 3641 - 3647; DOI:
10.1021/ic00318a006
PDF
Comparative kinetic study of oxygen atom transfer reactions of oxohydroxodiperoxomolybdenum(VI) and oxo(oxalato)diperoxomolybdenum(VI) in aqueous solution
Arlene F. Ghiron and Richard C. Thompson
pp 3647 - 3650; DOI:
10.1021/ic00318a007
PDF
Electron transfer. 100. Iron-catalyzed reduction of peroxide-bound chromium(IV) with mercapto acids
S. K. Ghosh and E. S. Gould
pp 3651 - 3655; DOI:
10.1021/ic00318a008
PDF
Redox potentials and related thermodynamic parameters of (diaminopolycarboxylato)metal(III/II) redox couples
Hiroshi Ogino, Takako Nagata, and Kazuko Ogino
pp 3656 - 3659; DOI:
10.1021/ic00318a009
PDF
Mechanistic differentiation between solvolysis reactions of pentaammine trifluoromethanesulfonato-O complexes of cobalt(III), chromium(III), and rhodium(III)
Surapong Suvachittanont and Rudi Van Eldik
pp 3660 - 3662; DOI:
10.1021/ic00318a010
PDF
Mechanistic interpretation of high-pressure effects on the photosubstitution of pyridine and 4-substituted pyridine in complexes of tungsten pentacarbonyl
S. Wieland, Rudi Van Eldik, D. R. Crane, and P. C. Ford
pp 3663 - 3666; DOI:
10.1021/ic00318a011
PDF
Ionization of pyridine bases and their reactions with cobalt(II) and nickel(II) acetates in anhydrous acetic acid
Kiyomi Azuma, Noriyuki Nakasuka, and Motoharu Tanaka
pp 3667 - 3671; DOI:
10.1021/ic00318a012
PDF
Quenching of the 2E excited state of tris(polypyridine)chromium(III) ions with titanium(III)
Patrick Huston, James H. Espenson, and Andreja Bakac
pp 3671 - 3674; DOI:
10.1021/ic00318a013
PDF
Protonation and complex formation of [(2,2'-bipyrazine)bis(2,2'-bipyridine)ruthenium(II)](2+) in the lowest excited state
Kazuteru Shinozaki, Youkoh Kaizu, Hiroyuki Hirai, and Hiroshi Kobayashi
pp 3675 - 3679; DOI:
10.1021/ic00318a014
PDF
Excited-state lifetime of the nonemissive complex [(2,2'-4H-bipyrazinium(1+))bis(2,2'-bipyridine)ruthenium(II)](3+)
Kazuteru Shinozaki, Osamu Ohno, Youkoh Kaizu, Hiroshi Kobayashi, Minoru Sumitani, and Keitaro Yoshihara
pp 3680 - 3683; DOI:
10.1021/ic00318a015
PDF
Lewis base properties of 1,5-diphosphadithiatetrazocines: crystal and molecular structures of 1,5-Ph4P2N4S2Me+CF3SO3-
Tristram Chivers, Georges Y. Denes, Stephen W. Liblong, and John F. Richardson
pp 3683 - 3688; DOI:
10.1021/ic00318a016
PDF
Monomeric rhenium(IV) phenoxides and their development from mononuclear rhenium halides with oxygen and sulfur donor ligands
Ian M. Gardiner, Michael A. Bruck, Pamela A. Wexler, and David E. Wigley
pp 3688 - 3695; DOI:
10.1021/ic00318a017
PDF
Heterobimetallic gold-platinum phosphine complexes. X-ray crystal and molecular structures of [(PPh3)Pt(AuPPh3)6](NO3)2 and [(PPh3)(CO)Pt(AuPPh3)6](PF6)2
Larry N. Ito, James D. Sweet, Ann M. Mueting, Louis H. Pignolet, M. F. J. Schoondergang, and J. J. Steggerda
pp 3696 - 3701; DOI:
10.1021/ic00318a018
PDF
Oxamidato complexes. 1. A study of the formation of complexes between copper(II) and H2pmox (H2pmox = N,N'-bis(2-pyridylmethyl)oxamide). Synthesis, crystal structure, and magnetic properties of the alternating-chain compound [Cu2(pmox)(H2pmox)(H2O)2](NO3)2.cntdot.8H2O
Francesc Lloret, Miguel Julve, Juan Faus, Yves Journaux, Michele Philoche-Levisalles, and Yves Jeannin
pp 3702 - 3706; DOI:
10.1021/ic00318a019
PDF
Structural, magnetic, and electrochemical studies on macrocyclic dicopper(II) complexes with varying chelate ring size
Sanat K. Mandal, Laurence K. Thompson, Michael J. Newlands, and Eric J. Gabe
pp 3707 - 3713; DOI:
10.1021/ic00318a020
PDF
Preparation, structure, and properties of manganese toluene-3,4-dithiolate complexes in different oxidation states
Klaus Greiwe, Bernt Krebs, and Gerald Henkel
pp 3713 - 3720; DOI:
10.1021/ic00318a021
PDF
Novel chiral trinuclear and symmetric tetranuclear imidazolate-bridged cobalt(III) complexes of a synthetic analog of bleomycin
Steven J. Brown, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 3720 - 3728; DOI:
10.1021/ic00318a022
PDF
Technetium thiolate complexes as oxygen atom transfer catalysts
Nadine De Vries, Alun G. Jones, and Alan Davison
pp 3728 - 3734; DOI:
10.1021/ic00318a023
PDF
Chemistry of molybdenum with hard-soft donor ligands. 2. Molybdenum(VI), -(V), and -(IV) oxo complexes with tridentate Schiff base ligands
Sanchita Purohit, Aditya P. Koley, Lakkaraju S. Prasad, P. T. Manoharan, and Saktiprosad Ghosh
pp 3735 - 3742; DOI:
10.1021/ic00318a024
PDF
Oxidative electrochemistry of cobalt tetraphenylporphyrin under a CO atmosphere. Interaction between carbon monoxide and electrogenerated [(TPP)Co]+ in nonbonding media
X. H. Mu and Karl M. Kadish
pp 3743 - 3747; DOI:
10.1021/ic00318a025
PDF
Fluoride-assisted stabilization of manganese(III) in aqueous medium. A general approach to the synthesis of mixed-ligand fluoro complexes of manganese(III)
Manabendra N. Bhattacharjee, Mihir K. Chaudhuri, and Ranendra N. Dutta Purkayastha
pp 3747 - 3752; DOI:
10.1021/ic00318a026
PDF
Potentiometric and spectrophotometric study of the proton, cobalt(II), nickel(II), and copper(II) complexes of 2-amino-N,3-dihydroxybutanamide and 2-amino-N-hydroxy-3-phenylpropanamide in aqueous solution
Enrico Leporati
pp 3752 - 3759; DOI:
10.1021/ic00318a027
PDF
Kinetics and mechanism of solvent-exchange and anation reactions of sterically hindered diethylenetriamine complexes of palladium(II) in aqueous solution
J. Berger, M. Kotowski, R. Van Eldik, U. Frey, L. Helm, and A. E. Merbach
pp 3759 - 3765; DOI:
10.1021/ic00318a028
PDF
Structure and vibrational spectra of tetrafluoroammonium tetrafluoroborate: a reappraisal
Mona Arif and Sidney F. A. Kettle
pp 3765 - 3766; DOI:
10.1021/ic00318a029
PDF
Preparation, characterization, and chemistry of 3-(2,2-dioxo-4,4-difluorothietanylidene)tetrafluorosulfur
R. Winter, D. H. Peyton, and Gary L. Gard
pp 3766 - 3770; DOI:
10.1021/ic00318a030
PDF
Metal complexes with tetrapyrrole ligands. 53. Hydrogen-1 NMR spectrum of dicerium(III) tris(octaethylporphyrinate), Ce2(OEP)3: evidedence for alkyl group steric interaction
Johann W. Buchler, Martina Kihn-Botulinski, Juergen Loeffler, and Mark Wicholas
pp 3770 - 3772; DOI:
10.1021/ic00318a031
PDF
Preparation and characterization of the monomeric copper(II) siloxide complex Cu[OSi(OCMe3)3]2(py)2
Anne K. McMullen, T. Don Tilley, Arnold L. Rheingold, and Steven J. Geib
pp 3772 - 3774; DOI:
10.1021/ic00318a032
PDF

Issue 20


Rhenium phosphine heptahydride complexes: proton NMR evidence for classical structures in solution
Xiao Liang Luo and Robert H. Crabtree
pp 3775 - 3777; DOI:
10.1021/ic00319a001
PDF
A high-potential mononuclear manganese(IV) complex. Synthesis, structure, and properties, including EPR spectroscopy and electrochemistry, of [Mn(HB(3,5-Me2pz)3)2] (ClO4)2 (pz = pyrazolyl)
Michael K. Chan and William H. Armstrong
pp 3777 - 3779; DOI:
10.1021/ic00319a002
PDF
Aerobic and anaerobic photooxidation of p-xylene in the presence of phosphotungstic acid and its tetrabutylammonium salt
Donato Attanasio and Lorenza Suber
pp 3779 - 3781; DOI:
10.1021/ic00319a003
PDF
Kinetics and mechanism of electron transfer from pentacarbonylrhenate to metal carbonyl dimers by infrared stopped-flow spectroscopy
M. Shauna Corraine and Jim D. Atwood
pp 3781 - 3782; DOI:
10.1021/ic00319a004
PDF
Preparation and x-ray structure of (tetramethyldibenzotetraaza[14]annulene)chromium dimer [(tmtaa)Cr]2. A multiply bonded complex of dichromium(II) without bridging ligands
Jilles J. H. Edema, Sandro Gambarotta, Paul Van der Sluis, Wilberth J. J. Smeets, and Anthony L. Spek
pp 3782 - 3784; DOI:
10.1021/ic00319a005
PDF
Alkoxide and thiolate rhenium(VII) oxo-alkyl complexes and Re2O5(CH2CMe3)4, a compound with a [O2Re-O-ReO2]4+ core
Shiang Cai, David M. Hoffman, and Derk A. Wierda
pp 3784 - 3786; DOI:
10.1021/ic00319a006
PDF
Electron-transfer reactions in mixed solvents. An electrochemical probe of unsymmetrical selective solvation
Robert L. Blackbourn and Joseph T. Hupp
pp 3786 - 3790; DOI:
10.1021/ic00319a007
PDF
Redox thermodynamics of dinuclear transition-metal complexes. Unusual entropy and electronic coupling effects in mixed solvents
Jeff C. Curtis, Robert L. Blackbourn, Kelly S. Ennix, Shixu Hu, Jody A. Roberts, and Joseph T. Hupp
pp 3791 - 3795; DOI:
10.1021/ic00319a008
PDF
Medium effects in weakly coupled electron-transfer processes. Calculation of inner-sphere reorganizational energies at zero ionic strength
Nita A. Lewis, Yaw S. Obeng, and William L. Purcell
pp 3796 - 3799; DOI:
10.1021/ic00319a009
PDF
Solution properties and reactivity of the aqua ion of the trimolybdenum(IV) incomplete cuboidal Mo/S cluster nonaaquatetrasulfidotrimolybdenum(4+)
Bee Lean Ooi and A. Geoffrey Sykes
pp 3799 - 3804; DOI:
10.1021/ic00319a010
PDF
Hydrolytic reactions of copper(II) bipyridine complexes
Istvan Fabian
pp 3805 - 3807; DOI:
10.1021/ic00319a011
PDF
Chlorine transfer from chloramine to amines in aqueous medium. 1. Reaction between chloramine and methylamine
Michel Ferriol, Josette Gazet, Rosette Rizk-Ouaini, and Marie Therese Saugier-Cohen Adad
pp 3808 - 3813; DOI:
10.1021/ic00319a012
PDF
Synthesis, spectroscopy and structural characterization of five-coordinate, bis(aryldiazenido)technetium complexes and their protonation reactions. X-ray structure of [TcCl(PPh3)2(NNC6H4Br)2]
Terrence Nicholson, Nadine De Vries, Alan Davison, and Alun G. Jones
pp 3813 - 3819; DOI:
10.1021/ic00319a013
PDF
Technetium bis(.mu.-oxo) dimers of 1,4,7-triazacyclonane-N,N',N''-triacetate (TCTA). Synthesis and characterization of [(TCTA)Tc(.mu.-O)2Tc(TCTA)]n- (n = 2, 3) and the crystal structure of Ba2[(TCTA)Tc(.mu.-O)2Tc(TCTA)](ClO4).9H2O
Karen E. Linder, John C. Dewan, and Alan Davison
pp 3820 - 3825; DOI:
10.1021/ic00319a014
PDF
Synthesis and molecular structure of a "lantern" dimer, bis(tetraphenylarsonium) tetrakis(N,N'-ethylenebis(2-mercaptoactamide)dioxoditechnetate(2-)
Nathan J. Bryson, David Brenner, John Lister-James, Alun G. Jones, John C. Dewan, and Alan Davison
pp 3825 - 3828; DOI:
10.1021/ic00319a015
PDF
Preparation and crystal structure of thallium 2,4,6-tris(trifluoromethyl)phenoxide, a compound of thallium(I) with coordination number 2 at the thallium atom
Herbert W. Roesky, Mario Scholz, Mathias Noltemeyer, and Frank T. Edelmann
pp 3829 - 3830; DOI:
10.1021/ic00319a016
PDF
Unique properties of ruthenium(II) phosphole complexes
Rahel Vac, John H. Nelson, Emil B. Milosavljevic, and Ljiljana Solujic
pp 3831 - 3836; DOI:
10.1021/ic00319a017
PDF
Synthesis and reactivity of functionalized rhenium phosphido complexes (.eta.5-C5H5)Re(NO)(PPh3)(PXX'): an unusual carbon tetrachloride 1,3-addition leading to an exo-substituted .eta.4-cyclopentadiene complex
William E. Buhro, Atta M. Arif, and James A. Gladysz
pp 3837 - 3845; DOI:
10.1021/ic00319a018
PDF
The reaction of cobaltocene with secondary phosphine oxides revisited. Trapping of an intermediate cobalt(I) complex
Wolfgang Klaeui and Choong Eui Song
pp 3845 - 3849; DOI:
10.1021/ic00319a019
PDF
Electronic structure of 42- and 44-electron Cp2M2(CO)4E2 butterfly complexes (M = Cr, Mo, W; E = S, Se, SR, PR...): rationalization of their structures and isomerization processes
Moulay El Khalifa, Francois Y. Petillon, Jean Yves Saillard, and Jean Talarmin
pp 3849 - 3855; DOI:
10.1021/ic00319a020
PDF
Steric effects associated with monosubstituted cyclopentadienyl transition-metal complexes. Synthesis and NMR spectroscopic and molecular mechanics study of [(.eta.5-C5H4Bu-tert)Fe(CO)(L)I] complexes and crystal structure determination of [(.eta.5-C5H4Bu-tert)Fe(CO)(PPh3)I]
Karen E. Du Plooy, Charles F. Marais, Laurence Carlton, Roger Hunter, Jan C. A. Boeyens, and Neil J. Coville
pp 3855 - 3860; DOI:
10.1021/ic00319a021
PDF
Preparation and properties of tantalum imido complexes and their reactions with alkynes. Coordination control through multiple metal-ligand bonding
Yuan Wei Chao, Pamela A. Wexler, and David E. Wigley
pp 3860 - 3868; DOI:
10.1021/ic00319a022
PDF
Methanol synthesis catalysts based on cesium/copper/zinc oxide/metal oxide (metal = aluminum, chromium, gallium): genesis from coprecipitated hydrotalcite-like precursors, solid-state chemistry, morphology, and stability
John G. Nunan, Paul B. Himelfarb, Richard G. Herman, Kamil Klier, Charles E. Bogdan, and Gary W. Simmons
pp 3868 - 3874; DOI:
10.1021/ic00319a023
PDF
Interconversion of persulfido, sulfur hydride, and hydride ligands coordinated to CpRu(PPh3)2+
Jayantha Amarasekera and Thomas B. Rauchfuss
pp 3875 - 3883; DOI:
10.1021/ic00319a024
PDF
Structural, vibrational and solid-state NMR studies of the halogenocuprate(I) complexes [(PPh3)2CuI2]- and [(PPh3)CuI3Cu(PPh3)]-
Graham A. Bowmaker, Annamaria Camus, Peter C. Healy, Brian W. Skelton, and Allan H. White
pp 3883 - 3888; DOI:
10.1021/ic00319a025
PDF
Preparation, characterization, and low-temperature transition of (triazatetrabenzoporphyrinato)copper(I) iodide, a new porphyrinic conductor with local moments coupled to itinerant charge carriers
Kwangkyoung Liou, Michael Y. Ogawa, Timothy P. Newcomb, Guy Quirion, Moohee Lee, Mario Poirier, William P. Halperin, Brian M. Hoffman, and James A. Ibers
pp 3889 - 3896; DOI:
10.1021/ic00319a026
PDF
Structural, optical, and redox properties of lamellar solids derived from copper(I) complexes and n-butylammonium uranyl phosphate and arsenate
Anthony T. Jacob and Arthur B. Ellis
pp 3896 - 3900; DOI:
10.1021/ic00319a027
PDF
Photochemical generation of alkyl radicals and their reactions with methyl viologen radical cation and with transition-metal complexes in aqueous solution
Andreja Bakac and James H. Espenson
pp 3901 - 3904; DOI:
10.1021/ic00319a028
PDF
Electrochemical and spectroelectrochemical investigations of dichlorotetrakis(pyridine)rhodium(1+) chloride in nonaqueous solvents. Generation and reactions of monomeric rhodium(II) species
J. E. Anderson and T. P. Gregory
pp 3905 - 3909; DOI:
10.1021/ic00319a029
PDF
Solution conformations of calcium chloride and calcium nitrate complexes of chiral tetramethyl 18-crown-6-macrocycles: a 1D and 2D proton and carbon-13 NMR investigation
John F. Lewison, Robert G. Ghirardelli, and Richard A. Palmer
pp 3909 - 3916; DOI:
10.1021/ic00319a030
PDF
Synthesis and characterization of mixed-ligand technetium(II) complexes containing halides, phosphines, and either 2,2'-bipyridine, 1,10-phenanthroline, or 2,2':6'2''-terpyridine. X-ray crystal structures of cis(Cl),trans(P)-[TcCl2(P(CH3)2C6H5)2(phen)] and trans(P)-[TcBr(P(CH3)2C6H5)2(terpy)]SO3CF3
Bruce E. Wilcox, Douglas M. Ho, and Edward Deutsch
pp 3917 - 3923; DOI:
10.1021/ic00319a031
PDF
1,2-Difluorobenzene: a relatively inert and noncoordinating solvent for electrochemical studies on transition-metal complexes
Terrence R. O'Toole, Janet N. Younathan, B. Patrick Sullivan, and Thomas J. Meyer
pp 3923 - 3926; DOI:
10.1021/ic00319a032
PDF
Preferential solvation effects observed in a kinetic study of the reaction of [.eta.6-C6Me6)Ru(.eta.6-anthracene)][PF6]2 with acetonitrile
Daniel A. Freedman and Kent R. Mann
pp 3926 - 3929; DOI:
10.1021/ic00319a033
PDF
Nucleophilicities of the metal carbonyl anions: effects of ligands, solvent and countercation
Chung Kung Lai, William G. Feighery, Yueqian Zhen, and Jim D. Atwood
pp 3929 - 3930; DOI:
10.1021/ic00319a034
PDF

Issue 21


A simple route to the first 1,3-diaza-2-phosphetine cations
Christian Roques, Marie Rose Mazieres, Jean Pierre Majoral, Michel Sanchez, and Joel Jaud
pp 3931 - 3933; DOI:
10.1021/ic00320a001
PDF
Reduction of oxygen- and sulfur-bonded (thiocarbamato)pentaamminecobalt(III) complexes by chromium(II)
Robert J. Balahura, Michael Johnson, and Tim Black
pp 3933 - 3937; DOI:
10.1021/ic00320a002
PDF
Kinetic study of the formation of oxo diperoxo complexes of molybdenum(VI) and tungsten(VI) and their reduction by iron(II), europium(II), the methyl viologen radical cation, and the dithionite ion
Lisa M. Schwane and Richard C. Thompson
pp 3938 - 3946; DOI:
10.1021/ic00320a003
PDF
Kinetics of ferrate(V) decay in aqueous solution. A pulse-radiolysis study
J. D. Rush and Benon H. J. Bielski
pp 3947 - 3951; DOI:
10.1021/ic00320a004
PDF
Effect of steric crowding on the rates of reactions of a nickel(I) tetraaza macrocycle with organic halides and hydroperoxides
Novelette Sadler, Susannah L. Scott, Andreja Bakac, James H. Espenson, and M. S. Ram
pp 3951 - 3954; DOI:
10.1021/ic00320a005
PDF
Synthesis, properties, and molecular structure of trans-chloro(nitrosyl)bis(2,2'-bipyridine)ruthenium(2+): trans and cis isomer characteristics compared
Hirotaka Nagao, Hisatoshi Nishimura, Hirofumi Funato, Yuri Ichikawa, F. Scott Howell, Masao Mukaida, and Hidetake Kakihana
pp 3955 - 3959; DOI:
10.1021/ic00320a006
PDF
Molecular geometry of d8 five-coordination. 1. Data search, description of conformation, and preliminary statistics
Thomas P. E. Auf der Heyde and Hans Beat Buergi
pp 3960 - 3969; DOI:
10.1021/ic00320a007
PDF
Molecular geometry of d8 five-coordination. 2. Cluster analysis, archetypal geometries, and cluster statistics
Thomas P. E. Auf der Heyde and Hans Beat Buergi
pp 3970 - 3981; DOI:
10.1021/ic00320a008
PDF
Molecular geometry of d8 five-coordination. 3. Factor analysis, static deformations, and reaction coordinates
Thomas P. E. Auf der Heyde and Hans Beat Buergi
pp 3982 - 3989; DOI:
10.1021/ic00320a009
PDF
Synthesis and characterization of new binuclear electron-transfer models containing rigid aromatic spacers
Yun Kim and Charles M. Lieber
pp 3990 - 3992; DOI:
10.1021/ic00320a010
PDF
Detailed study of the hysteresis associated with the spin-state transition in bis(2,6-bis(pyrazol-3-yl)pyridine)iron(II) bis(tetrafluoroborate) and the hypothesis of independent domains
E. Koenig, B. Kanellakopulos, B. Powietzka, and H. A. Goodwin
pp 3993 - 3996; DOI:
10.1021/ic00320a011
PDF
Electronic, EPR and vibrational spectra of the hexachlorocuprate(4-) ion
Robbie G. McDonald and Michael A. Hitchman
pp 3996 - 4001; DOI:
10.1021/ic00320a012
PDF
Infrared spectra of the tetraarsenic-ozone reaction and photolysis products in solid argon
Lester Andrews and Zofia Mielke
pp 4001 - 4006; DOI:
10.1021/ic00320a013
PDF
UV-visible IR thin-layer spectroelectrochemical studies of hexakis(aryl isocyanide)chromium complexes. In situ generation and characterization of four oxidation states
John P. Bullock and Kent R. Mann
pp 4006 - 4011; DOI:
10.1021/ic00320a014
PDF
Stereochemical inhibition of substitution in simple coordination compounds. Experimental and molecular mechanics evidence for discrimination between dissociative and interchange pathways in trans-dichloro(meso- and rac-(1,8)-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)cobalt(III)
Carolyn L. Schwarz and John F. Endicott
pp 4011 - 4018; DOI:
10.1021/ic00320a015
PDF
EXAFS analysis of xanthine oxidase complexes with alloxanthine, violapterin, and 6-pteridylaldehyde
R. Hille, G. N. George, M. K. Eidsness, and S. P. Cramer
pp 4018 - 4022; DOI:
10.1021/ic00320a016
PDF
Boron-nitrogen compounds. 121. Triazaboles and related triazole derivatives of boron
Kurt Niedenzu and K. R. Woodrum
pp 4022 - 4026; DOI:
10.1021/ic00320a017
PDF
Synthetic and structural studies of a series of soluble cerium(IV) alkoxide and alkoxide nitrate complexes
William J. Evans, Timothy J. Deming, Jeffrey M. Olofson, and Joseph W. Ziller
pp 4027 - 4034; DOI:
10.1021/ic00320a018
PDF
Synthesis and structure of a tetrameric tantalum(III) compound
P. F. Gilletti, V. G. Young, and T. M. Brown
pp 4034 - 4036; DOI:
10.1021/ic00320a019
PDF
Crystal structure and magnetic susceptibility of the dinuclear manganese(IV) complex Mn2O2(pic)4.cntdot.MeCN (picH = picolinic acid)
Eduardo Libby, Robert J. Webb, William E. Streib, Kirsten Folting, John C. Huffman, David N. Hendrickson, and George Christou
pp 4037 - 4040; DOI:
10.1021/ic00320a020
PDF
Crown thioether chemistry. The silver(I) complexes of trithia-9-crown-3, trithia-12-crown-3, and hexathia-18-crown-6
Philip J. Blower, Julie A. Clarkson, Simon C. Rawle, JudithAnn R. Hartman, Robert E. Wolf, Rahmi Yagbasan, Simon G. Bott, and Stephen R. Cooper
pp 4040 - 4046; DOI:
10.1021/ic00320a021
PDF
Formation of the metal-sulfide aggregate [W3S10]2- through a novel balanced intramolecular condensation redox-process with principal relevance to the formation of amorphous metal-sulfides like tungsten trisulfide
A. Mueller, E. Diemann, U. Wienboeker, and H. Boegge
pp 4046 - 4049; DOI:
10.1021/ic00320a022
PDF
Synthesis and characterization of bis[tetraphenylphosphonium] hexaselenoxoditungstate(2-)
Ying Jie Lu, Mohammad A. Ansari, and James A. Ibers
pp 4049 - 4050; DOI:
10.1021/ic00320a023
PDF
Structure, dynamics, and comparative stability of a mixed-ligand compound of tin(II)
Michael J. McGeary, Kirsten Folting, and Kenneth G. Caulton
pp 4051 - 4053; DOI:
10.1021/ic00320a024
PDF
Synthesis of boron nitride ceramics from 2,4,6-triaminoborazine
Chaitanya K. Narula, Riley Schaeffer, Ahbaya Datye, and Robert T. Paine
pp 4053 - 4055; DOI:
10.1021/ic00320a025
PDF
Inelastic neutron-scattering study of potassium pentadecacarbonylhydridohexacobaltate(1-): implications for location of the hydride
J. Eckert, A. Albinati, and G. Longoni
pp 4055 - 4056; DOI:
10.1021/ic00320a026
PDF
Magic numbers in atom and electron counting of supraclusters based on vertex-sharing icosahedra [Erratum to document cited in CA108(6):44256r]
Boon K. Teo and Hong Zhang
pp 4056 - 4056; DOI:
10.1021/ic00320a027
PDF

Issue 22


Structural features suggesting relativistic effects in a dimeric gold complex
Raphael G. Raptis, John P. Fackler, H. H. Murray, and Leigh C. Porter
pp 4057 - 4059; DOI:
10.1021/ic00321a001
PDF
Intercalation in the linear-chain compound molybdenyl hydrogen phosphate hydrate
T. R. Gilson and M. T. Weller
pp 4059 - 4061; DOI:
10.1021/ic00321a002
PDF
Stereoselective electron-transfer reaction between ferrocytochrome c and tris(acetylacetonato)cobalt(III)
Shigeyoshi Sakaki, Yuichi Nishijima, Hidetoshi Koga, and Katsutoshi Ohkubo
pp 4061 - 4063; DOI:
10.1021/ic00321a003
PDF
Organometallic complexes with electronic bridges. 4. Redox-active phenylene-bridged polymetallic .sigma.,.pi. complexes containing iron and chromium
George B. Richter-Addo and Allen D. Hunter
pp 4063 - 4065; DOI:
10.1021/ic00321a004
PDF
The first structural characterization of a nickel(I) macrocyclic system: structure of nickel(I) diphenyldi-p-toyl-21-thiaporphyrin
Lechoslaw Latos-Grazynski, Marilyn M. Olmstead, and Alan L. Balch
pp 4065 - 4066; DOI:
10.1021/ic00321a005
PDF
Aromatic ring stacking in the ternary copper(II) complexes [Cu(histamine)(L-AA)(ClO4)] (AA = phenylalaninate, tyrosinate). Structural evidence for intramolecular stacking involving a coordinated imidazole ring
Osamu Yamauchi, Akira Odani, Takamitsu Kohzuma, Hideki Masuda, Koshiro Toriumi, and Kazuo Saito
pp 4066 - 4068; DOI:
10.1021/ic00321a006
PDF
Synthesis and characterization of the new soluble selenide anion tris(tetraselenido)platinate(2-)
Mohammad A. Ansari and James A. Ibers
pp 4068 - 4069; DOI:
10.1021/ic00321a007
PDF
Comparative studies of the photophysical properties of copper phenanthrolines: from Cu(dmp)2+ to the copper(I) catenates
Ann K. I. Gushurst, David R. McMillin, Christiane O. Dietrich-Buchecker, and Jean Pierre Sauvage
pp 4070 - 4072; DOI:
10.1021/ic00321a008
PDF
Kinetic studies of the reductive quenching of photoexcited tris(2,2'-bipyrazine)ruthenium(II) by an oxalate ion in a photoelectrochemical system
Suzuko Nishida, Yutaka Harima, and Kazuo Yamashita
pp 4073 - 4077; DOI:
10.1021/ic00321a009
PDF
Photoselection studies of mixed-ligand ruthenium(II) complexes: [RuL2L']2+ multiple-state emission
Michael L. Myrick, M. Keith De Armond, and Richard L. Blakley
pp 4077 - 4084; DOI:
10.1021/ic00321a010
PDF
MLCT excited states. Role of the hydrido ligand in hydrido polypyridyl complexes of osmium(II) and ruthenium(II)
Elise Graham Megehee and Thomas J. Meyer
pp 4084 - 4091; DOI:
10.1021/ic00321a011
PDF
Structures, energetics, and vibrational frequencies of the silicon and germanium dichlorides and dibromides and their dimers
J. M. Coffin, T. P. Hamilton, P. Pulay, and I. Hargittai
pp 4092 - 4094; DOI:
10.1021/ic00321a012
PDF
Band structure and bonding of erbium rhodium carbide (Er8Rh5C12) and other carbides with C2 pairs
Stephen Lee, Wolfgang Jeitschko, and Rolf Dieter Hoffmann
pp 4094 - 4104; DOI:
10.1021/ic00321a013
PDF
Structural, spectroscopic and theoretical studies of novel d6 fac-bromotricarbonyl(dithiooxamide)rhenium complexes
Peter C. Servaas, Derk J. Stufkens, Ad Oskam, Pieter Vernooijs, Evert Jan Baerends, Dirk J. A. De Ridder, and Caspar H. Stam
pp 4104 - 4113; DOI:
10.1021/ic00321a014
PDF
EPR and FTIR spectroscopic study of the reaction of rhodium atoms with carbon monoxide in a rotating cryostat: formation of rhodium tetracarbonyl, dirhodium octacarbonyl, and tetrarhodium dodecacarbonyl
J. H. B. Chenier, M. Histed, J. A. Howard, H. A. Joly, H. Morris, and B. Mile
pp 4114 - 4119; DOI:
10.1021/ic00321a015
PDF
Solid-state phosphorus-31 NMR investigations of phosphido-bridged complexes: chemical shift bond angle correlations
A. J. Carty, C. A. Fyfe, M. Lettinga, S. Johnson, and L. H. Randall
pp 4120 - 4124; DOI:
10.1021/ic00321a016
PDF
Linear-chain ordering in a spin-3/2 system: magnetic susceptibilities of trichlorotris(pyridine)chromium
K. E. Merabet and Richard L. Carlin
pp 4125 - 4128; DOI:
10.1021/ic00321a017
PDF
Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers. Part 2. Zerovalent molybdenum complexes of mesocyclic and macrocyclic crown thioethers
Gregory J. Grant, Joseph P. Carpenter, William N. Setzer, and Donald G. VanDerveer
pp 4128 - 4131; DOI:
10.1021/ic00321a018
PDF
Ruthenium(II)-promoted site-selective intramolecular Diels-Alder reactions
Rahel Vac, John H. Nelson, Emil B. Milosavljevic, Ljiljana Solujic, and Jean Fischer
pp 4132 - 4139; DOI:
10.1021/ic00321a019
PDF
The Hurtley reaction. 2. Novel complexes of disubstituted acetylenes with copper(I) benzoates having a reactive ortho carbon-chlorine or carbon-bromine bond. X-ray structural characterization of tetrakis(2-chlorobenzoato)bis(diethyl acetylenedicarboxylate)tetracopper(I)
Henk L. Aalten, Gerard Van Koten, Ed Riethorst, and Casper H. Stam
pp 4140 - 4146; DOI:
10.1021/ic00321a020
PDF
Relative stabilities and interconversion of exo- and endo-trithiatetrazocines. Preparation and structure of exo-Ph2PN4S3NPPh3
A. Wallace Cordes, Stephen W. Liblong, Susan G. Phillips, and Richard T. Oakley
pp 4147 - 4150; DOI:
10.1021/ic00321a021
PDF
Cyclophospha(III)thiazenes: preparation and structural comparison of cis-(CO)5Cr[tert-BuP(NSN)2PBu-tert]Cr(CO)5 and trans-(CO)5Cr[iso-Pr2NP(NSN)2PNPriso2]Cr(CO)5 and a rational synthesis of the PIIIN3S2 ring
Tristram Chivers, Kaveripatnam S. Dhathathreyan, Cees Lensink, Auke Meetsma, Johan C. Van de Grampel, and Jan L. De Boer
pp 4150 - 4154; DOI:
10.1021/ic00321a022
PDF
Syntheses and characterization of trigonal-bipyramidal rhodium(I) complexes of tris(2-(diphenylphosphino)ethyl)phosphine and determination of a spectroscopic trans-influence series by phosphorus-31{proton} NMR spectroscopy
Jeffrey J. Gambaro, William H. Hohman, and Devon W. Meek
pp 4154 - 4159; DOI:
10.1021/ic00321a023
PDF
Synthesis and characterization of a biferrocene with a fulvalene ligand fused into a cis conformation: x-ray structure of N,N-dimethyl-2,5''-(2-azoniapropane-1,3-diyl)biferrocene pentaiodide
Wei Zhang, Scott R. Wilson, and David N. Hendrickson
pp 4160 - 4165; DOI:
10.1021/ic00321a024
PDF
Reactivity of bromodiisopropylgallium with ethanethiol and ethaneselenol. Synthesis of iso-C3H7(Br)GaEC2H5 (E = S, Se)
Gerhard G. Hoffmann and Roland Fischer
pp 4165 - 4167; DOI:
10.1021/ic00321a025
PDF
Redox kinetics of metal complexes in nonaqueous solutions: oxidation of methyl-substituted tris(1,10-phenanthroline)iron(II) complexes by hexakis(N,N-dimethylformamide)iron(III) in acetonitrile
Roland Schmid, Karl Kirchner, and V. N. Sapunov
pp 4167 - 4171; DOI:
10.1021/ic00321a026
PDF
Tetramethylammonium salts of tetrafluorochlorate(1-), tetrafluorobromate(1-) and hexafluorobromate(1-)
William W. Wilson and Karl O. Christe
pp 4172 - 4175; DOI:
10.1021/ic00321a027
PDF
Anion exchange in tetrafluoroammonium salts using graphite salts as an oxidizer- and acid-resistant anion-exchange medium
Karl O. Christe and Richard D. Wilson
pp 4175 - 4177; DOI:
10.1021/ic00321a028
PDF
Synthesis and structure of the Zintl phase potassium silicon arsenide, K2SiAs2
Weir Mirn Hurng, Eric S. Peterson, and John D. Corbett
pp 4177 - 4180; DOI:
10.1021/ic00321a029
PDF
Structural and kinetic investigations of a Tc(III)/Tc(II) redox couple. X-ray crystal structures of trans-[TcII(DPPE)2Cl2] and trans-[TcIII(DPPE)2C12]NO3.HNO3, where DPPE = 1,2-bis(diphenylphosphino)ethane [Erratum to document cited in CA109(16):135852u]
Karen Libson, Mary Noon Doyle, Rudy W. Thomas, Theodore Nelesnik, Mary Woods, James C. Sullivan, R. C. Elder, and Edward Deutsch
pp 4180 - 4180; DOI:
10.1021/ic00321a030
PDF

Issue 23


Stepwise synthesis and structural characterization of the molybdenum-iron-sulfur {[MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)2}6- and {[MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)(.mu.2-OH}5- doubly bridged double cubanes obtained by the coupling of [MoFe3S4] clusters
Dimitri Coucouvanis, P. R. Challen, Sang Man Koo, W. M. Davis, W. Butler, and W. R. Dunham
pp 4181 - 4183; DOI:
10.1021/ic00322a001
PDF
A novel ferromagnetic inorganic-organic host-guest system. Synthesis of crystalline small magnetite particles complexed with bis(pyridoxylidenehydrazino)phthalazine (DPDHP) at ambient temperature and neutral pH
Shalom Sarel, Schelly Avramovic-Grisaru, E. Rivka Bauminger, Israel Felner, Israel Nowik, R. J. P. Williams, and Nigel P. Hughes
pp 4183 - 4187; DOI:
10.1021/ic00322a002
PDF
Ground- and excited-state properties of a photostable hemicage ruthenium(II) polypyridine complex
Ruth Freitag Beeston, Steven L. Larson, and Michael C. Fitzgerald
pp 4187 - 4189; DOI:
10.1021/ic00322a003
PDF
Protein site recognition by chromium(III) complexes probed through NOE quenching
Jeffrey R. Bocarsly and Jacqueline K. Barton
pp 4189 - 4190; DOI:
10.1021/ic00322a004
PDF
Metalloporphyrin DNA interactions: insights from NMR studies of oligodeoxyribonucleotides
James A. Strickland, Luigi G. Marzilli, W. David Wilson, and Gerald Zon
pp 4191 - 4198; DOI:
10.1021/ic00322a005
PDF
Zinc(II), aluminum(III), and gallium(III) complexes of Schiff bases of 3-amino-3-phosphonopropionic acid and 5'-deoxypyridoxal
Arthur E. Martell and Bruno Szpoganicz
pp 4199 - 4206; DOI:
10.1021/ic00322a006
PDF
(CN)-chelate, N,N'-bridged dimeric palladium complexes derived from hydrazones PhC(R):NN'HPh. X-ray structure of [Pd(o-C6H4C(R):NNPh)L]2 [R = Me, L = P(OMe)3]
Pablo Espinet, Gabriel Garcia, Francisco J. Herrero, Yves Jeannin, and Michele Philoche-Levisalles
pp 4207 - 4211; DOI:
10.1021/ic00322a007
PDF
Derivatives of the type Os4(.mu.-H)(CO)14(ER3) (E = Si, Ge, Sn; R = Me, Ph): structure of tetradecacarbonyl(.mu.-hydrido)(trimethylstannyl)tetraosmium
Chang Yao Lu, Frederick W. B. Einstein, Victor J. Johnston, and Roland K. Pomeroy
pp 4212 - 4216; DOI:
10.1021/ic00322a008
PDF
Synthesis and cis-trans isomerism of (pentamethylcyclopentadienyl)rhenium(III) halide complexes formed by oxidative addition of X2 or HX (X = chlorine, bromine, iodine) to (.eta.5-C5Me5)Re(CO)2(PMe3) or (.eta.5-C5Me5)Re(CO)(PMe3)(N2)
A. Hugo Klahn-Oliva, Robert D. Singer, James M. Aramini, and Derek Sutton
pp 4217 - 4221; DOI:
10.1021/ic00322a009
PDF
Synthesis and characterization of the bis(1,3-bis(methylthio)-1,3-propanedithionate) complexes M[S2C3H(SCH3)2]2 (M = nickel, palladium, platinum)
Harkesh B. Singh, Roy H. Jacobson, Klaus Hinkelmann, Gordana Srdanov, and Fred Wudl
pp 4221 - 4225; DOI:
10.1021/ic00322a010
PDF
Coordination chemistry of neutral phenylcyanamide ligands bound to pentaammineruthenium(II)
Mark L. Naklicki and Robert J. Crutchley
pp 4226 - 4229; DOI:
10.1021/ic00322a011
PDF
Ferromagnetic behavior of linear-chain organometallic complexes. Structural and magnetic properties of 1:1 decamethylferrocenium salts of planar radical anion bis(dithiolato)metalates
Joel S. Miller, Joseph C. Calabrese, and Arthur J. Epstein
pp 4230 - 4238; DOI:
10.1021/ic00322a012
PDF
Preparation and spectroscopic characterization of difluorophosphorane, PH3F2. Phosphorus-31 NMR spectrum of protonated diphosphine, P2H5+
Rolf Minkwitz and Andreas Liedtke
pp 4238 - 4242; DOI:
10.1021/ic00322a013
PDF
Theoretical, UV-PES, XPS, and Moessbauer investigation of the electronic structure of dinuclear metal carbonyl diimine complexes with a metallacyclopentadienyl system
R. Bertoncello, Maurizio Casarin, M. Dal Colle, G. Granozzi, G. Mattogno, F. Muller, U. Russo, and K. Vrieze
pp 4243 - 4250; DOI:
10.1021/ic00322a014
PDF
Acid-base behavior in the ground and excited states of ruthenium(II) complexes containing tetraimines or dicarboxybipyridines as protonatable ligands
M. K. Nazeeruddin and K. Kalyanasundaram
pp 4251 - 4259; DOI:
10.1021/ic00322a015
PDF
Ligand fields from misdirected valency. 5. Consequences for spectral intensity distributions
Melinda J. Duer and Malcolm Gerloch
pp 4260 - 4264; DOI:
10.1021/ic00322a016
PDF
Solvent effects on two-bond tin-119-tin-117 spin coupling in bis(tributyltin) oxide and bis(trimethyltin) oxide
Thomas P. Lockhart
pp 4265 - 4268; DOI:
10.1021/ic00322a017
PDF
Diamond-square-diamond isomerization of heptahydrodicarbaheptaborane
Jane J. Ott, Carl A. Brown, and Benjamin M. Gimarc
pp 4269 - 4273; DOI:
10.1021/ic00322a018
PDF
Linkage isomer ratios in thermal and photochemical anation of acidopentacyanocobaltate(III) anions
Alexander David Kirk and Diane M. Kneeland
pp 4274 - 4278; DOI:
10.1021/ic00322a019
PDF
Synthesis and characterization of the new macrocyclic cage 5,12,17-trimethyl-1,5,9,12,17-pentaazabicyclo[7.5.5]nonadecane (L), which can selectively encapsulate lithium ion. Thermodynamic studies on protonation and complex formation. Crystal structures of the salt [HL][Cl].cntdot.3H2O and of the lithium complex [LiL][BPh4]
Andrea Bencini, Antonio Bianchi, Angela Borselli, Mario Ciampolini, Enrique Garcia-Espana, Paolo Dapporto, Mauro Micheloni, Paola Paoli, Jose Antonio Ramirez, and Barbara Valtancoli
pp 4279 - 4284; DOI:
10.1021/ic00322a020
PDF
Rate of reaction of tricarbonylbis(tricyclohexylphosphine)tungsten with pyridine, trimethyl phosphite, methyldiphenylphosphine and 2,6-dimethylpyridine. Stopped-flow kinetic study of concerted reactions at a sterically crowded metal center
Alberto A. Gonzalez, Kai Zhang, and Carl D. Hoff
pp 4285 - 4290; DOI:
10.1021/ic00322a021
PDF
Synthesis and reactivity of alkoxide-bridged cobaltic acetates
Charles E. Sumner and Guy R. Steinmetz
pp 4290 - 4294; DOI:
10.1021/ic00322a022
PDF
Entropy of binding molecular hydrogen and nitrogen in the complexes tricarbonylbis(tricyclohexylphosphine)transition metal (transition metal chromium, molybdenum, tungsten)
Alberto A. Gonzalez and Carl D. Hoff
pp 4295 - 4297; DOI:
10.1021/ic00322a023
PDF
New and general route to the synthesis of oxopolymetalates via peroxometalates in aqueous medium: synthesis and crystal and molecular structure of bis[bis(triphenylphosphine)nitrogen(1+)] nonadecaoxohexatungstate(2-)
Ramgopal Bhattacharyya, Sudeb Biswas, Jeffrey Armstrong, and Elizabeth M. Holt
pp 4297 - 4300; DOI:
10.1021/ic00322a024
PDF
Synthesis and structures of (2,9-dimethyl-1,10-phenanthroline)(acetonitrile)copper(I) perchlorate and hexafluorophosphate. A correlation between bond angles and bond distances in T- and Y-shaped three-coordinate copper(I) complexes
Megumu Munakata, Masahiko Maekawa, Susumu Kitagawa, Shinzi Matsuyama, and Hideki Masuda
pp 4300 - 4302; DOI:
10.1021/ic00322a025
PDF
A novel polynuclear molybdenum-copper cluster from tetrathiomolybdate: preparation and structure of (Et4N)2[Mo2Cu5S8(S2CNMe2)3].cntdot.2H2O
Xinjian Lei, Zhiying Huang, Qiutian Liu, Maochun Hong, and Hanqin Liu
pp 4302 - 4304; DOI:
10.1021/ic00322a026
PDF
Kinetics and mechanism of carbon monoxide substitution of osmium pentacarbonyl
Jiankun Shen, Yici Gao, Qizhen Shi, and Fred Basolo
pp 4304 - 4306; DOI:
10.1021/ic00322a027
PDF
Resonance Raman spectra and excited-state lifetimes for a series of 3,3'-polymethylene-2,2'-bipyridine complexes of ruthenium(II) [Erratum to document cited in CA111(8):66867e]
Thomas C. Strekas, Harry D. Gafney, Steven A. Tysoe, Randolph P. Thummel, and Francois Lefoulon
pp 4306 - 4306; DOI:
10.1021/ic00322a028
PDF

Issue 24


Pyrazolyl-bridged iridium dimers. 14. Steric control in ground-state oxidative addition of methyl iodide to complexes related to tetracarbonylbis(.mu.-pyrazolyl)diiridium
Ron D. Brost and Stephen R. Stobart
pp 4307 - 4308; DOI:
10.1021/ic00323a001
PDF
Utility of the 2,6-dimethylphenoxide ligand in providing chloride- and oxide-free yttrium [Y(OR)3(solvent)a]b complexes with accessible coordination sites
William J. Evans, Jeffrey M. Olofson, and Joseph W. Ziller
pp 4308 - 4309; DOI:
10.1021/ic00323a002
PDF
Oxidation photochemistry of dimolybdenum(II) diaryl phosphate promoted by visible light
I Jy Chang and Daniel G. Nocera
pp 4309 - 4311; DOI:
10.1021/ic00323a003
PDF
Facile regioselective ligand substitution for the in-plane bridging acetates in octakis(.mu.-acetato-O,O')tetraplatinum(II)
Tadashi Yamaguchi, Yoichi Sasaki, Akira Nagasawa, Tasuku Ito, Nobuaki Koga, and Keiji Morokuma
pp 4311 - 4312; DOI:
10.1021/ic00323a004
PDF
Redox regulation in ruthenium(II) complexes of 2,6-bis(N-pyrazolyl)pyridine ligands: synthetically versatile analogs of 2,2':6',2''-terpyridine
Donald L. Jameson, Jean K. Blaho, Katherine T. Kruger, and Kenneth A. Goldsby
pp 4312 - 4314; DOI:
10.1021/ic00323a005
PDF
Kinetics and mechanism of the anation of aquocobalamin (vitamin B12a) by cyanoferrates. Isolation and identification of a cyano-bridged product and mechanistic information from pressure effects
G. Stochel, R. Van Eldik, H. Kunkely, and A. Vogler
pp 4314 - 4318; DOI:
10.1021/ic00323a006
PDF
Reactions of cobalt(II) macrocycles with alkyl and alkylperoxy radicals
Andreja Bakac and James H. Espenson
pp 4319 - 4322; DOI:
10.1021/ic00323a007
PDF
Kinetics of reduction of a series of imidazolium ions and cobalt(III)-imidazole complexes by 1-hydroxy-1-methylethyl radicals
Andreja Bakac, Vjera Butkovic, James H. Espenson, Jasna Lovric, and Matko Orhanovic
pp 4323 - 4326; DOI:
10.1021/ic00323a008
PDF
Kinetics and mechanism of the oxidation of the hypophosphite ion by the tetrahydroxoargentate(III) ion
Raj N. Mehrotra and Louis J. Kirschenbaum
pp 4327 - 4330; DOI:
10.1021/ic00323a009
PDF
Mechanism of ligand substitution in aluminum(III) complexes
Brian J. Plankey and Howard H. Patterson
pp 4331 - 4333; DOI:
10.1021/ic00323a010
PDF
Unusual bonding in a main-group multiple-bonded system: umbrella-shaped diphosphenes
T. Busch, W. W. Schoeller, E. Niecke, M. Nieger, and H. Westermann
pp 4334 - 4340; DOI:
10.1021/ic00323a011
PDF
Molecular structure and internal rotation potential of perfluoro-2,3-diaza-1,3-butadiene, CF2:N.N = CF2. An electron diffraction and ab initio study
Heinz Oberhammer, Charles W. Bauknight, and Darryl D. DesMarteau
pp 4340 - 4344; DOI:
10.1021/ic00323a012
PDF
Photophysical, photochemical, and electrochemical properties of mononuclear and dinuclear ruthenium(II) complexes containing 2,2'-bipyridine and the 3,5-bis(pyridin-2-yl)-1,2,4-triazolate ion
Francesco Barigelletti, Luisa De Cola, Vincenzo Balzani, Ronald Hage, Jaap G. Haasnoot, Jan Reedijk, and Johannes G. Vos
pp 4344 - 4350; DOI:
10.1021/ic00323a013
PDF
Oligomeric dicyanobis(polypyridine)ruthenium(II) complexes. Synthesis, spectroscopic, and photophysical properties
C. A. Bignozzi, S. Roffia, C. Chiorboli, J. Davila, M. T. Indelli, and F. Scandola
pp 4350 - 4358; DOI:
10.1021/ic00323a014
PDF
Quantitative evaluation of the relationships between excited-state geometry and the intensities of fundamentals, overtones, and combination bands in resonance Raman spectra
Kyeong Sook Kim Shin and Jeffrey I. Zink
pp 4358 - 4366; DOI:
10.1021/ic00323a015
PDF
Electronic absorption and MCD spectra for the binuclear three-coordinate gold(I) complex Au2(dmpm)32+ (dmpm = bis(dimethylphosphino)methane)
Huey Rong C. Jaw, M. Meral Savas, and W. Roy Mason
pp 4366 - 4369; DOI:
10.1021/ic00323a016
PDF
Electronic absorption and MCD spectra for isoelectronic linear two-coordinate bis(tri-tert-butylphosphine)metal complexes of platinum(0) and gold(I)
Huey Rong C. Jaw and W. Roy Mason
pp 4370 - 4373; DOI:
10.1021/ic00323a017
PDF
Synthesis and characterization of copper(II) 5,10,15,20-tetrakis(2,6-dipivalamidophenyl)porphyrinate: a bis-picket-fence porphyrin
C. M. Drain and Barry B. Corden
pp 4374 - 4376; DOI:
10.1021/ic00323a018
PDF
Synthesis and reactivity of a nickel(II) complex with a macrocycle containing a peripheral hydroxyl group
Neil A. Stephenson, Harrell E. Tweedy, and Daryle H. Busch
pp 4376 - 4379; DOI:
10.1021/ic00323a019
PDF
Charge distribution in transition-metal complexes of a Schiff base biquinone ligand. Structural and electrochemical properties of the MII(Cat-N-BQ)2MIII(Cat-N-BQ)(Cat-N-SQ)MIV(Cat-N-SQ)2 tautomeric series
Cathy L. Simpson, Steven R. Boone, and Cortlandt G. Pierpont
pp 4379 - 4385; DOI:
10.1021/ic00323a020
PDF
Aspects of the oxygen atom transfer chemistry of tungsten
Shi Bao Yu and R. H. Holm
pp 4385 - 4391; DOI:
10.1021/ic00323a021
PDF
Synthesis, characterization, and molecular structures of a series of [(3,5-dimethylpyrazolyl)borato]vanadium(III) and -(IV) complexes
Ellen Kime-Hunt, K. Spartalian, Martin DeRusha, Christine M. Nunn, and Carl J. Carrano
pp 4392 - 4399; DOI:
10.1021/ic00323a022
PDF
Synthesis and characterization of vanadium(V) and -(IV) hydroxamate complexes. X-ray crystal structures of oxochlorobis(benzohydroxamato)vanadium(V) and oxoisopropoxo(N,N'-dihydroxy-N,N'-diisopropylheptanediamido)vanadium(V)
Diane C. Fisher, Susan J. Barclay-Peet, Carol A. Balfe, and Kenneth N. Raymond
pp 4399 - 4406; DOI:
10.1021/ic00323a023
PDF
Study of the high-temperature spin-state crossover in the iron(II) pyrazolylborate complex Fe[HB(pz)3]2
Fernande Grandjean, Gary J. Long, Bennett B. Hutchinson, LaNelle Ohlhausen, Paul Neill, and J. David Holcomb
pp 4406 - 4414; DOI:
10.1021/ic00323a024
PDF
Photochemical reactions of Cp'2Mo2(CO)6 (Cp' = .eta.5-C5H4CH3) with amines. Descriptive chemistry of the disproportionation reactions
Cecelia E. Philbin, Albert E. Stiegman, Steve C. Tenhaeff, and David R. Tyler
pp 4414 - 4417; DOI:
10.1021/ic00323a025
PDF
Isocyanide complexes of titanium(IV) and vanadium(V): concerning the nonexistent insertion of isocyanides into a metal-chloride bond
Tommaso Carofiglio, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 4417 - 4419; DOI:
10.1021/ic00323a026
PDF
Kinetic study of the formation of the oxo diperoxo complex of tungsten(VI) in aqueous perchloric acid solution
M. Ashraf Islam and Richard C. Thompson
pp 4419 - 4422; DOI:
10.1021/ic00323a027
PDF
Intermediates in the charge-transfer and ligand-labilization photoreactions of molybdenum(V) .mu.-oxo dimers
M. Feliz and G. Ferraudi
pp 4422 - 4425; DOI:
10.1021/ic00323a028
PDF
Two polymorphs of the diazaphosphole oxide C6H4(NH)2P(O)Ph
Joseph M. Barendt, Elizabeth G. Bent, R. Curtis Haltiwanger, Christopher A. Squier, and Arlan D. Norman
pp 4425 - 4427; DOI:
10.1021/ic00323a029
PDF
A stable .mu.-peroxo complex of rhodium(II) intercalated in the interlamellar spaces of montmorillonite. Solid-state aluminum-27, silicon-29 and phosphorus-31 NMR and ESR investigation
M. M. Taqui Khan, M. R. H. Siddiqui, and S. A. Samad
pp 4427 - 4430; DOI:
10.1021/ic00323a030
PDF

Issue 25


Formation of metal-chalcogen bonds by the reaction of metal-alkyls with silyl chalcogenides
S. M. Stuczynski, J. G. Brennan, and M. L. Steigerwald
pp 4431 - 4432; DOI:
10.1021/ic00324a001
PDF
A cyclic octanuclear polyoxoalkoxy vanadate(IV) with an oxalate-binding cavity, [(n-C4H9)4N]2[V8O8(OCH3)16(C2O4)]. Structural comparison with the analogous polymolybdates(V) complex [(n-C4H9)4N]2[Mo8O16(OC2H5)8(C2O4)]
Qin Chen, Shuncheng Liu, and Jon Zubieta
pp 4433 - 4434; DOI:
10.1021/ic00324a002
PDF
Skeletal rearrangement of boridohexadecacarbonyltetrairondirhodate(1-). An example of an associative cluster isomerization
Ananda K. Bandyopadhyay, Rajesh Khattar, and Thomas P. Fehlner
pp 4434 - 4436; DOI:
10.1021/ic00324a003
PDF
Intrinsic transition metal-carbon double bond dissociation energies: periodic trends in M+-CH2 bond strengths
P. B. Armentrout, L. S. Sunderlin, and Ellen R. Fisher
pp 4436 - 4437; DOI:
10.1021/ic00324a004
PDF
From cis-dichloride complexes to dihydride complexes of the iron group metals via two successive .eta.2-dihydrogen intermediates
E. Paul Cappellani, Patricia A. Maltby, Robert H. Morris, Caroline T. Schweitzer, and Mark R. Steele
pp 4437 - 4438; DOI:
10.1021/ic00324a005
PDF
Synthesis and solid- and liquid-state characterization of a hexameric cluster of titanium(IV): Ti6(.mu.2-O)2(.mu.3-O)2(.mu.2-OC4H9)2(OC4H9)6(OCOCH3)8
S. Doeuff, Y. Dromzee, F. Taulelle, and C. Sanchez
pp 4439 - 4445; DOI:
10.1021/ic00324a006
PDF
Synthesis, structure, and characterization of a mixed-valence manganese(III)-manganese(IV) bis(.mu.-oxo) complex with a macrocyclic tetraaza ligand
Karen J. Brewer, Melvin Calvin, Richard S. Lumpkin, John W. Otvos, and Larry O. Spreer
pp 4446 - 4451; DOI:
10.1021/ic00324a007
PDF
Studies of carbon monoxide labilization and intramolecular hydride transfer reactions in Group VI (chromium, molybdenum, tungsten) metal-platinum heterobimetallic .mu.-phosphido hydrido carbonyl complexes
John Powell, Michael R. Gregg, and Jeffery F. Sawyer
pp 4451 - 4460; DOI:
10.1021/ic00324a008
PDF
Carbon monoxide labilization and hydrogen-transfer pathways in cationic phosphido-bridged rhenium-platinum heterobimetallic systems and the molecular structures of [.eta.5-Cp(ON)Re(.mu.-PR2)(.mu.-H)Pt(PPh3)2]X (R = Cy, X- = PF6-; R = Ph, X- = BF4) and [.eta.5-Cp(ON)HRe(.mu.-PCy2)Pt(PPh3)2]BF4, a rare example of bridging- and terminal-hydrido geometric isomers
John Powell, Jeffery F. Sawyer, and Matthew V. R. Stainer
pp 4461 - 4470; DOI:
10.1021/ic00324a009
PDF
Synthesis of "platinum-diruthenium" and "platinum-triruthenium" heterometallic complexes from the reaction of undecacarbonyl(diphenylphosphine)triruthenium with zerovalent complexes of platinum. Single-crystal x-ray diffraction studies of PtRu2(.mu.-PPh2)(.mu.-H)(CO)7(PCy3) and PtRu3(.mu.-PPh2)(.mu.-H)(CO)9(PCy3)
John Powell, John C. Brewer, Giulia Gulia, and Jeffery F. Sawyer
pp 4470 - 4476; DOI:
10.1021/ic00324a010
PDF
A new tetranuclear oxohydroxoiron(III) cluster: crystal structure, magnetic properties, and EXAFS investigation of [L4Fe4(.mu.-O)2(.mu.-OH)4]I4.cntdot.3H2O (L = 1,4,7-triazacyclononane)
Stefan Drueke, Karl Wieghardt, Bernhard Nuber, Johannes Weiss, Emile L. Bominaar, A. Sawaryn, H. Winkler, and A. X. Trautwein
pp 4477 - 4483; DOI:
10.1021/ic00324a011
PDF
Molybdenum(VI)-dioxo complexes with linear and tripodal tetradentate ligands: models for the molybdenum(VI/V) centers of the molybdenum hydroxylases and related enzymes. 1. Syntheses and structures
Carol J. Hinshaw, Gang Peng, Raghuvir Singh, Jack T. Spence, John H. Enemark, Michael Bruck, John Kristofzski, Shannath L. Merbs, Richard B. Ortega, and Pamela A. Wexler
pp 4483 - 4491; DOI:
10.1021/ic00324a012
PDF
Influence of thiolate ligation on the heme electronic structure in microsomal cytochrome P-450 and model compounds: resonance Raman spectroscopic evidence
Pavel Anzenbacher, Ruby Evangelista-Kirkup, John Schenkman, and Thomas G. Spiro
pp 4491 - 4495; DOI:
10.1021/ic00324a013
PDF
Proton and carbon-13 NMR studies of electron spin delocalization in nickel(II) bis(alkyl xanthate) complexes of nitrogenous bases and comparison with nickel-nitroxyl interactions in analogous spin-labeled complexes
Scott K. Sheppard, Gareth R. Eaton, and Sandra S. Eaton
pp 4496 - 4499; DOI:
10.1021/ic00324a014
PDF
Thermal decomposition of energetic materials. 34. Decarbonylation, decarboxylation, and coupling reactions of metal propiolates, M[O2CC.tplbond.CH]
C. E. Stoner and T. B. Brill
pp 4500 - 4506; DOI:
10.1021/ic00324a015
PDF
UV photochemistry of trans-cyanothiocyanatotetraamminechromium(III). Communication between charge-transfer and ligand-field states
Pietro Riccieri, Edoardo Zinato, and Antonella Damiani
pp 4506 - 4509; DOI:
10.1021/ic00324a016
PDF
Differences in nature and stability of cadmium complexes with Group 15/Group 16 donor ligands as determined by multinuclear (phosphorus-31, selenium-77, cadmium-113) magnetic resonance and electrochemical techniques
Alan M. Bond, Ray Colton, Jennifer Ebner, and S. Richard Ellis
pp 4509 - 4516; DOI:
10.1021/ic00324a017
PDF
Similarities and differences in the structural and electronic properties of .kappa.-phase organic conducting and superconducting salts
D. Jung, M. Evain, J. J. Novoa, M. H. Whangbo, M. A. Beno, A. M. Kini, A. J. Schultz, J. M. Williams, and P. J. Nigrey
pp 4516 - 4522; DOI:
10.1021/ic00324a018
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Solid-state geometric isomers of octahydridotetrakis(triphenylphosphine)dirhenium
F. Albert Cotton and Rudy L. Luck
pp 4522 - 4527; DOI:
10.1021/ic00324a019
PDF
Structure and reactivity of tetrakis(dimethylphenylphosphine)tetrahydridorhenium(1+)
Diane M. Lunder, Mark A. Green, William E. Streib, and Kenneth G. Caulton
pp 4527 - 4531; DOI:
10.1021/ic00324a020
PDF
Synthesis and structural studies of nickel(II) complexes of 14-membered trans-N2O2 and trans-N2S2 quadridentate macrocycles
Paul A. Duckworth, Frederick S. Stephens, Kevin P. Wainwright, K. D. V. Weerasuria, and S. Bruce Wild
pp 4531 - 4535; DOI:
10.1021/ic00324a021
PDF
Synthesis of unsymmetrical bidentate and tridentate phosphines by [4 + 2] Diels-Alder cycloadditions and Michael additions of (phosphole)- and (vinylphosphine)molybdenum carbonyl complexes
Salina Affandi, John H. Nelson, and Jean Fischer
pp 4536 - 4544; DOI:
10.1021/ic00324a022
PDF
Synthetic and mechanistic investigations of the reactions of organic nitriles with thiazyl chloride and the thermolysis of 1,3-dichloro-1,3,2,4,6-dithiatriazines
Allen Apblett and Tristram Chivers
pp 4544 - 4548; DOI:
10.1021/ic00324a023
PDF
Chromium(II) and vanadium(II) reduction of pentacyanocobaltate(III) complexes
Robert J. Balahura and Michael D. Johnson
pp 4548 - 4551; DOI:
10.1021/ic00324a024
PDF
Crystal and molecular structure of dichlorobis(4-nitroso-N,N-dimethylaniline)zinc(II), an example of an oxygen-bonded arylnitroso ligand
Shengzhi Hu, Darren M. Thompson, Philip O. Ikekwere, Richard J. Barton, Keith E. Johnson, and Beverly E. Robertson
pp 4552 - 4554; DOI:
10.1021/ic00324a025
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Q-band splitting in the spectra of heme proteins
J. A. Cowan and Harry B. Gray
pp 4554 - 4556; DOI:
10.1021/ic00324a026
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Issue 26


A general method for assembling (.mu.-oxo)bis(.mu.-carboxylato)diiron(III) complexes with labile terminal sites using a bridging dicarboxylate ligand
Robert H. Beer, William B. Tolman, Simon G. Bott, and Stephen J. Lippard
pp 4557 - 4558; DOI:
10.1021/ic00325a001
PDF
Fluoride ion promoted oxidative cleavage of (.mu.-oxo)iron(III) tetraarylporphyrins
Alaganandan Nanthakumar and Harold M. Goff
pp 4559 - 4561; DOI:
10.1021/ic00325a002
PDF
Oxygen-atom transfer catalyzed by an oxo-bridged molybdenum(V) compound
Donald M. Baird, S. Falzone, and J. E. Haky
pp 4561 - 4562; DOI:
10.1021/ic00325a003
PDF
Conversion of long-chain terminal alcohols and secondary amines into tertiary amines using dichlorotris(triphenylphosphine)ruthenium(II) as catalyst
Sanjoy Ganguly, Frederick L. Joslin, and D. Max Roundhill
pp 4562 - 4564; DOI:
10.1021/ic00325a004
PDF
Dichloro[hydrotris(1-pyrazolyl)borato]sulfidotechnetium(V): the first complex containing a technetium-sulfur double bond
Adriano Duatti, Francesco Tisato, Fiorenzo Refosco, Ulderico Mazzi, and Marino Nicolini
pp 4564 - 4565; DOI:
10.1021/ic00325a005
PDF
Reversible dimerization of a titanium ketyl: (silox)3TiOCPh2.bul. (silox = tert-Bu3SiO-)
Katharine J. Covert and Peter T. Wolczanski
pp 4565 - 4567; DOI:
10.1021/ic00325a006
PDF
Ion association and the reactions of cobalt(III)-acido complexes. 4. Origin of the products in the base hydrolysis of [Co(NH3)5X](3-n)+ complexes
Nicola E. Brasch, David A. Buckingham, Charles R. Clark, and Kim S. Finnie
pp 4567 - 4574; DOI:
10.1021/ic00325a007
PDF
Theoretical study of the electron density in iron(II) porphyrin bis(water)
Marie Madeleine Rohmer
pp 4574 - 4578; DOI:
10.1021/ic00325a008
PDF
Photochemical reactivity of the cluster tetradecachlorohexamolybdate(2-): photosubstitution and photoredox processes
B. Kraut and G. Ferraudi
pp 4578 - 4583; DOI:
10.1021/ic00325a009
PDF
Europium-151 Moessbauer effect study of several organoeuropium(II) complexes
Alan F. Williams, Fernande Grandjean, Gary J. Long, Tamara A. Ulibarri, and William J. Evans
pp 4584 - 4588; DOI:
10.1021/ic00325a010
PDF
Electronic structures of trifluorodixenon(+) and xenon iodide trifluoride. Examples of 5c,6e hypervalent bonding
David A. Dixon, Anthony J. Arduengo, and William B. Farnham
pp 4589 - 4593; DOI:
10.1021/ic00325a011
PDF
Preparation, characterization, and structural aspects of transition metal complexes with 4,7,10-trioxa-1,13-dithia[13](2,5)-1,3,4-thiadiazolophane
Raffaele Bonomo, Francesco Bottino, Frank R. Fronczek, Antonino Mamo, and Sebastiano Pappalardo
pp 4593 - 4598; DOI:
10.1021/ic00325a012
PDF
Synthesis, molecular and electronic structure, and properties of mononuclear trimethylphosphine-containing cyclopentadienyl derivatives of molybdenum(III) and molybdenum(IV). Direct evidence of molybdenum(III)-phosphorus .pi. back-bonding
Steven T. Krueger, Rinaldo Poli, Arnold L. Rheingold, and Donna L. Staley
pp 4599 - 4607; DOI:
10.1021/ic00325a013
PDF
Heat capacity study of the abrupt valence-detrapping phase transition of mixed-valence hexakis(acetato)oxotris(pyridine)trimanganese.pyridine
Motohiro Nakano, Michio Sorai, John B. Vincent, George Christou, Ho G. Jang, and David N. Hendrickson
pp 4608 - 4614; DOI:
10.1021/ic00325a014
PDF
Synthesis and structure of dirhodium compounds featuring an end-on-bridging ditellurium
Massimo Di Vaira, Maurizio Peruzzini, and Piero Stoppioni
pp 4614 - 4619; DOI:
10.1021/ic00325a015
PDF
Oxidation chemistry of ruthenium-salen complexes
Wa Hung Leung and Chi Ming Che
pp 4619 - 4622; DOI:
10.1021/ic00325a016
PDF
Luminescent extended one-dimensional heterobimetallic chain compounds with relativistic metal-metal bonds. Synthesis, crystal structures, and spectroscopic studies of AuTl(MTP)2 and Au2Pb(MTP)4 (MTP = [CH2P(S)Ph2]-
Suning Wang, Guillermo Garzon, Christopher King, Ju Chun Wang, and John P. Fackler
pp 4623 - 4629; DOI:
10.1021/ic00325a017
PDF
Reactions of 5-(perfluoroalkyl)tetrazolates with cyanogen, nitrosyl, and cyanuric chlorides
Earnest Obed John, Robert L. Kirchmeier, and Jeanne M. Shreeve
pp 4629 - 4633; DOI:
10.1021/ic00325a018
PDF
Dinuclear complexes of a [30]py2N4O4 macrocyclic ligand containing two .alpha.,.alpha.'-bis(aminomethyl)pyridine moieties. Comparison with analogous 22- and 24-membered macrocyclic ligands
Rached Menif, Dian Chen, and Arthur E. Martell
pp 4633 - 4639; DOI:
10.1021/ic00325a019
PDF
Synthesis, structure, and spectroscopic properties of five-coordinate mercaptoiron(II) porphyrins. Models for the reduced state of cytochrome P450
M. Schappacher, L. Ricard, J. Fischer, Raymond Weiss, R. Montiel-Montoya, E. Bill, and A. X. Trautwein
pp 4639 - 4645; DOI:
10.1021/ic00325a020
PDF
Stabilization of biochemically interesting intermediates by metal coordination. 6. Charge transfer in complexes of 1,3-dimethyllumazine with low-valent metals
Christian Bessenbacher, Conny Vogler, and Wolfgang Kaim
pp 4645 - 4648; DOI:
10.1021/ic00325a021
PDF
Preparation and properties of the nitrido-bridged osmium(IV) binuclear complexes [OsIV2N(NH3)10-nCln]Cl5-n (n = 2, 3)
Sook Hui Kim, Bruce A. Moyer, Sarah Azan, Gilbert M. Brown, Ada L. Olins, and David P. Allison
pp 4648 - 4650; DOI:
10.1021/ic00325a022
PDF
Proton NOE studies on dicopper(II) dicobalt(II) superoxide dismutase
Lucia Banci, Ivano Bertini, Claudio Luchinat, Mario Piccioli, Andrea Scozzafava, and Paola Turano
pp 4650 - 4656; DOI:
10.1021/ic00325a023
PDF
Interactions between cyanoborohydrides and (bis(diphenylphosphino)methane)dichloroplatinum. X-ray structural characterization of the complexes [Pt(dppm)(CNBH2CN)]2.cntdot.CHCl3, [Pt(dppm)(CN)]2.cntdot.1/2C5H5N, and [Pt(dppm)(CNBH3)]2.cntdot.H2O. Isomerization of trans-[Pt(dppm)(NCBH2CN)]2 to trans-[Pt(dppm)(CNBH2CN)]2
M. Nazrul I. Khan, Christopher King, Ju Chun Wang, Suning Wang, and John P. Fackler
pp 4656 - 4662; DOI:
10.1021/ic00325a024
PDF
ENDOR spectroscopy of (pentamethylcyclopentadienyl)(cyclotetraene)zirconium, [{.eta.5-(CH3)5C5}Zr(.eta.8-C8H8)]: the first stable paramagnetic zirconium sandwich compound
Didier Gourier, Edmond Samuel, and Jan H. Teuben
pp 4663 - 4667; DOI:
10.1021/ic00325a025
PDF
Unanticipated redox transformations in gold polyselenides. Isolation and characterization of diselenobis(tetraselenido)diaurate(2-) and undecaselenido(2-)
Mercouri G. Kanatzidis and Song Ping Huang
pp 4667 - 4669; DOI:
10.1021/ic00325a026
PDF